Removal of Methylene Blue by Low-Cost Adsorbent Prepared from Jujube Stones – Kinetic and Thermodynamic Studies

• Autorzy: Sanad Asmae , Bensemlali Meryem , Hatimi Badreddine , Chajri Fatima Zahra , Joudi Meryeme , Aarfane Abdellatif , Labjar Najoua , Bakasse Mina , Nasrellah Hamid

Identyfikatory

DOI

10.12912/27197050/186904

• Języki publikacji: EN

Abstrakty

EN

Agricultural residue emerges as a cost-effective and readily available option for the adsorption of dyes, owing to its affordability and efficacy. The purpose of our study focuses on the methylene blue dye (MB) removal using chemically modified jujube stone (MJS) as an adsorbent. The MJS underwent characterization through multiple methodologies including scanning electron microscopy (SEM), Energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). The research systematically investigated contact time, PH, temperature, initial dye concentration, and adsorbent dosage impact to optimize the removal efficiency. Experimental findings demonstrated that the MJS adsorbent achieved a dye removal efficiency of approximately 94% under batch mode and room temperature conditions. Kinetic analysis revealed an equilibrium time of around 70 minutes. Remarkably, this study unveils the novel application of chemically customized jujube stone a highly effective adsorbent for removing methylene blue dye. Applying the pseudo-second-order model provides the most precise description for methylene blue (MB) adsorption onto MJS. The modeling of adsorption isotherms indicated conformity to the Langmuir model. The thermodynamic study shows a negative value of ΔG, which demonstrates spontaneous MB adsorption into MJS, while a positive value of ΔH implies an endothermic adsorption process.

Słowa kluczowe

EN

kinetic; thermodynamic study; methylene blue; adsorption; removal; jujube Stones

• Wydawca: Lubelski Oddział Polskiego Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology ; WNGB Wydawnictwo Naukowe
• Czasopismo: Ecological Engineering & Environmental Technology
• Rocznik: 2024
• Tom: Vol. 25, iss. 6
• Strony: 148--158
• Opis fizyczny: Bibliogr. 56 poz., rys., tab.

Twórcy

autor

Sanad Asmae

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0009-0006-1314-518X

autor

Bensemlali Meryem

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0000-0002-4860-4829

autor

Hatimi Badreddine

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0000-0001-9200-2334

autor

Chajri Fatima Zahra

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0000-0002-4189-5379

autor

Joudi Meryeme

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco
• Laboratory of Analytic and Molecular Chemistry, Faculty of Sciences Casablanca, Morocco

• https://orcid.org/0000-0002-4938-6501

autor

Aarfane Abdellatif

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco
• Higher School of Education and Training, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0009-0005-8160-1119

autor

Labjar Najoua

• Laboratory of Spectroscopy, Molecular Modelling, Materials, Nanomaterials, Water and Environnement, ENSAM University Mohammed V in Rabat, Morocco
• Higher School of Education and Training, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0000-0002-9273-2799

autor

Bakasse Mina

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0000-0001-7300-0712

autor

Nasrellah Hamid

• Laboratory of Organic Bioorganic Chemistry and Environment, Faculty of Sciences, University Chouaib Doukkali, El Jadida, Morocco
• Higher School of Education and Training, University Chouaib Doukkali, El Jadida, Morocco

• https://orcid.org/0000-0002-9224-2220

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