Reagent Removal of Heavy Metals From Waters of Coal Mines and Spoil Tips of the Lviv-Volyn Industrial Mine Region

• Autorzy: Mazurak Oksana , Solovodzinska Irina , Mazurak Andriy , Gryncyhshyn Nataliia

Identyfikatory

DOI

10.12911/22998993/110829

• Języki publikacji: EN

Abstrakty

EN

The article substantiates the efficiency of using chemical (reagent) technologies for the purification of industrial water from mines and spoil tips from heavy metals-toxicants and reducing their ecological hazard. The ecological risk indices of toxicants and their proportion in the overall level of ecological danger of the investigated object were presented. The results of experimental studies, interaction of comparative qualitative indicators of removal of heavy metal ions by inorganic reagents – calcium carbonate and sodium hydroxide were provided. It is shown that the solution of the ecological problem concerning the reduction of the toxicity level of subterminal waters of mines is their treatment with fine calcium carbonate CaCO₃ that converts the heavy metal ions into hardly soluble basic carbonates or heavy metal hydroxides. Positive results concerning the efficiency of the subterminal water treatment of the «Velikomostovskaya» mine of the Chervonograd mining area by calcium carbonate were identified. That indicates a significant reduction of the ecological hazard indicator of the treated wastewater. The content of ions of most heavy metals, which precipitate in the form of basic carbonates at values close to pH = 8.5, was significantly reduced.

Słowa kluczowe

EN

ecological hazard; heavy metals; toxicant; mine; calcium carbonate; sodium hydroxide

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2019
• Tom: Vol. 20, nr 8
• Strony: 50--59
• Opis fizyczny: Bibliogr. 27 poz., rys., tab.

Twórcy

autor

Mazurak Oksana

• Department of Ecology, Lviv National Agrarian University 1, V.Velykogo St., 30831 Dubliany, Lviv region, Ukraine

autor

Solovodzinska Irina

• Department of Ecology, Lviv National Agrarian University 1, V.Velykogo St., 30831 Dubliany, Lviv region, Ukraine

autor

Mazurak Andriy

• Department of Building and Architecture, Lviv National Agrarian University 1, V.Velykogo St., 30831 Dubliany, Lviv region, Ukraine

autor

Gryncyhshyn Nataliia

• Department of ecological safety, Lviv State University of Life Safety, 35, Kleparivska St., 79007, Lviv, Ukraine

Bibliografia

• 1. Adamenko Ya.O. et al. 2016. Territorial norm of quality of hydro eco-systems of protected territories. Hydrobiological Journal. Begell House.
• 2. Borovikov V. P. Ivchenko G. I. 1999. Forecasting in the STATISTICA system in the WINDOWS environment. Finance and Statistics. Moscow, 382.
• 3. Buchatska G. M. 2009. Hydrogeological conditions and hydrogeochemical zonation of Lviv-Volyn coal basin. Visnyk of Lviv University. Geological series, Lviv, 23. 175–183.
• 4. Dlamini C., Fadiran A. and Thwala J. 2013. A Study of Environmental Assessment of Acid Mine Drainage in Ngwenya, Swaziland, Journal of Environmental Protection, Vol. 4 (11B), 2013, 20–26.
• 5. Dong J. et al. 2011. Assessing the Concentration and Potential Dietary Risk of Heavy Metals in Vegetables at a Pb/Zn Mine Site. China Environ. Earth Sci., 64, 1317–1321.
• 6. Grishko V.M. et al. 2012. Heavy metals: soil retrieval, translocation in plants and environmental safety. Donbass, Donetsk, 304.
• 7. Gruszecka-Kosowska A., Baran P., Wdowin M., Franus W. 2017. Waste dolomite powder as an adsorbent of Cd, Pb(II), and Zn from aqueous solutions. Environ Earth Sci, 76(521), 1–12.
• 8. Guidelines for the sampling of sewage. Part 10. DSTU ISO 5667–10–2001. Derzhspozhyvstandart of Ukraine, Kyiv, 2006, 42.
• 9. Guiding normative documents of the Ministry of Environmental Protection of Ukraine, which regulate methods of determining the parameters of composition and properties of natural and sewage. GND 211.1.4. Derzhspozhyvstandart of Ukraine. 2006, Kyiv, 246.
• 10. Keng P. S.et al. 2014. Removal of Hazardous Heavy Metals From Aqueous Environment by Low-Cost Adsorption Materials. Civil and Environmental Engineering Faculty Publications. 100 s.
• 11. Knysh I.B., Karabin V. 2010. Geochemistry of trace elements in the rocks of the waste heap of the Mezhyrichanska reservoir of the Lviv-Volyn Carboniferous Basin. Geology and geochemistry of combustible minerals, 3–4 (152–153), 85–101.
• 12. Matlock M.M, Howerton B.S, Atwood D.A. 2002. Chemical precipitation of heavy metals from acid mine drainage. Water Res, 36, 4757–4764.
• 13. Myung J. 2008. Heavy Metal Concentrations in Soils and Factors Affecting Metal Uptake by Plants in the Vicinity of a Korean Cu-W Mine. Areas of Misurata. Libya International Journal of Analytical Chemistry, Volume 2013. http://www.mdpi.org.
• 14. Nabivanets B. Y. 1996. Analytical chemistry of the environment. Lybid, Kyiv, 304.
• 15. Nemati M., Harison STL. 2000. Comparative study on thermophilic and mesophilic bioxidation of ferrous iron. Miner Eng., 13, 19–24.
• 16. Pestrikov S.V. et al. 2009. Geo-ecological technologies: reagent purification of metal-containing sub-water waters of the spent career Kuly-YurtTau. Engineering ecology, 3, 44–52.
• 17. Rene E. et al. 2017. Sustainable heavy metal remediation. V. 2: сase studies. Cham, Switzerland: Springer. 278 p.
• 18. Samchuk A. 2009. Spatial-temporal peculiarities of the distribution of heavy metals in anthropogenized Polissya landscapes: Ukrainian Geographical Journal, 1, 19–24.
• 19. Safarova V. at al. 2011. Methods of Sample Preparation of Soil, Bottom Sediments, and Solid Wastes for Atomic Absorption Determination of Heavy Metals. Inorganic Materials, 2011, Vol. 47(14), 1512–1517.
• 20. Standard methods for the examination of water and wastewater. Washington: APHA-AWWA-WEF, 2005. 21.
• 21. Thiruvenkatachari, R., Vigneswaran, S., & Naidu, R. 2008. Permeable reactive barrier for groundwater remediation. Journal of Industrial and Engineering Chemistry, 14 (2), 145–156.
• 22. Tobylko V. 2016. Development of sorption technologies for protecting water against contamination by heavy metals and radionuclides: diss. Cand. tech Sciences: 21.06.01. Kyiv. 184.
• 23. Volkov A., Zharsky I. Big chemical guide. Minsk: Modern School, 2005, 608.
• 24. Voytovich S.P. 2015. Hydrogeochemical zoning of the Chervonograd mining area: Collective. sciences works Kyiv. UkrDGRI. 2, 109–124.
• 25. Wang. J., & Chen C. 2009. Biosorbents for heavy metals removal and their future. Biotechnology Advances, 27 (2), 195–226.
• 26. Zasidko I. et al. 2019. Complex technology of sewage purification from heavy-metal іons by natural adsorbents and utilization of sewage sludge. Journal of Ecological Engineering, 20(5), 209–216.
• 27. Zhou, H. and Guo, X. (2015). Soil Heavy Metal Pollution. Evaluation around Mine Area with Traditional and Ecological Assessment Methods. Journal of Geoscience and Environment Protection, 3, 28–33.