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Eustachy Gryszkiewicz - Trochimowski (1888-1971) chemik

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Eustachy Gryszkiewicz - Trochimowski (1888-1971)- chemist
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Eustachy Gryszkiewicz-Trochimowski was born on April 17, 1888, in Kowle on Volhynia. Having graduated from classical grammar-school in Human, he began his studies in the faculty of Mathematics and Natural Science m the University of St. Włodzimierz in Kiev. His scientific interests in chemistry appeared already during university studies. This fact attracted his teacher's attention a distinguished organic chemist- professor S. N. Reformatski (I860 -1938). The first works he published in the years 1908-1909. In 1910 professor Reformatski appointed him to a post of assistant in laboratory of organic chemistry within Higher Women Classes. In 1913 Gryszkiewicz-Trochimowski was employed as an assistant professor, and as a lecturer in chemistry was appointed to a post of professor in Higher Institute of Trade. After professor Reformatski had retired in 1917, Gryszkiewicz-Trochimowski was appointed to a professorship and took over a chair in Organic Chemistry Department. In 1925, having moved to Poland, he resigned from academic career. Having returned to Poland, he began to work in Research Institute of Chemical Weapons, in which look up systematic and extensive research works over arsenoorganic compounds, and combinations including fluorine. He worked out an original method of producing an unavailable compound of oxym of phosgene, which later was widely used, and also beyond the army. The combination was available just by dint of the method that was introduced by Gryszkiewicz-Trochimowski. In Poland the method of producing oxym of phosgene was concealed, and the compound was produced under a secret name TSD together with sulphuric yperile. Moreover, Gryszkiewicz-Trochimowski took up intensive scientific researches on synthesis of halogen derivatives of aliphatic, and aliphatic and aromatic ketones. In the second half of the 1930s, together with the closest co-workers - doctor Adam Sporzyński and Lieutenant MA Jakub Wnuk- he worked out a new method of synthesis of organic-fluoric combinations. The method was kept in the strictest secrecy and was revealed in 1942 to the English by doctor Sporzyński while visiting Great Britain. The results of the Warsaw research works were laid before professor of the University of Cambridge - H. McCombiem, who presented them as his own discovery, and who look a patent for the method. While doing research works in the Institute, Eustachy Gryszkiewicz Trochimowski with an approval of army adminislration since January, 1929, started to work in Industry and Trade Establishments of Chemistry - L. Spiess & Son. Co-operating with the company for 10 years, he elaborated and applied the modified methods of producing many synthetic remedies, and worked out a program of establishment's production that could easily conform with the modern chemical and pharmaceutical factory. The program in the post-war period was continued almost for two decades. Gryszkiewicz-Trochimowski was the only chemist in Poland, who did his research works over synthetic healers. In the period of occupation he worked for a while in the company "Spiess", In 1943 he was informed of the murder in Katyń of his co-worker-captain doctor Wnuk. A perspective of annextion of Polish territories by the Soviets was for him a serious threat and thus he started making attempts at leaving for the west. He left the country under unknown circumstances and found himself in France. After the end of World War II he published a greal many of his works that earlier had been kept in secret. In France he was employed in the military scientific and research institution - Centre d'Eludes du Buchct - and was engaged in works over a French program of defence. Having lived to be seventy nine, died on February 25, 1971, in Brazil.
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Bibliografia
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  • 17. Knoll A.G.: DRP 427858 (anm. 03.01.1924).
  • 18. Gryszkiewicz - Trochimowski: Przepis na otrzymanie kardjazolu. Warszawa 28.04.1939. Rękopis w posiadaniu autora.
  • 19. Boehringer: A process for preparing di-substituted tetrazoles. British Patent nr 309949 (Convention data l8.04.1928 Germany).
  • 20. Knoll A.G.: Verfahren zur Herstellung von disubstituierten tetrazolen. DRP 537739 (anm. 19.04.1928).
  • 21. Mieczysław Buczwiński; Sposób otrzymywania cyklopentametylonotetrazolu. Zgłoszenie Patentowe 59892 (zgł. 02.01.1939).
  • 22. Rudolf Arcichowski: Sposób otrzymywaniu pentametylenotetrazolu. Patent Polski nr 10830 (zgł. 19.04.1929).
  • 23. Rudolf Arcichowski: Sposób wytwarzania pentametylenotetrazolu. Patent Polski nr 30862 dodatkowy do patentu nr 10830 (zgł. 24.11.1937). udzielony 24.08.1942.
  • 24. Rudolf Arcichowski. Sposób wytwarzania cyklopentametylenotetrazolu. Patent Polski nr 28406 (zgł. 27.04.1937).
  • 25. Teodor Kikta; Przemysł Farmaceutyczny w Polsce (1823 1930). Warszawa 1972 s. 286.
  • 26. Cardiazole, Knoll, Minden. B.I.O.S. Final Report No 766 s. 50-52 (British Intelligence objectioves subcommittee, London).
  • 27. Prandtlu. K. Sennewald: Tri-nutriso-mthan, dichloro-formoxim (Phosgenoxim) und einige ihrer Derivative. "Berichte" 1929 t. 62 s. 1754-l768.
  • 28. Paolini: Dioximes. ,,Gazzetta chemica italiana" 1930 t. 60 s. 700 704.
  • 29. Endres: Über die Einwirkung von Halogen auf Knallquecksilber. "Berichte" 1932 t. 63 s. 65-69.
  • 30. Prandtlu. W. Dolfus: Über das Trichlor-nitroso-methan, das Diechlor-form-oxim (Phosgen-oxim) und einige ihrer Derivate. 2. Mitteil: Über zwei neue Derivate der Kohlensäure. "Berichte" 1932 t. 65 s. 754-759.
  • 31. P. Ehman and W. Walker: Phosgene oxime. US Patent nr 2299742 (app. 27.10.1943).
  • 32. Brintzinger, H. Z Igleru. E. Schnelder: Der Verlauf der kathodischen Reduktion von Trichlorinitromethan. "Zeitschrift für Elektrochemie Angewandte Physikalische Chemie" 1949 t. 53 s. 109-113.
  • 33. J. Madaus and H. Urbach: Elecrolytic production of dichloroformoxime, US Patent nr 2918418 (app. 22.12.1959).
  • 34. Hydro: Production of dichloroformoxime. US Patent nr 4558160 (app. 25.04.1985).
  • 35. Jared Ludgard: A Laboratory History of chemical Warfare Agents. 2006 s. 149 153.
  • 36. P.C. Ray: A New method of fluorination of organic compounds. "Nature" 1933 t. 132 s. 173-174.
  • 37. H.C. Goswami and P.B. Sarkar: Ethyl and methyl esters of fluoroformic acid. ,,Journal of Indian Chemical Society" ("J. Indian Chem. Soc.") 1933 t. 10 s. 537-539 Chemical Abstracts 1934 t. 28 s. 1332.
  • 38. P.C. Ray, H.C. Goswami and A.C. Ray: Fluorination of organic- compounds. ,, J. Indian Chem. Soc." 1935 t. 12 s. 93-95 Chemical Abstracts 1935 t. 29 s. 4330.
  • 39. Bacon, C. Bradley, E. Hoegberg, P. Tarrant and J. Cassaday: Some amides and esters of fluoroacetic acid. "Journal of American Chemical Society" 1948 t. 70 s. 2653-2655.
  • 40. Stanisław Konarski: Sporzyński Adam Przemysław, [w:] Polski słownik biograficzny t. 41/2 Warszawa-Kraków 2002 s. 163-164.
  • 41. McCombie and B. Saunders: Fluoroacetates and allied compounds. ,,Nature" 1946 t. 158 s. 382-385.
  • 42. C.A.W. Instytut Przeciwgazowy. I. 342. 2. 35.
  • 43. Ignacy Siemion: Reakcje imienne chemików Polaków. Warszawa 1987 s. 106-110.
  • 44. Amtliches Material zum Massenmord von Katyń, 1943. 4121 (pozycja rejestracji zwłok).
  • 45. Józewski: Zamiast pamiętnika. "Zeszyty Historyczne". Instytut Literacki Paryż 1982 t. 59 s. 3-77.
  • 46. Andrzej Mochola: Rosyjska Praga. "Tygodnik Powszechny" www.tygodnik.com.pl/contrapunkt/17-l8/.
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Bibliografia
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bwmeta1.element.baztech-article-LOD6-0026-0020
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