Kinetics of acetic acid – methanol esterification reaction over sulfonic acid-functionalized mcf catalyst

• Autorzy: Maresz K. , Malinowski J. J. , Odrozek K. , Koreniuk A. , Mrowiec-Białoń J. , Jarzębski A. B.

Warianty tytułu

PL

Kinetyka reakcji estryfikacji kwasu octowego metanolemwobecności katalizatora mcf funkcjonalizowanego grupami kwasowymi

• Języki publikacji: EN

Abstrakty

EN

The esterification of acetic acid with methanol was studied in the presence of heterogeneous acidic catalyst - sulfonic acid functionalized silica mesoporous cellular foam (MCF) in order to determine its potentials. The effects of catalyst loading, molar ratio of substrates and temperature on the reaction rate were discussed. The kinetic model for this reaction was proposed.

PL

Przedstawiono wyniki badań kinetycznych reakcji estryfikacji kwasu octowego metanolem w obecności stałego kwasowego katalizatora – mezoporowatowego materiału krzemionkowego o strukturze piankowej, funkcjonalizowanego grupami sulfonowymi. Określono wpływ ilości katalizatora, stosunku molowego substratów oraz temperatury na szybkość reakcji. Zaproponowano model kinetyczny reakcji przeprowadzonej w obecności otrzymanego katalizatora.

Słowa kluczowe

PL

analiza kinetyczna; estryfikacja; moduł Thielego

• Wydawca: Instytut Inżynierii Chemicznej Polskiej Akademii Nauk
• Czasopismo: Prace Naukowe Instytutu Inżynierii Chemicznej Polskiej Akademii Nauk
• Rocznik: 2013
• Tom: nr 17
• Strony: 35--46
• Opis fizyczny: Bibliogr. 28 poz., rys., tab.

Twórcy

autor

Maresz K.

• Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice

autor

Malinowski J. J.

• Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice

autor

Odrozek K.

• Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice

autor

Koreniuk A.

• Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice

autor

Mrowiec-Białoń J.

• Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice
• Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice

autor

Jarzębski A. B.

• Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice
• Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice

Bibliografia

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