Statistical optimization of the synthesis of plant-derived fatty acid esters of TMP over homogeneous organometallic tin catalyst

• Autorzy: Nowicki J. , Drabik J. , Stańczyk D. , Mosio-Mosiewski J. , Woszczyński P.

Identyfikatory

DOI

10.2478/pjct-2018-0024

• Języki publikacji: EN

Abstrakty

EN

A class of very important industrial-grade biolubricants was synthesized from plant-derived fatty acids (oleic and isostearic acid) by direct esterifi cation of trimethylolpropane according to novel effective and high selective method using Sn bis(2-ethylhexanoate) as catalyst. Model transesterifi cation reactions were performed with oleic and isostearic acids to optimize the reaction conditions to obtain maximum content of TMP triesters. Used specifi c homogeneous Sn catalyst allows to obtain TMP esters with very high content of triesters, above of 94 wt% without deep vacuum purifying distillation. Both TMP esters were evaluated for their physicochemical and tribological properties using ASTM standards. Both TMP esters exhibited high viscosity indexes and excellent low temperature properties.

Słowa kluczowe

EN

tin catalyst; trimethylolpropane esters; statistical optimization; tribology

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2018
• Tom: Vol. 20, nr 2
• Strony: 61--70
• Opis fizyczny: Bibliogr. 36 poz., rys., tab.

Twórcy

autor

Nowicki J.

• Institute of Heavy Organic Synthesis “Blachownia”, Energetyków 9, PL47225 Kędzierzyn-Koźle, Poland

autor

Drabik J.

• Institute for Sustainable Technologies – National Research Inst., K. Pulaskiego 6/10, PL26600 Radom, Poland

autor

Stańczyk D.

• Institute of Heavy Organic Synthesis “Blachownia”, Energetyków 9, PL47225 Kędzierzyn-Koźle, Poland

autor

Mosio-Mosiewski J.

• Institute of Heavy Organic Synthesis “Blachownia”, Energetyków 9, PL47225 Kędzierzyn-Koźle, Poland

autor

Woszczyński P.

• Institute of Heavy Organic Synthesis “Blachownia”, Energetyków 9, PL47225 Kędzierzyn-Koźle, Poland

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).