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The flotation separation of fluorite and calcite poses one of the most difficult problems in the mineral processing industry. In particular, the surface homogenization of fluorite and calcite worsens the result of fluorite flotation. In this paper, time of flight secondary ion mass spectrometry and principal component analysis are used to study the surface homogenization of fluorite and calcite during grinding and in solution using X-ray photoelectron spectroscopy, infrared spectroscopy, and solution chemical calculations. The results show that the surface composition of calcite converts to fluorite after mixed grinding and that the surface composition of fluorite also converts to calcite in clarified calcite solution.
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Tom
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250--258
Opis fizyczny
Bibliogr. 22 poz., rys., tab., wykr.
Twórcy
autor
- Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China 2 State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization , Kunming 650093,Yunnan, China
autor
- Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China 2 State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization , Kunming 650093,Yunnan, China
autor
- Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China 2 State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization , Kunming 650093,Yunnan, China
autor
- Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China 2 State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization , Kunming 650093,Yunnan, China
autor
- Faculty of Land Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China 2 State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization , Kunming 650093,Yunnan, China
Bibliografia
- AROCENA, J. M., GLOWA, K. R., 2000. Mineral weathering in ectomycorrhizosphere of subalpine fir (Abies lasiocarpa (Hook.) Nutt.) as revealed by soil solution composition. Forest Ecology & Management, 133(1-2), 61-70.
- BERMAN, E.S.F., WU, L., FORTSON, S.L., KULP, K.S., NELSON, D.O., WU, K.J., 2009. Chemometric and statistical analyses of ToF-SIMS spectra of increasingly complex biological samples. Surface & Interface Analysis, 41, 97-104.
- BRUCKARD, W. J., SPARROW, G. J., WOODCOCK, J. T., 2011. A review of the effects of the grinding environment on the flotation of copper sulphides. International Journal of Mineral Processing, 93(1-2), 1-13.
- DENG, J. S., WEN, S. M., WU, D. D., LIU, J., ZHANG, X. L., SHEN, H. Y., 2013. Existence and release of fluid inclusions in bornite and its associated quartz and calcite. International Journal of Minerals Metallurgy and Materials, 20(009), 815-822.
- GAO, Z., BAI, D., SUN, W., CAO, X., HU, Y., 2015. Selective flotation of scheelite from calcite and fluorite using a collector mixture. Minerals Engineering, 72, 23-26.
- GERSON, A. R., SMART, R. S. C., LI, J., KAWASHIMA, N., WEEDON, D., TRIFFETT, B., BRADSHAW, D., 2012. Diagnosis of the surface chemical influences on flotation performance: Copper sulfides and molybdenite. International Journal of Mineral Processing, 106-109(none), 16-30.
- HU, Y. H. (1989). Study on Solution Chemistry Calculation and Graphic Method and Flotation Behavior of Salt Minerals. Central South University of Technology,
- JIANG, W., GAO, Z., KHOSO, S. A., GAO, J., SUN, W., PU, W., HU, Y., 2018. Selective adsorption of benzhydroxamic acid on fluorite rendering selective separation of fluorite/calcite. Applied Surface ence, 435(MAR.30), 752-758.
- LIU, C., FENG, Q., ZHANG, G., CHEN, W., CHEN, Y., 2016. Effect of depressants in the selective flotation of scheelite and calcite using oxidized paraffin soap as collector. International Journal of Mineral Processing, 157, 210-215.
- LIU, C., ZHOU, M., XIA, L., FU, W., YANG, S., 2020. The utilization of citric acid as a depressant for the flotation separation of barite from fluorite. Minerals Engineering, 156, 106491.
- MARKOVSKI, J.S., MARKOVIĆ, D.D., ĐOKIĆ, V.R., MITRIĆ, M., MARINKOVIĆ, A.D., 2014. Arsenate adsorption on waste eggshell modified by goethite, α-MnO2 and goethite/α-MnO2. Chemical Engineering Journal, 237, 430-442.
- MILLER, J.D., HISKEY, J.B., 1972. Electrokinetic behavior of fluorite as influenced by surface carbonation. Journal of Colloid & Interface ence, 41(3), 567-573.
- MOULDER, J. F., 1992. Handbook of X-ray Photoelectron Spectroscopy, Physical Electronics Division, Perkin-Elmer Corporation, pp. 261
- NAKAMOTO, K., HUANG, D.R., 1986. Infrared and Raman spectra of inorganic and coordination compounds. Chemical Industry Press.
- PARK, J. W., MIN, H., KIM, Y. P., SHON, H. K., KIM, J., MOON, D. W., LEE, T. G., 2010. Multivariate analysis of ToF-SIMS data for biological applications. Surface & Interface Analysis, 41(8), 694-703.
- TIAN, J., XU, L., SUN, W., ZENG, X., FANG, S., HAN, H., HONG, K., HU, Y., 2019. Use of Al2(SO4)3 and acidified water glass as mixture depressants in flotation separation of fluorite from calcite and celestite. Minerals Engineering, 137, 160-170.
- TYLER, B. J., RAYAL, G., CASTNER, D. G., 2007. Multivariate analysis strategies for processing ToF-SIMS images of biomaterials. Biomaterials, 28(15), 2412-2423.
- PENG, W.J., ZHANG., L.Y., BAI, L.L., QIU, Y.S., 2014. Flotation research of a fluorite ore. Appl. Mech. Mater., 539, 781- 784.
- ZHANG, C., WEI, S., HU, Y., TANG, H., GAO, J., YIN, Z., GUAN, Q., 2017. Selective adsorption of tannic acid on calcite and implications for separation of fluorite minerals. Journal of colloid and interface ence, 512, 55.
- ZHOU, H., ZHANG, Y., TANG, X., CAO, Y., LUO, X., 2020. Flotation separation of fluorite from calcite by using psyllium seed gum as depressant. Minerals Engineering, 159, 106514.
- ZHOU, W., MORENO, J., TORRES, R., VALLE, H., SONG, S., 2013. Flotation of fluorite from ores by using acidized water glass as depressant. Minerals Engineering, 45, 142-145.
- ZHU, H., QIN, W., CHEN, C., CHAI, L., JIAO, F., JIA, W., 2018. Flotation separation of fluorite from calcite using polyaspartate as depressant. Minerals Engineering, 120, 80-86.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-b083902e-e1fa-4d52-a2a2-d5f139f66a21