Structural analysis and dielectric relaxation mechanism of conducting polymer/volcanic basalt rock composites

• Autorzy: Bulgurcuoğlu Ayşe Evrim , Karabul Yaşar , Kiliç Mehmet , Özdemir Zeynep Güven , Erdönmez Seda , Misirlioğlu Banu Süngü , Okutan Mustafa , İçelli Orhan

Identyfikatory

DOI

10.2478/msp-2019-0042

• Języki publikacji: EN

Abstrakty

EN

In this work, polypyrrole and polythiophene conducting polymers (CPs) have been synthesized and doped with volcanic basalt rock (VBR) in order to improve their dielectric properties for technological applications. The structure and morphology of the composites with different VBR doping concentrations were characterized by FT-IR and SEM analyses. The best charge storage ability was achieved for maximum VBR doping concentration (50.0 wt.%) for both CPs. Dielectric relaxation types of the composites were determined as non-Debye type due to non-zero absorption coefficient and observation of semicircles whose centers were below Z′ axis at the Nyquist plots. It was also ascertained that VBR doping makes the molecular orientation easier than for non-doped samples and reduced energy requirement of molecular orientation. In addition, AC conductivity was totally masked by DC conductivity for all samples at low frequency.

Słowa kluczowe

EN

composite materials; polypyrrole; polythiophene; volcanic basalt rock; dielectric spectroscopy

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2019
• Tom: Vol. 37, No. 3
• Strony: 353--363
• Opis fizyczny: Bibliogr. 48 poz., tab., rys.

Twórcy

autor

Bulgurcuoğlu Ayşe Evrim

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

autor

Karabul Yaşar

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

autor

Kiliç Mehmet

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

autor

Özdemir Zeynep Güven

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

autor

Erdönmez Seda

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

autor

Misirlioğlu Banu Süngü

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

autor

Okutan Mustafa

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

autor

İçelli Orhan

• Department of Physics, Yildiz Technical University, 34220 ˙Istanbul, Turkey

Bibliografia

• [1] Ates M. Mat. Sci. Eng. C-Mater. 33 (2013) 1853.
• [2] Snook G.A. Kao P. Best A.S. J. Power Sources 196 (2011) 1.
• [3] Das T.K. Prusty S. Polym.-Plast. Technol. 51 (2012) 1487.
• [4] Long Y-Z. Li M-M. Gu C. Wan M. Duvail J-L. Liu Z. Fan Z. Prog. Polym. Sci. 36 (2011) 1415.
• [5] Balint R. Cassidy N.J. Cartmell S.H. Acta Biomater. 10 (2014) 2341.
• [6] Yakuphanoglu F. Yahia I. Senkal B. Sakr G. Farooq W. Synthetic Met. 161 (2011) 817.
• [7] Bai Y-M. Qiu P. Wen Z-L. Han S-C. J. Alloy. Compd. 508 (2010) 1.
• [8] Dhibar S. Bhattacharya P. Hatui G. Das C. J. Alloy. Compd. 625 (2015) 64.
• [9] Ke R. Zhang X. Wang L. Zhang C. Zhang S. Mao C. Niu H. Song J. Jin B. Tian Y. J. Alloy. Compd. 622 (2015) 1027.
• [10] Li Y. Chen G. Li Q. Qiu G. Liu X. J. Alloy. Compd. 509 (2011) 4104.
• [11] Liu P. Huang Y. Wang L. Zhang W. J. Alloy. Compd. 573 (2013) 151.
• [12] Shen J. Chen K. Li L. Wang W. Jin Y. J. Alloy. Compd. 615 (2014) 488.
• [13] Varshney S. Singh K. Ohlan A. Jain V. Dutta V. Dhawan S. J. Alloy. Compd. 538 (2012) 107.
• [14] Wang Q. Zheng L. Chen Y. Fan J. Huang H. Su B. J. Alloy. Compd. 637 (2015) 127.
• [15] Azadmanjiri J. Hojati-Talemi P. Simon G. Suzuki K. Selomulya C. Polym. Eng. Sci. 51 (2011) 247.
• [16] Erdoğan M.K. Karakişla M. Saçak M. J. Macromol. Sci. A 49 (2012) 473.
• [17] Gupta A. Varshney S. Goyal A. Sambyal P. Gupta B.K. Dhawan S. Mater. Lett. 158 (2015) 167.
• [18] Najar M.H. Majid K. J. Mater. Sci.-Mater. El. 26 (2015) 6458.
• [19] Le Maitre R.W. Streckeisen A. Zanettin B. Le Bas M. Bonin B. Bateman P. Igneous Rocks: a Classification and Glossary of Terms: Recommendations of the International Union of Geological Sciences Subcommission on the Systematics of Igneous Rocks Cambridge University Press New York 2005.
• [20] Çetin A. Okutan M. Içelli O. Yalçin Z. San S. Kibar R. Pesen E. Vacuum 97 (2013) 75.
• [21] El-Shennawi A.W.A. Mandour M.A. Morsi M.M. Abdel-Hameed S.A. J. Am. Ceram. Soc. 82 (1999) 1181.
• [22] Yeşilkaya S. Özdemir Z.G. Canli N.Y. Yildiz A. Içelli O. Okutan M. Compos. Part B-Eng. 95 (2016) 488.
• [23] Kang Y-Q. Cao M-S. Yuan J. Zhang L. Wen B. Fang X-Y. J. Alloy. Compd. 495 (2010) 254.
• [24] Basavaraja C. Veeranagouda Y. Lee K. Vishnuvardhan T. Pierson R. J. Polym. Res. 17 (2010) 233.
• [25] Maity A. Sinha Ray S. Macromol. Rapid Comm. 29 (2008) 1582.
• [26] Nicho M. Hu H. Sol. Energ. Mat. Sol. C. 63 (2000) 423.
• [27] Gao F. Hou X. Wang A. Chu G. Wu W. Chen J. Zou H. Particuology 26 (2016) 73.
• [28] Karim M.R. Lee C.J. Chowdhury A.S. Nahar N. Lee M.S. Mater. Lett. 61 (2007) 1688.
• [29] Yang C. Liu P. Guo J. Wang Y. Synthetic Met. 160 (2010) 592.
• [30] Gök A. Omastová M. Yavuz A.G. Synthetic Met. 157 (2007) 23.
• [31] Karim M.R. Lee C.J. Lee M.S. J. Polym. Sci. Pol. Chem. 44 (2006) 5283.
• [32] Lu M-D. Yang S-M. Synthetic Met. 154 (2005) 73.
• [33] Udum Y.A. Pekmez K. Yildiz A. Eur. Polym. J. 41 (2005) 1136.
• [34] Gnanakan S.R.P. Rajasekhar M. Subramania A. Int. J. Electrochem. Sc. 4 (2009) 1289.
• [35] Çinar M. Kiliç M. Karabul Y. Canli N.Y. Alkan Ü. Okutan M İçelli O. J. Nanoelectron. Optoe. 11 (2016) 477.
• [36] Hong X. Chung D. Carbon 91 (2015) 1.
• [37] Panwar V. Park J.O. Park S.H. Kumar S. Mehra R. J. Appl. Polym. Sci. 115 (2010) 1306.
• [38] Blakemore J.S. Solid State Physics Cambridge University Press New York 1985.
• [39] Çavdar Ş. Koralay H. Tuğluoğlu N. Günen A. Supercond. Sci. Tech. 18 (2005) 1204.
• [40] Haase W. Wróbel S. Relaxation phenomena: liquid crystals magnetic systems polymers high-Tc superconductors metallic glasses Springer New York 2003.
• [41] Meller A. Gmelin Handbook of Inorganic and Organometallic Chemistry. 4th Supplement Volume 3a: B Boron Compounds The System Boron-Nitrogen Springer Berlin 1991.
• [42] Misirlioglu B. Karaman F. Ugraskan V. Serin M. Yazici O. J. Optoelectron. Adv. M. 17 (2015) 1874.
• [43] Jonscher A. J. Mater. Sci. 16 (1981) 2037.
• [44] Migahed M. Ishra M. Fahmy T. Barakat A. J. Phys. Chem. Solids 65 (2004) 1121.
• [45] Psarras G. Manolakaki E. Tsangaris G. Compos. Part A-Appl. S. 34 (2003) 1187.
• [46] Elliott S. Adv. Phys. 36 (1987) 135.
• [47] Ghosh A. Phys. Rev. B 41 (1990) 1479.
• [48] Tiwari T. Srivastava N. Srivastava P. Int. J. Electrochem. 2013 2013.

Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).