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Laserowa modyfikacja właściwości materiałów przewodzących

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EN
Laser modification of properties of conducting materials
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PL
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PL
W pracy przedstawiono zagadnienie modyfikacji właściwości materiałów przewodzących, ze szczególnym uwzględnieniem konduktywności stałoprądowej, przy wykorzystaniu technologii laserowych, w których oddziarywanie promieniowania z powierzchnią ciała stałego ma charakter termiczny. Zaprezentowano zakres zastosowań laserowych technologii w elektronice i elektrotechnice, w tym problemy wytwarzania elementów przewodzących w laserowych procesach zapisu bezpośredniego. Poddano analizie laserowe procesy modyfikacji właściwości materiałów zachodzące ze zmianą stanu skupienia oraz z wprowadzaniem obcych domieszek. Omówiono zespół najważniejszych zjawisk, towarzyszących oddziaływaniu zogniskowanej wiązki laserowej z ciałami stałymi, charakterystycznych dla tych procesów technologicznych. W poszczególnych przypadkach rozpatrywano możliwość zastosowania laserowych systemów impulsowych lub wykorzystujących wiązkę ciągłą. Dla rozważanych procesów technologicznych określono możliwy zakres modyfikacji konduktywności oraz innych wybranych parametrów materiałów przewodzących, a także zespół niezbędnych parametrów technologicznych. Wiele uwagi poświęcono bardzo efektywnym dla modyfikacji właściwości procesom domieszkowania laserowego, w tym opracowanym przez autora metodom wytwarzania elementów warstwowych o dużej rezystywności oraz mikroobszarów rezystywnych. Wykazano, że ekstremalne skutki oddziaływania koherentnej i monochromatycznej wiązki promieniowania laserowego, w szczególności bardzo duże prędkości nagrzewania, chłodzenia oraz krystalizacji, a także występujący w niektórych procesach dynamiczny ruch masy, mają decydujący wpływ na przebieg i efekty laserowych procesów technologicznych. W zastosowaniu do materiałów przewodzących pozwalają one modyfikować w szerokim zakresie konduktywność oraz inne właściwości istotne dla zastosowań. Przedyskutowano także zmiany konduktywności materiałów przewodzących w laserowych procesach łączenia, ze szczególnym uwzględnieniem mikropołączeń spawanych i lutowanych. Zaprezentowano metodę wyodrębnienia strukturalnego składnika rezystancji połączeń spawanych, wykorzystującą obraz pola elektrycznego w połączeniu modelowym. Wykazano korzystny wpływ lutowania laserowego na zmniejszenie rezystancji połączeń, w wyniku ograniczenia wzrostu wysokorezystywnych związków międzymetalicznych. Analizę wszystkich zagadnień, dotyczących modyfikacji właściwości materiałów przewodzących w laserowych procesach termicznych, potwierdzono wynikami doświadczalnych prac autora. Obejmowały one badania zjawisk, występujących w tych procesach oraz badania właściwości strukturalnych materiałów poddanych laserowej modyfikacji, z wykorzystaniem metod mikroskopii elektronowej, mikroanalizy rentgenowskiej, a także termografii. Zaprezentowano i poddano analizie badania stałoprądowej konduktywności elektrycznej modyfikowanych materiałów przewodzących w zakresie temperatur 77-400K. W poszczególnych przypadkach podano prognozę zastosowania modyfikowanych materiałów.
EN
In the work, the modification of properties of conducting materials by means of laser technologies, in which the interaction with the surface of a solid is of thermal character, with a focus on direct-current conductivity, has been discussed. A range of applications of laser technologies in electronics and electrical engineering, including problems of production of conducting elements in direct writing laser processes, have been presented. Laser processes of modification of material properties occurring along with the change of state and the introduction of foreign elements have been analyzed. The most important phenomena accompanying the interaction of a focused laser beam with solids have been discussed. In individual cases, the possibility to use pulsed laser and continuous laser systems has been considered. For the technological processes under consideration, a possible range of modification of conductivity and other selected parameters of conducting materials, as well as a set of necessary technological parameters have been determined. Much attention has been paid to laser alloying processes, very effective for the modification of properties, including the author's own methods of producing layer elements of a high resistivity and resistive micro-areas. It has been demonstrated that extreme effects of the interaction of a coherent and monochromatic laser radiation beam, and in particular high rates of heating, cooling and crystallization, as well as the dynamic motion of mass occurring in some processes, have a decisive influence on the course and effects of laser technological processes. When used for conducting materials, they allow conductivity and other properties essential for applications to be modified over a wide range. In addition, changes in the conductivity of conducting materials in laser processes of joining, with a special focus on welded and soldered micro-joints have been discussed. A method for separating a structural component of resistance of welded joints, making use of an image of an electric field in a model joint has been presented. A beneficial effect of laser soldering on the decrease in the resistance of joints as a result of limiting the growth in high-resistance intermetallics has been shown. The problems presented have been illustrated with the results of the author's own experimental work on laser modification of conducting materials, structural studies and studies on the properties of the materials modified, with a focus on electrical conductivity. In individual cases, prognoses for the application of modified materials have been given.
Rocznik
Tom
Strony
3--218
Opis fizyczny
Bibliogr. 493 poz.
Twórcy
autor
  • Zakład Inżynierii Materiałowej i Systemów Pomiarowych. Instytut Systemów Inżynierii Elektrycznej Politechniki Łódzkiej
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