Środki wspomagające roztwarzanie masy typu kraft : przeszłość, teraźniejszość i przyszłość

• Autorzy: Quinde A. , Gaziński J.

Warianty tytułu

EN

Pulping additives in kraft pulping : past, present and future

• Języki publikacji: PL

Abstrakty

PL

Przedstawiono różne procesy rozszerzonej delignifikacji w produkcji celulozy typu ECFI TCF. Te wielce pożądane masy celulozowe, wytwarzane całkowicie bez użycia chloru (TCF), można wytwarzać tylko jeśli osiągnie się niskie liczby kappa. Obecnie dostępne opcje to: rozszerzona delignifikacja, bardziej efektywne mycie, delignifikacja tlenem i/lub zastosowanie enzymu i dalej bielenie przy użyciu innych chemikaliów niż chlor. Opisano chronologię dozowania chemikaliów przy rozszerzonej delignifikacji w procesie kraft i przyszłe, możliwe kombinacje. Skupiono się na siarczku sodu (Na2S), aminach alkilowych (R-NH2), wielosiarczkach (Na2Sx+1), związkach powierzchniowo czynnych i antrachinonie (AQ).

EN

A bries presentation on the different enhanced delignification processes for ECF/TCF pulp production will be given. These greatly desired totally chlorine-free (TCF) pulps are obtained only if very low kappa numbers are achieved in kraft pulping. At present, available options are: extended delignification, more effective pulp washing, oxygen delignification and/or enzymatic treatments followed by final bleaching using other Chemicals than chlorine. A chronological order of the current additives used for extended delignification in the kraft process and examination of future alter-natives is presented. Special attention is given to sodium sulfide (Na2S), alkylamines (R-NHJ, polysulfides (Na2Sx+1), surfactants and anthraguinone (AQ).

Słowa kluczowe

PL

celuloza; masa celulozowa; delignifikacja

EN

cellulose; cellulose pulp; delignification

• Wydawca: Wydawnictwo SIGMA-NOT
• Czasopismo: Przegląd Papierniczy
• Rocznik: 2008
• Tom: R. 64, nr 5
• Strony: 269--274
• Opis fizyczny: Bibliogr. 60 poz.

Twórcy

autor

Quinde A.

autor

Gaziński J.

• Kemira Paper, Vaasa Finland

Bibliografia

• 1.Shrinath SA, Bowen I.J.: "An Overview of AOX Regulations and Reduction Strategies", Tappi Pulping Conference Proceedings, 1-15, Atlanta 14-18.11.1993.
• 2.Jiang J.E.: "Extended Delignification of Southern Pine with Polysulfide and Anthraquinone", Tappi Pulp. Confer. Proceedings, 313-321, Atlanta 14-18.11.1993.
• 3.Katz G.: "Anthraquinone and Anthraquinone-Polysulfide Pulping for Extended Delignification", Tappi Pulp. Confer. Proceedings, 323-331, Atlanta 14-18.11.1993.
• 4.Macleod J.M.: "Extended Delignification: A Status Report", Appita 46, 6, 445-451 (1993).
• 5.McDonald S., Uusitalo P., Hiljanen S.: "Performance of Mill-Scale Superbatch Displacement Batch Cooking Systems", Tappi Pulp. Confer. Proceedings, 415-421, Atlanta 14-18.11.1993.
• 6.Parsad B., Gratzl J., Kirkman A., Jameel H" Rost T., Magnott A.: "Extended Delignification by Kraft Pulping Followed by Oxygen/Alkali Treatment: Technical and Economic Evaluation", Tappi Pulp. Confer. Proceedings, 297-302, Atlanta 14-18.11.1993.
• 7.Perala J., Germgard U.: "The Building Blocks of the Fiberline for Totally Chlorine-Free Kraft pulping", 79th Annual Meeting, Technical Section, CPPA, A281 - A285, Montreal 26-27.01.1993.
• 8.Scheldorf J.J., Eswards L.L.: "Challenges in Modeling the RDH process: A Discontinuous Dynamic System", Tappi 76,11, 97-104 (1993).
• 9.Sturgeoff L.G., Pitl Y.: "Low Kappa Pulping Without Capital Investment - Use of Anthraquinone for Low Kappa Pulping", Tappi Pulp. Confer. Proceedings, 423-429, Atlanta 14-18.11.1993.
• 10.Kovasin K.K., Tikka P.O.: "Low-Kappa Kraft pulping and its Advantages", Paperi Puu 75, 7, 491-497 (1993).
• 11.Korhonen H., Hiljanen S.: "Enocell's New Pulp Started Up", Paperi Puu 75, 5, 286-(1993).
• 12.Goyal G.C., Powers J., Cronlund M.: "Anthraquinone - A Simple Approach for Extended Delignification in Conventional Kraft Pulping", Tappi Pulp. Confer. Proceedings, vol. 3,1047-1053, Boston 1-5.01.1992.
• 13.Rajan P.S., Wayne Griffin C, Jameel H., Gratzl J.S.: "Extending the Digester Delignification with Anthraquinone", Tappi Pulp. Confer. Proceedings, vol. 3, 985-1004, Boston 1-5.01.1992.
• 14.Macleod J.M.: "Is Unbleached Softwood Kraft Pulp Strongest at 30 Kappa Number", Paperi Puu 73, 8, 773-777 (1991).
• 15.Tikka P.O., Kovasin K.K.: "Displacement vs. Conventional Batch Kraft Pulping: Delignification Patterns and Pulp Strength Delivery", Paperi Puu 72, 8, 773-779 (1990).
• 16.Andrews E.K.: "RDH Kraft Pulping to Extend Delignification, Decrease Effluent, and Improve Productivity and Pulp Properties", Tappi 72, 11, 55-61 (1989).
• 17.Pekkala O.: "Prolonged Kraft Cooking Modified by Anthraquinone and Polysulfide", Paperi Puu 68, 5, 385-400 (1986).
• 18.Blain T.J.: "Anthraquinone Pulping: Fifteen Years After", Tappi Pulp. Confer. Proceedings, 1005-1014, Boston 1-5.11.1992.
• 19.Malkov Y.: "A Polysulfide Liquor Regeneration Process With the Use of an MT Catalyst", Paperi Puu 72,10, 961-966 (1990).
• 20.Green R.P., Smith G.C.: "The Use of Quinone Additives in Kraft and Poplysulfide Pulping", Tappi Pulp. Confer. Proceedings, 79-84, Houston, 24-26.10.1983.
• 21.Yamaguchi A.: "Operating Experiences With the Moxy Process and Ouinoid Compounds", Tappi Pulp. Confer. Proceedings, 544-548, Houston 24-26.10.1983.
• 22.Pekkala 0.: "On the Extended Delignification Using Polysulfide or Anthraquinone in Kraft Pulping", Paperi Puu 64,11, 735-744 (1982).
• 23.Kleppe P.J.: "A Mili Trial With the Addition of a Small Amount of AQ to Kraft and Polysulfide Pulping", Paperi Puu 63, 4, 204-210 (1981).
• 24.Chen G.C.: "Application of a Surfactant as a Kraft Pulping Additive", Tappi 77,2,125-128(1994).
• 25.Kocurek M.J., Ed.: "Pulp and Paper Manufacture", Vol. 5, Alkaline Pulping, Georgia, The Joint Textbook of the Paper Industry TAPPI and CPPA 1983.
• 26.Gierer J, Lenz B" Wallin N.-H.: Acta Chem. Scand. 18, 6,1469 (1964).
• 27.Watson P.A., Gustafson R.R., McKean W.T., Andrews E.K.: "Low Sulfidity and Additive Pulping by Modified Batch (MB) Cooking", Tappi Pulp. Confer. Proceeding, 847-854, Boston 1-5.11.1992.
• 28.Kent W.R., Hatton J.V.: "Low-Sulfidity Krafl-Anthraquinone Pulping of Hardwood/Softwood Mixtures", Tappi Pulp. Confer. Proceedings, 69-77, Houston 24-26.11.1983.
• 29.Blain T.J.: "The Influence of Sulfidity on the Bleachability and strength Properties of Alkaline-Anthraquinone Softwood Pulps", Tappi 63, 5, 125-128 (1980).
• 30.Blain T.J.: "Low-Sulfidity Pulping With Anthraquinone", Tappi 62,6, 53-55 (1979).
• 31.Peterson F.C., Wise L.E.: U.S. Patent 2,192, 202 (1936).
• 32.Peterson F.C., Wise L.E.: U.S. Patent 2, 218, 419 (1936).
• 33.Kubes G.J., Bolker H.I.: "Sulfur-Free Delignification. I. Alkaline Pulping With Monoethanolamine and Ethylene Diamine", Cellulose Chem. Technol. 12, 621-645 (1978).
• 34.Enkvist V.T., Moilanen M., Alfredsson B.: Svensk Papperstidn. 52,12, 517 (1949).
• 35.Macleod J.M., Kubes G.J., Fleming B.I., Bolker H.I.: Tappi Pulp. Confer. Proceedings, 273, New Orleans 5-8.11.1978.
• 36.Ahlgren P" Teder A.: "Delignification Rate in Polysulfide Pulping", Svensk Papperstidn. 70, 4,135-143(1967).
• 37.Smith G.C., Knowles S.E., Green R.P.: "All it Takes is Moxy: Mead Oxidation System Generates Polysulfide Liquor", Paper Trade J. 159,13,38-41 (1975).
• 38.Rao A.R.K., Varadhan R., Rao N.R.M., Murthy N.V.S.R.: "Polysulfide Pulping of Bamboo", Tappi 61, 5, 81-83 (1978).
• 39.Ouinde A.: "The Synthesis of Methyl-Substituted Anthraquinone Derivatives and Their Use in the Soda Pulping of Norway Spruce", M.Sc. Thesis, State University of New York, Syracuse, U.S.A., pp. 114 (1981).
• 40.Bach B., Fiehn G.: "New Possibilities for Carbohydrate Stabilization in Alkaline Pulping of Wood", Zellstoffe Papier 21, 3, 3-7 (1972).
• 41.Nomura Y.: Japan Tappi 34,1, 50 (1974).
• 42.Dutta T., Biermann C.J.: "Kraft Pulping of Douglas Fir With 1,4-Dihydro-9,10-dihydroxyanthracene", Tappi 72, 2,175-177 (1989).
• 43.Fleming B.I., Kubes G.J., Macleod J.M., Bolker H.I.: "Soda pulping With Anthraquinone: A Mechanism", Tappi 61, 6, 43-46 (1978).
• 44.Lowendahl L, Samuelson O.: "Carbohydrate Stabilization During Soda Pulping With Addition of Anthraquinone", Tappi 61, 2,19-21 (1978).
• 45.Vuorinen T.: "The Role of Carbohydrates in Alkali Anthraquinone Pulping", Wood Chem. Technol. 13,1, 97-125 (1993).
• 46.Gierer J.: Svensk Papperstidn. 73,18, 571 (1970).
• 47.Landucci L.L.: "Ouinones in Alkaline Pulping: Characterization of an Anthrahydroquinone-quinone methide Intermediate", Tappi 63, 7, 95-99 (1980).
• 48.Holton H.H.: "Soda Additive Softwood Pulping: A Major New Process", Pulp and Paper Canada 78,10, T218-T223 (1977).
• 49.McDonough T.J., Van Drunen V.J.: "Pulping to Low Residual Lignin Contents in the Kraft-Anthraquinone and Kraft Processes", Tappi 63,11, 83-87 (1980).
• 50.McDonough T.J., Herro J.L.: "The Influence of Low-Lignin Pulping Conditions on Bleachability: The Effects of Anthraquinone and Effective Alkali Charge", Tappi Pulp. Confer. Proceedings, 371-378, Denver 19-21.10.1981.
• 51.Porter M.R.: "Recent Developments in the Technology of Surfactants", New York, Elsevier Applied Science, pp. 203 (1991).
• 52.Parker ET., Lundsteds L.G., U.S.A. Patent 3, 909, 345 (1975).
• 53.Mutton D.B.: "Hardwood Resin", Tappi 41,11, 632-643 (1958).
• 54.Aurell R., Hartler N.: "Sulphate Cooking With the Addition of Reducing Agents-Part II", Tappi 46, 4, 209-215 (1963).
• 55.Nillson E.R., Osterg K.: "Kraft Pulping With the Addition of Hydrazine", Svensk Papperstidn. 71,3, 71-76(1968).
• 56.Minor J.L., Springer E.L: "Delignification of Wood Fibers With Peroxymonosulfate", Paperi Puu 72,10, 967-973 (1990).
• 57.Mortimer R.D.: "The Acceleration of Delignification With Selenium", Pulp Paper Sci. 15, 3, J97-J99 (1989).
• 58.Dimmel D.R., Bozell J.J.: "Pulping Catalysts From Lignin", Tappi 74, 5, 239-241 (1991).
• 59.Watson P.A., Wright L.J., Fullerton T.J.: "Reactions of Metal Ion Complexes With Lignin Model Compounds. Part II. Fe(TSPC) Catalyzed Formation of Oxidized Products in the Absence of Oxygen", Wood Chem. Technol. 13,3,391 - 409 (1993).
• 60.Watson P.A., Wright L.J., Fullerton T.J.: "Reactions of Metal Ion Complexes With Lignin Model Compounds. Part III. Rh(TSPP) Catalyzed Formation of Guaiacol From B-Aryl Ethers in Exceptionally High Yield", Wood Chem. Technol. 13, 3, 411-428 (1993).