PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Kinetics of acetic acid – methanol esterification reaction over sulfonic acid-functionalized mcf catalyst

Treść / Zawartość
Identyfikatory
Warianty tytułu
PL
Kinetyka reakcji estryfikacji kwasu octowego metanolemwobecności katalizatora mcf funkcjonalizowanego grupami kwasowymi
Języki publikacji
EN
Abstrakty
EN
The esterification of acetic acid with methanol was studied in the presence of heterogeneous acidic catalyst - sulfonic acid functionalized silica mesoporous cellular foam (MCF) in order to determine its potentials. The effects of catalyst loading, molar ratio of substrates and temperature on the reaction rate were discussed. The kinetic model for this reaction was proposed.
PL
Przedstawiono wyniki badań kinetycznych reakcji estryfikacji kwasu octowego metanolem w obecności stałego kwasowego katalizatora – mezoporowatowego materiału krzemionkowego o strukturze piankowej, funkcjonalizowanego grupami sulfonowymi. Określono wpływ ilości katalizatora, stosunku molowego substratów oraz temperatury na szybkość reakcji. Zaproponowano model kinetyczny reakcji przeprowadzonej w obecności otrzymanego katalizatora.
Słowa kluczowe
Rocznik
Tom
Strony
35--46
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
autor
  • Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice
  • Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice
autor
  • Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice
autor
  • Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice
  • Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice
  • Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice
  • Institute of Chemical Engineering Polish Academy of Sciences Gliwice, Baltycka 5, 44-100 Gliwice
  • Department of Chemical Engineering and Process Design, Faculty of Chemistry, Silesian University of Technology, Strzody 7, 44-100 Gliwice
Bibliografia
  • [1] RUSSBUELDT B.M.E., HOELDERICH W.F., New sulfonic acid ion-exchange resins for the preestrification of different oils and fats with high content of free fatty acids. Appl. Catal.A: Gen. 2009, 362, 47.
  • [2] KOMOŃ T., NIEWIADOMSKI P., ORACZ P., JAMRÓZ M.E., Esterification of acrylic acid with 2-ethylhexan-1-ol: Thermodynamic and kinetic study. Appl. Catal. A: Gen. 2013, 451, 127.
  • [3] PETERS T.A., BENES N.E., HOLMEN A., KEURENTJES J.T.F., Comparison of commercial solid acid catalysts for the esterification of acetic acid with butanol. Appl. Catal. A: Gen. 2006, 297, 182.
  • [4] KIRUMAKKI S.R., NAGARAJU N., NARAYANAN S., A comparative esterification of benzyl alkohol with acetic acid over zeolites Hβ, HY and HZSM5. Appl. Catal. A: Gen. 2004, 273, 1.
  • [5] BEDARD J., CHIANG H., BHAN A.. Kinetics and mechanism of acetic acid esterification with ethanol on zeolites, J. Catal. 2012, 290, 210.
  • [6] ZHU S., ZHU Y., GAO X., MO T., ZHU Y., LI Y., Production of bioadditives from glicerol esterification over zirconia supported heteropolyacids. Bioresour. Technol. 2013, 130, 45.
  • [7] POSADA J.A., CARDONA C.A., GIRALDO O., Comparison of acid sulfonic mesostructured silicas for 1-butylacetate synthesis. Mater. Chem. Phys. 2010, 121, 215 .
  • [8] ABBASI A., MAHJOUB A.R., BADIEI A.R., Fast and easy preparation of a novel highly acidic sulfonic-functionalized SBA-1 cubic mesoporous catalyst and its application in the esterification of palmitic acid. Mater. Sci-Poland. 2010, 28, 617 .
  • [9] TANG Y., MIAO S., SHANKS B.H., ZHENG X., Bifunctional mesoporous organic-inorganic hybryd silica for combined one-step hydrogenation/esterification. Appl. Catal. A: Gen. 2010, 375, 310.
  • [10] BANDYOPADHYAY M., SHIJU N.R., BROWN D.R., MCM-48 as a support for sulfonic acid catalysts. Catal. Commun. 2010, 11, 660.
  • [11] MARESZ K., MALINOWSKI J. J., MROWIEC-BIAŁOŃ J ., JARZĘBSKI A.B., Wpływ struktury nośnika na właściwości katalityczne mezoporowatych krzemionek funkcjonalizowanych grupami arenosulfonowymi. Przem. Chem. 2012, 91, 2061.
  • [12] SCHMIDT-WINKEL P., LUKENS W. W., YANG P., MARGOLESE D. I., LETTOW J. S., YING J. Y., STUCKY G. D. Microemulsion templating of siliceous mesostructured cellular foams with welldefined ultralarge mesopores. Chem. Mater. 2000, 12, 686.
  • [13] SCHMIDT-WINKEL P., GLINKA C. J., STUCKY G. D. Microemulsion templates for mesoporous silica. Langmuir 2000, 16, 356.
  • [14] SZYMAŃSKA K., BRYJAK J.,MROWIEC-BIAŁOŃ J., JARZĘBSKI A.B., Application and properties od siliceous mesostructured cellular foams as enzyme carriers to obtain efficient catalysts, Micropor. Mesopor. Mater. 2007, 99, 167.
  • [15] XUE P., XU F., XU L. Epoxy-functionalized mesostructured cellular foams as effective suport for covalent immobilization of penicillin G acylase, Appl. Surf. Sci. 2008, 255, 1625.
  • [16] SZYMAŃSKA K., BRYJAK J., JARZĘBSKI A.B., Immobilization of invertase on mesoporous silicas to obtain hyper active biocatalysts. Top. Catal. 2009, 53, 1030.
  • [17] SHAKERI M., KAWAKAMI K. Enhancement of Rhizopus oryzae lipase activity immobilized on alkyl-functionalized spherical mesocellular foam: Influence of alkyl chain length. Micropor. Mesopor. Mater. 2009, 118, 115.
  • [18] KIM H., JUNG J. C., YEOM S. H., LEE K.-Y., YI J., SONG I. K., Immobilization of a heteropolyacid catalyst on the aminopropyl-functionalized mesostructured cellular foam (MCF) silica, Mat. Res. Bull. 2007, 42, 2132.
  • [19] KANNAN K., JASRA R. V., Immobilization of alkaline serine endopeptidase from Bacillus licheniformis on SBA-15 and MCF by surface covalent binding. J. Mol. Catal. B: Enzymatic 2009, 56, 34.
  • [20] KIM H., JUNG J. C., KIM P., YEOM S. H., LEE K.-Y., SONG I. K., Preparation of H3PMo12O40 catalyst immobilized on surface modified mesostructured cellular foam (SM-MCF) silica and its application to the ethanol conversion reaction. J. Mol. Catal. A: Chem. 2006, 259, 150.
  • [21] MROWIEC-BIAŁOŃ J., MARESZ K., MALINOWSKI J. J., JARZĘBSKI A. B., Organosulfonic acid functionalised silica mesostructured cellular foams – efficient catalysts for reactions of esterification. Chem. Proc. Eng. 2008, 29, 701.
  • [22] SZARAWARA J., SKRZYPEK J., GAWDZIK A., Podstawy inżynierii reaktorów chemicznych. 1991 WNT Warszawa.
  • [23] PETERS T. A., BENES N. E., HOLMEN A., KEURENTIJES J. T. F., Comparison of commercial solid catalysts for the esterification of acetic acid with butanol. Appl. Catal. A: General 2006, 297, 182.
  • [24] LIU Q. L., CHEN H. F., Modeling of esterification of acetic acid with n-butanol in the presence of Zr(SO4)2.4H2O coupled pervaporation. J. Membrane Sci., 2002, 196, 171.
  • [25] KIRUMAKKI S. R., NAGARAJU N., CHARY K. V. R., Esterification of alcohols with acetic acid over zeolitem Hβ, HY and HZSM5. Appl. Catal. A; Gen., 2006, 299, 185.
  • [26] LIU Y., LOTERO E., GOODWIN JR. J. G., A comparison of the esterification of acetic acid with methanol using heterogeneous versus homogeneous acid catalysis. J. Catal., 2006, 242, 278.
  • [27] DASH S., PARIDA K. M., Esterification of acetic acid with n-butanol over manganese nodule leached residue. J. Mol. Catal. A: Chem. 2007, 266, 88.
  • [28] HELMINEN J., PAATERO E., Inorganic solid supported polymer acid catalyst – Sulfonated polystyrene grafted silica gel in liquid phase esterification. React. Funct. Polym. 2006, 66, 1021.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b0a935e0-578f-4c5c-856d-4aab086116d6
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.