CVD diamond layers for electrochemistry

• Autorzy: Kowalska M. , Fabisiak K. , Wrzyszczyński A. , Banaszak A. , Szybowicz M. , Paprocki K. , Bała W , Bylicki F

Identyfikatory

DOI

10.2478/s13536-014-0211-3

• Języki publikacji: EN

Abstrakty

EN

Diamond electrodes of different morphologies and qualities were manufactured by hot filament chemical deposition (HF CVD) techniques by changing the parameters of diamond growth process. The estimation of diamond quality and identification of different carbon phases was performed by Raman spectroscopy measurements. The effect of diamond quality and amorphous carbon phase content on the electrochemical response of an obtained diamond electrode in 0.5 M H2SO4 as supporting electrolyte was investigated by cyclic voltammetry with [Fe(CN)6]4−/3− as a redox probe. The kinetic parameters such as catalytic reaction rate constant k0 and electron transfer coefficient α were determined. The obtained results show that the analytical performance of undoped diamond electrodes can be implemented just by the change of diamond layers quality.

Słowa kluczowe

EN

cyclic voltammetry; Raman spectroscopy; undoped diamond layer; amorphous carbon phase

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2014
• Tom: Vol. 32, No. 3
• Strony: 475--480
• Opis fizyczny: Bibliogr. 16 poz., rys., wykr., tab.

Twórcy

autor

Kowalska M.

• Faculty of Chemical Technology and Engineering, University of Technology and Life Sciences, Seminaryjna 3, 85-326 Bydgoszcz, Poland

autor

Fabisiak K.

• Institute of Physics, Kazimierz Wielki University, Powstancow Wielkopolskich 2, 85-090 Bydgoszcz, Poland

autor

Wrzyszczyński A.

• Faculty of Chemical Technology and Engineering, University of Technology and Life Sciences, Seminaryjna 3, 85-326 Bydgoszcz, Poland

autor

Banaszak A.

• Institute of Physics, Kazimierz Wielki University, Powstancow Wielkopolskich 2, 85-090 Bydgoszcz, Poland

autor

Szybowicz M.

• Institute of Physics, Kazimierz Wielki University, Powstancow Wielkopolskich 2, 85-090 Bydgoszcz, Poland
• Faculty of Technical Physics, Poznan University of Technology, Nieszawska 13A, 60-965 Poznan, Poland

autor

Paprocki K.

• Institute of Physics, Kazimierz Wielki University, Powstancow Wielkopolskich 2, 85-090 Bydgoszcz, Poland

autor

Bała W

• Institute of Physics, Kazimierz Wielki University, Powstancow Wielkopolskich 2, 85-090 Bydgoszcz, Poland

autor

Bylicki F

• Institute of Physics, Kazimierz Wielki University, Powstancow Wielkopolskich 2, 85-090 Bydgoszcz, Poland

Bibliografia

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