Removal of Rhodamine B from aqueous solution by ZnFe2O4 nanocomposite with magnetic separation performance

Konicki, W.; Siber, D.; Narkiewicz, U.

doi:10.1515/pjct-2017-0069

Artykuł - szczegóły

Tytuł artykułu

Removal of Rhodamine B from aqueous solution by ZnFe2O4 nanocomposite with magnetic separation performance

Autorzy

Konicki W. , Siber D. , Narkiewicz U.

Treść / Zawartość

Pełne teksty:

Polish Journal of Chemical Technology_4_2017_Konicki.pdf

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Identyfikatory

DOI

10.1515/pjct-2017-0069

Warianty tytułu

Języki publikacji

Abstrakty

Magnetic ZnFe₂ O₄ nanocomposite (ZnFe-NC) was used as an adsorbent for the removal of Rhodamine B (RB) from aqueous solution. The synthesized nanocomposite was characterized by XRD, SEM, HRTEM, BET and FTIR. The effects of various parameters such as initial RB concentration (5–25 mg L⁻¹ ), pH (3.4–11.1) and temperature (20–60°C) were investigated. The adsorption capacity at equilibrium increased from 5.02 to 9.83 mg g⁻¹ , with the increase in the initial concentration of RB from 5 to 25 mg L⁻¹ at pH 7.0 and at 20°C. The experimental results indicated that the maximum RB removal could be attained at a solution pH of 4.4 and the adsorption capacity obtained was 6.02 mg g⁻¹ . Kinetic adsorption data were analyzed using the pseudo-first-order kinetic model, the pseudo-second-order model and the intraparticle diffusion model. The adsorption kinetics well fitted using a pseudo-second-order kinetic model. The experimental isotherm data were analyzed using two isotherm models, namely, Langmuir and Freundlich. The results revealed that the adsorption behavior of the RB onto ZnFe-NC fitted well with the Langmuir isotherm model. In addition, various thermodynamic parameters, such as standard Gibbs free energy (ΔG°), enthalpy (ΔH°) and entropy (ΔS°) have been calculated.

Słowa kluczowe

adsorption Rhodamine B ZnFe2O4 kinetics thermodynamics

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

2017

Tom

Vol. 19, nr 4

Strony

65--74

Opis fizyczny

Bibliogr. 59 poz., rys., tab.

Twórcy

autor

Konicki W.

w.konicki@am.szczecin.pl

Maritime University of Szczecin, Department of Environmental Protection, Henryka Pobożnego 11, 70-507 Szczecin, Poland

autor

Siber D.

West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, Faculty of Chemical Technology and Engineering, ul. Pułaskiego 10, Szczecin 70-322, Poland

autor

Narkiewicz U.

West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, Faculty of Chemical Technology and Engineering, ul. Pułaskiego 10, Szczecin 70-322, Poland

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-b188bfa8-4b26-41c4-b4f2-e17b7bb36d96