Metody stosowane w usuwaniu związków smół z gazu otrzymanego ze zgazowania biomasy – praca przeglądowa

Wnukowski, M.

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Tytuł artykułu

Metody stosowane w usuwaniu związków smół z gazu otrzymanego ze zgazowania biomasy – praca przeglądowa

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Wnukowski M.

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Warianty tytułu

Methods used in tar removal from biomass gasification gas – a review

Języki publikacji

Abstrakty

Podstawowym problemem związanym ze zgazowaniem biomasy jest obecność związków smół w gazach procesowych. Zastosowanie gazu generatorowego w maszynach cieplnych, takich jak silniki wewnętrznego spalania czy turbiny, wymaga głębokiego oczyszczenia gazu. W tym celu stosuje się wiele metod charakteryzujących się różną skutecznością i stopniem skomplikowania.Należą do nich metody: mechaniczne, termiczne, plazmowe, katalityczne, pierwotne oraz mieszane. W artykule przedstawiono problematykę związaną z występowaniem smół w gazie generatorowym oraz opisano szeroki zakres metod stosowanych w celu ich usunięcia.

The main problem with the biomass gasification is the presence of tar compounds in the process gas. Use of the produced gas in thermal machines such as internal combustion engines or turbines requires deep gas cleansing. For this purpose, several methods, characterized by varying degrees of effectiveness and complexity, are applied, namely: mechanical, thermal, plasma, catalytic, primary and mixed methods. The article presents the problems connected with the presence of tar and describes a wide range of methods used to remove it.

Słowa kluczowe

biomasa zgazowanie smoły

biomass gasification tar

Wydawca

Mastermedia sp. z o.o.

Czasopismo

Archiwum Gospodarki Odpadami i Ochrony Środowiska

Rocznik

2016

Tom

Vol. 18, nr 2

Strony

17--34

Opis fizyczny

Bibliogr. 76 poz.

Twórcy

autor

Wnukowski M.

mateusz.wnukowski@pwr.wroc.pl

Politechnika Wrocławska; Zakład Kotłów, Spalania i Procesów Energetycznych, Wyb. Stanisława Wyspiańskiego 27, Wrocław 50-370 tel.:71 320 42 69

Bibliografia

1. IEA. World Energy Outlook 2006.Paris : International Energy Agency, 2006.
2. HH. Roger, A. Popescu. An Introduction to Energy. World energy assessment: energy and the challenge of sustainability. NowyYork : United Nations Development Programme, 2000.
3. Basu, P. Biomass Gasification and Pyrolysis Practical Design. Oxford : Elsevier, 2010.
4. Kaygusuz, K. Biomass as a Renewable Energy Source for Sustainable Fuels. 2009, Vol. 31, 6, pp. 535-545.
5. J.P.A. Neeft, H.A.M. Knoef, U. Zielke, K. Sjöström, P. Hasler, P.A. Simell, M.A. Dorrington, N. Abatzoglou, S. Deutch, C. Greil, G.J. Buffinga, C. Brage, M. Soumalainen. Guideline for Sampling an Analysis of Tar and Particles in Biomass Producer Gas, Version 3.1. 1999. Energy project EEN5-1999-00507 (tar protocol).
6. T.A. Milne, R.J. Evans, N. Abatzoglou. Biomass Gasifier Tars: Their Nature, Formation, and Conversion. Golden, Colorado : National Renewable Energy Laboratory, 1998.
7. S. Anis, Z.A. Zainala. Tar reduction in biomass producer gas via mechanical, catalytic and thermal methods: A review. Renewable and Sustainable Energy Reviews. 2011, Vol. 15, pp. 2355-2377.
8. Y. Shen, K. Yoshikawa. Recent progresses in catalytic tar elimination during biomass gasification or pyrolysis—A review.Renewable and Sustainable Energy Reviews. 2013, Vol. 21, pp. 371-392.
9. L. Devi, K.J. Ptasinski, F.J.J.G. Janssen. A review of the primary measures for tar elimination in biomass gasification processes. Biomass and Bioenergy. 2003, Vol. 24, pp. 125-140.
10. C. Brage, Q. Tu, G. Chen, K. Sjostrom. Tar evaluation profiles obtained from gasification of biomass and coal. Biomass and Bioenergy. 2000, Vol. 18, pp. 87-91.
11. Q. Yu, C. Brage, G. Chen, K. Sjostrom. Temperature impact on the formation of tar from biomass pyrolysis in a free-fall reactor.Journal of Analytical and Applied Pyrolysis. 1997, Vols. 40-41, pp. 481-489.
12. CM. Kinoshita, Y. Wang, J. Zhou. Tar formation under different biomass gasification conditions. Journal of Analytical and Applied Pyrolysis. 1994, Vol. 29, pp. 169-181.
13. I. Narvaez, A. Orio, MP. Aznar, J. Corella. Biomass gasifiaction with air in an atmospheric bubbling Fluidized bed. Effect of six operational variables on the quality of produced raw gas. Industrial and Engineering Chemistry Research. 1996, Vol. 35, pp. 2110-2120.
14. Knight, R.A. Experience with raw gas analysis from pressurized gasi cation of biomass. 2000, Vol. 18, pp. 67-77.
15. J. Herguido, J. Corella, J. Gonzalez-Saiz. Steam gasification of lignocellulosic residues in a fluidised bed at a small pilot scale.E3ect of the type of feedstock. 1992, Vol. 31, pp. 1274-1282.
16. J. Gil, MP. Aznar, MA. Caballero, E. Frances, J. Corella. Biomass gasification fluidized bed at pilot scale with steam-oxygen mixtures. Product distribution for very different operating conditions. 1997, Vol. 11, pp. 1109-1118.
17. Z. Abu El-Rub, E.A. Bramer, G. Brem. Review of Catalysts for Tar Elimination in Biomass Gasification Processes. 2004, Vol. 43, pp. 6911-6919.
18. G. Karlsson, C. Ekstrom, L. Liinaki. The development of a biomass IGCC process for power and heat production.Biomass for Energy, Environment, Agriculture and Industry.s.l. :PergamonPr; 1st edition, 1995, pp. 1538-1549.
19. J. Corella, J. Herguido, J. Gonzalez-Saiz, JF. Alday, JL. Rodriguez-Trujillo.Fluidized bed steam gasi cation of biomass with dolomite and with a commercial FCC catalyst.Research in thermochemical biomass conversion.London : Elsevier, 1988, pp. 754-765.
20. C. A. Jordan, G. Akay. Effect of CaO on tar production and dew point depression during gasification of fuel cane bagasse in a novel downdraft gasifier. 2013, Vol. 106, pp. 654-660.
21. S. Rapagna, N. Jand, A. Kiennemann, PU. Foscolo.Steam-gasification of biomass in a fluidized-bed of olivine particles. 2000, Vol. 19, pp. 187-197.
22. EG. Baker, LK. Mudge, MD. Brown.Methanol and ammonia from biomass. 1984, Vol. 80, pp. 43-46.
23. CE. Douglas, EG.Baker.The effect of catalysis on wood-gasiffcation tar composition. 1986, Vol. 9, pp. 195-203.
24. Seshadri, KS. Effects of temperature, pressure, and carrier gas on the cracking of coal tar over a char–dolomite mixture and calcined dolomite in a fixed-bed reactor. 1998, Vol. 37, pp. 3830-3837.
25. YG. Pan, X. Roca, E. Velo, L. Puigjaner.Removal of tar by secondary air injection in fluidized bed gasification of residual biomass and coal. 1999, Vol. 78, pp. 1703-1709.
26. T. Bui, R. Loof, SC. Bhattacharya. Multi-stage reactor for thermal gasi cation of wood. 1994, Vol. 19, pp. 397-404.
27. P. Brandt, E. Larsen, U. Henriksen. High tar reduction in a two-stage gasifier. 2000, Vol. 14, pp. 816-819.
28. H. Susanto, AACM. Beenackers.A moving-bed gasifier with internal recycle of pyrolysis gas. 1996, Vol. 75, pp. 1139-1147.
29. E. B. Machin, D. T. Pedroso, N. Proenza, J. L. Silveira, L. Conti, L. B. Braga, A. B. Machin. Tar reduction in downdraft biomass gasifier using a primary method. 2015, Vol. 78, pp. 478-483.
30. Asadullah, M. Biomass gasification gas cleaning for downstream applications: A comparative critical review. 2014, Vol. 40, pp. 118-132.
31. P. Hasler, Th. Nussbaumer. Gas cleaning for IC engine applications from fixed bed biomass gasification.Biomass and Bioenergy. 1999, Vol. 16, pp. 385-395.
32. 14th European Biomass Conference & Exhibition. H. Boerrigter, S. van Passen, P. Bergman, J-W. Konemann, R. Emmen. Paris :s.n., 2005. Tar removal from biomass product gas; development and optimisation of the OLGA tar removal technology.
33. W. de Jong, O.rUnal, J.s Andries, K.R.G. Hein. Biomass and fossil fuel conversion by pressurisedfluidised bed gasification using hot gas ceramic filters as gas cleaning. Biomass and Bioenergy. 2003, Vol. 25, pp. 59-83.
34. J. la C. Jansen, K. Jönsson, M. Hagman. Biological detoxification of tar-water.Water Science and Technology. 2002, Vol. 46, pp. 59-65.
35. Decomposition of tar in gas from updraft gasifier by thermal cracking. Brandt P, UlrikHenriksen. Seville, Spain :s.n., 2000. Proceedings of the first world conference on biomass for energy and industry.
36. R. Zhang, R.C. Brown, A. Suby, K. Cummer. Catalytic destruction of tar in biomass derived producer gas. Energy Conversion and Management. 2004, Vol. 45, pp. 995-1014.
37. R. Coll, J. Salvado, X. Farriol, D. Montane. Steam reforming model compounds of biomass gasification tars: conversion at different operating conditions and tendency towards coke formation. Fuel Processing Technology. 2001, Vol. 74, pp. 19-31.
38. T. Wang, J. Chang, X. Cui, Q. Zhang, Y. Fu. Reforming of raw fuel gas from biomass gasification to syngas over highly stable nickel–magnesium solid solution catalysts.Fuel Processing Technology. 2006, Vol. 87, pp. 421-428.
39. J. Srinakruang, K. Sato, T. Vitidsant, K. Fujimoto. Highly efficient sulfur and coking resistance catalysts for tar gasification with steam.Fuel. 2006, Vol. 85, pp. 2419-2426.
40. T. Miyazawa, T. Kimura, J. Nishikawa, S. Kado, K. Kunimori, K. Tomishige. Catalytic performance of supported Ni catalysts in partial oxidation and steam reforming of tar derived from the pyrolysis of wood biomass. Catalysis Today. 2006, Vol. 115, pp. 254-262.
41. L. Haibo, C. Tianhu, Z. Xianlong, L. Jinhu, C. Dongyin, S. Lei. Effect of Additives on Catalytic Cracking of Biomass Gasification Tar over a Nickel-Based Catalyst.Chinese Journal of Catalysis. 2010, Vol. 31, pp. 409-414.
42. K. Tomishige, M. Asadullah, K. Kunimori. Syngas production by biomass gasification using Rh/CeO2/SiO2 catalysts and fluidized bed reactor.Catalysis Today. 2004, Vol. 89, pp. 389–403.
43. Md. A. Uddin, H. Tsuda, S. Wu, E. Sasaoka. Catalytic decomposition of biomass tars with iron oxide catalysts. Fuel. 2008, Vol. 87, pp. 451-459.
44. G. Duman, T. Watanabe, Md.A. Uddin, J. Yanik. Steamgasification of safflower seed cake and catalytic tar decomposition over ceria modified iron oxide catalysts. Fuel Processing Technology. 2014, Vol. 126, pp. 276-283.
45. J. Yanik, S. Ebale, A. Kruse, M. Saglam, M. Yuksel. Biomass gasification in supercritical water: II. Effect of catalyst.Int J Hydrogen Energy. 2008, Vol. 33, pp. 4520-4526.
46. Z. Wang, F. Wang, J. Cao, J. Wang. Pyrolysis of pine wood in a slowly heating fixed-bed reactor: Potassium carbonate versus calcium hydroxide as a catalyst. Fuel Processing Technology. 2010, Vol. 91, pp. 942-950.
47. Y.R. Xie, L.H. Shen, J. Xiao, D.X. Xie, J. Zhu. Influences of Additives on Steam Gasification of Biomass. 1. Pyrolysis Procedure. Energy Fuels. 2009, Vol. 23, pp. 5199-5205.
48. Zhang, X. The dissertation of Zhejiang University (China).The mechanism of tar cracking by catalyst and the gasification of biomass. 2003.
49. L. Devi, M. Craje, P. Thune, K.J. Ptasinski, F.J.J.G. Janssen. Olivine as tar removal catalyst for biomass gasifiers: Catalyst characterization. Applied Catalysis A: General. 2005, Vol. 294, pp. 68–79.
50. Z. Abu El-Rub, E.A. Bramer, G. Brem. Experimental comparison of biomass chars with other catalysts for tar reduction. Fuel. 2008, Vol. 87, pp. 2243-2252.
51. J. R. Kastner, S. Mani, A. Juneja. Catalytic decomposition of tar using iron supported biochar. Fuel Processing Technology. 2015, Vol. 130, pp. 31-37.
52. T.A. Milne, N. Abatzoglou, R.J. Evans. Biomass gasifier "tars": their nature, formation, and conversion. Golden, Colorado : National Renewable Energy Laboratory, 1998.
53. N. Tippayawong, P. Inthasan. Investigation of light tar cracking in a gliding arc plasma system.International Journal of Chemical Reactor Engineering. 2010, Vol. 8, pp. 1-16.
54. A. J. M. Pemen, S. A. Nair, K.Yan, E. J. M. van Heesch, K. J. Ptasinski, A. A. H. Drinkenburg. Pulsed Corona Discharges for Tar Removal from Biomass Derived Fuel Gas. Plasmas and Polymers. 2003, Vol. 8, pp. 209-224.
55. Ch. M. Du, J. H. Yan, X. D. Li, B. G. Cheron, X. F. You, Y. Chi, M. J. Ni, K. F. Cen. Simultaneous Removal of Polycyclic Aromatic Hydrocarbons and Soot Particles from flue Gas by Gliding arc Discharge Treatment. Plasma Chem Plasma Process. 2006, Vol. 26, pp. 517-525.
56. Dayton, D. A Review of the Literature on Catalytic. Golden, Colorado : National Renewable Energy Laboratory, 2002. NREL/TP-510–32815.
57. Y. N. Chun, Y.C. Yang, K. Yoshikawa. Hydrogen generation from biogas reforming using a gliding arc plasma-catalyst reformer.Catalysis Today. 2009, Vol. 148, pp. 283-289.
58. S.A. Nair, A.J.M. Pemen, K. Yana, F.M. van Gompel, H.E.M. van Leuken, E.J.M. van Heesch, K.J. Ptasinski, A.A.H. Drinkenburg. Tar removal from biomass-derived fuel gas by pulsed corona discharges. Fuel Processing Technology. 2003, Vol. 84, pp. 161-173.
59. B.E.J.M. van Heesch, G.A.J.M. Pemen, K. Yan, S.V.B. van Paasen, K.J. Ptasinski, P.A.H.J. Huijbrechts. Pulsed corona tar cracker. IEEE TRANSACTIONS ON PLASMA SCIENCE. 2000, Vol. 28, pp. 1571-1575.
60. Nair, S.A. PhD Thesis. Corona Plasma for Tar Removal.s.l. : Eindhoven University of Technology, 2004.
61. K. Pikoń, Z. Czekalska, S. Stelmach, W. Ścierski. Zastosowanie metod plazmowych do oczyszczania gazu procesowego ze zgazowania biomasy. Archiwum Gospodarki Odpadami i Ochrony Srodowiska. 2010, Vol. 12, pp. 61-72.
62. L.P.L.M. Rabou, R.W.R. Zwart, B.J. Vreugdenhil, L. Bos. Tar in Biomass Producer Gas, the Energy research Centre of The Netherlands (ECN) Experience: An Enduring Challenge. Energy Fuels. 2009, Vol. 23, pp. 6189–6198.
63. S.A. Nair, K. Yan, A.J.M. Pemen, G.J.J. Winands, F.M. van Gompel, H.E.M. van Leuken, E.J.M. van Heesch, K.J. Ptasinski, A.A.H. Drinkenburg. A high-temperature pulsed corona plasma system for fuel gas cleaning. Journal of Electrostatics. 2004, Vol. 61, pp. 117-127.
64. V.A. Bityurin, E.A. Filimonova, G.V. Naidis. Simulation of Naphthalene Conversion in Biogas Initiated by Pulsed Corona Discharges.IEEE TRANSACTIONS ON PLASMA SCIENCE. 2009, Vol. 37, pp. 911-919.
65. S.A. Nair, K. Yan, A. Safitri, A.J.M Pemen, E.J.M. van Heesch, K.J. Ptasinski, A.A.H. Drinkenburg. Streamer corona plasma for fuel gas cleaning: comparison of energization techniques. Journal of Electrostatics. 2005, Vol. 63, pp. 1105-1114.
66. L. Yu, X. Tu, X. Li, Y. Wang, Y. Chi, J. Yan. Destruction of acenaphthene, fluorene, anthracene and pyrene by a dc gliding arc plasma reactor.Journal of Hazardous Materials. 2010, Vol. 180, pp. 449-455.
67. Y.N. Chun, S.C. Kim, K. Yoshikawa. Decomposition of Benzene as a Surrogate Tar in a Gliding Arc Plasma. Environmental Progress & Sustainable Energy. 2012, Vol. 32, pp. 837-845.
68. Y.N. Chun, S.C. Kim, K. Yoshikawa. Removal characteristics of tar benzene using the externally oscillated plasma reformer. Chemical Engineering and Processing: Process Intensification. 2012, Vols. 57-58, pp. 65-74.
69. M. Jasiński, M. Dors, J. Mizeraczyk. Production of hydrogen via methane reforming using atmospheric pressure microwave plasma.Journal of Power Sources. 2008, Vol. 181, pp. 41-45.
70. Mączka, T. Idea plazmowego przetwarzania materiałów organicznych - Wykorzystanie plazmy wielkiej częstotliwości do termicznego przetwarzania materiałów organicznych. Tworzywa Sztuczne w Przemyśle. 2013, 3, pp. 41-44.
71. R.M. Eliott, M.F.M. Nogueira, A.S.S. Sobrinho, B.A.P. Couto, H.S. Maciel, P.T. Lacava. Tar Reforming under a Microwave Plasma Torch.2013, Vol. 27, p. 1174−1181.
72. S. Tuomi, E. Kurkela, P. Simell, M. Reinikainen. Behaviour of tars on the filter in high temperature filtration of biomass-based gasification gas.Fuel. 2015, Vol. 139, pp. 220-231.
73. S. Zhao, Y. Luo, Y. Zhang, Y. Long. Experimental investigation of the synergy effect of partial oxidation oxidationand and bio-char on biomass tar reduction.Journal of Analytical and Applied Pyrolysis. 2015.
74. A. Paethanom, S. Nakahara, M. Kobayashi, P. Prawisudha, K. Yoshikawa, A. Performance of tar removal by absorption and adsorption for biomass gasification. Fuel Processing Technology. 2012, Vol. 104, pp. 144-154.
75. K. Tao, N. Ohta, G. Liu, Y. Yoneyama, T. Wang, N. Tsubaki. Plasma enhanced catalytic reforming of biomass tar model compound to syngas. Fuel. 2013, Vol. 104, pp. 53-57.
76. K. Pikoń, Z. Czekalska, S. Stelmach, W. Ścierski. Zastosowanie metod plazmowych do oczyszczania gazu procesowego ze zgazowania biomasy. Archiwum Gospodarki Odpadami i Ochrony Środowiska. 2010, Vol. 12, pp. 61-72.

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Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.

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