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Leaching behaviour of a turkish lateritic ore in the presence of additives

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This paper investigates the dissolution mechanism of a lateritic nickel ore from the Caldag Region of Manisa in Turkey. The ore sample contained 1.2% Ni, 24.8% Fe, and 0.062% Co. The optimum leaching conditions were found to be temperature 80 oC, particle size -74 μm, H2SO4 concentration 200 g/dm3, solids ratio (by weight) 10% and leaching duration 8 h. The extractions of 98.2% Ni, 98.6% Fe and Co 98.9% were obtained under these conditions. Additionally, the effects of additional substances such as NaCl, Na2S2O5, Na2SO4, and KCl were investigated in order to decrease the leaching duration. The results showed that the additives accelerated the leaching kinetics and achieved nearly the same nickel and cobalt extractions at the end of 4 h compared to the results obtained after 8 h without the additives. If the additives containing chlorine were used, it was determined that the iron extraction showed no increase, although both the nickel and cobalt extractions increased.
Słowa kluczowe
Rocznik
Strony
112--123
Opis fizyczny
Bibliogr. 19 poz., rys., tab.
Twórcy
autor
  • Istanbul Technical University, Mining Faculty, Mineral Processing Engineering Department, Istanbul, Turkey
autor
  • Istanbul Technical University, Mining Faculty, Mineral Processing Engineering Department, Istanbul, Turkey
Bibliografia
  • BUYUKAKINCI E., TOPKAYA Y.A., 2009, Extraction of nickel from lateritic ores at atmospheric pressure with agitation leaching, Hydrometallurgy, 97, 33-38.
  • CHANDER S., 1982, Atmospheric pressure leaching of nickeliferous laterites in acidic media, Transactions of the Indian Institute of Metals, 35, 366-371.
  • CHANG Y.F., ZHAI X.J., LI B.C., FU Y., 2010, Removal of iron from acidic leach liquor of lateritic nickel ore by goethite precipitate, Hydrometallurgy, 101, 84-87.
  • CHONG S., HAWKER W., VAUGHAN J., 2013, Selective reductive leaching of oxidised cobalt containing residue, Minerals Engineering, 54, 82-87.
  • DALVI A., BACON G., OSBORNE R.C., 2004, The Past and the Future of Nickel Laterites, PDAC International Convention, Trade Show & Investors Exchange.
  • DAS G.K., ANAND S., DAS R.P., MUIR D.M., SENANAYAKE G., SINGH P., HEFTER G., 1997, Acid leaching of nickel laterites in the presence of sulphur dioxide at atmospheric pressure, In: Cooper, W.C., Mihaylov, I. (Eds.), Proceedings of the Nickel–Cobalt 97 International Symposium: Hydrometallurgy and Refining of Nickel and Cobalt, Vol. 1.Canadian Institute of Mining Metallurgy and Petroleum, pp. 471-488.
  • DAS G.K., DE LANGE J.A.B., 2011, Reductive atmospheric acid leaching of West Australian smectitic nickel laterite in the presence of sulphur dioxide and copper (II), Hydrometallurgy, 105, 264-269.
  • JOHNSON J.A., MCDONALD R.G., WHITTINGTON B.I., QUAN L.P., MUIR D.M., 2002, Process water salinity effects in the pressure acid leaching of Cawse nickel laterite ore, In: Peek E., Van Weert G. (Eds.), Chloride Metallurgy 2002, 1.Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, pp. 339-354.
  • JOHNSON J.A., WHITTINGTON B.I., 2004, Effect of ammonium, sodium and potassium sulphates and chlorides in the pressure acid leaching of Western Australian nickel laterite ores, In: Collins M.J., Papangelakis V.G. (Eds.), Pressure Hydrometallurgy 2004. Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, pp. 199-214.
  • JOHNSON J.A., CASHMORE B.C., HOCKRIDGE R.J., 2005, Optimization of nickel extraction from laterite ores by high pressure acid leaching with addition of sodium sulphate, Minerals Engineering, 18, 1297-1303.
  • KAYA S., TOPKAYA Y.A., 2011, High pressure acid leaching of a refractory lateritic nickel ore, Minerals Engineering, 24, 1188-1197.
  • KRAUSE E., SINGHAL A., BLAKEY B.C., PAPANGELAKIS V.G., GEORGIOU D., 1997, Sulphuric acid leaching of nickeliferous laterites, In: Cooper, W.C., Mihaylov, I. (Eds.), Proc. Nickel–Cobalt 97 International Symposium, 1.Canadian Institute of Mining, Metallurgy and Petroleum, Montreal, pp. 441-458.
  • LOVEDAY B.K., 2008, The use of oxygen in high pressure acid leaching of nickel laterites, Minerals Engineering, 21, 533–538.
  • MCDONALD R.G., WHITTINGTON B.I., 2008, Atmospheric acid leaching of nickel laterites review Part I. Sulphuric acid technologies, Hydrometallurgy, 91, 35-55.
  • MWEMA M.D., MPOYO M., KAFUMBILA K., 2002, Use of sulfur dioxide as reducing agent in cobalt leaching at Shituru hydrometallurgical plant, Journal of the South African Institute of Mining and Metallurgy, (January/February), 1-4.
  • NEUDORF D., 2007, Atmospheric Leaching Forum, ALTA 2007 Nickel/Cobalt 12. ALTA Metallurgical Services, Melbourne. pp.5.
  • SCHWERTMANN U., 1991, Solubility and dissolution of iron oxides, Plant and Soil 130, 1-25.
  • WHITTINGTON B.I., MCDONALD R.G., JOHNSON J.A., MUIR D.M., 2003, Pressure acid leaching of arid region nickel laterite ore Part I. Effect of water quality, Hydrometallurgy, 70, 31-46.
  • WHITTINGTON B.I., JOHNSON J.A., 2005, Pressure acid leaching of arid-region nickel laterite ore. Part III: Effect of process water on nickel losses in the residue, Hydrometallurgy, 78, 256-263.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą nauki
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b2635359-2316-4871-8b40-a32122c50dc5
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