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Characterisation of properties and microstructural changes of 12% Cr-W steels after long-term service

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: Characterization of the influence of long-term exposition on microstructural stability and properties of new modified ferritic steels containing 12% Cr with W addition. Design/methodology/approach: The examinations were made on samples from superheater tubes (HCM12 and HCM12A type of steel) after long term exposition (20 and 30 thousand hours). The major technique used to investigations are: microstructural analysis with the use of LM, SEM and TEM and measurement of hardness and strength at an ambient temperature and at 600° C. Findings: Investigated power plant steels exhibit high stability of microstructeres and mechanical properties. The main effects of degradation are related to the decomposition of martensite areas, the precipitation of M23C6 carbides and Laves' phases, and the processes of recrystallization and recovery. Results of mechanical examinations showed that main mechanical parameters was still satisfactory after 30.000 hours of operation. Research limitations/implications: Presented examination showed that new type of power plant steels are characterized by high stability of the microstructure and properties, however it necessary to identify the mechanisms of structure degradation and, in consequence, of adjusting the mechanical properties below the values required. It is therefore necessary to continue the investigations after successive periods of operation. Practical implications: Presented conclusion give the possibility to the determination of the degree of life-time lost of the investigated high-chromium steels and specification of the time of safety operation. Originality/value: This investigations are valuable contribution to the development of new steels for the power industry. They enable the identification of the degradation mechanisms in steels of new types, which enhances the durability and safety of boilers' operation.
Rocznik
Strony
312--319
Opis fizyczny
Bibliogr. 15 poz., wykr.
Twórcy
autor
autor
autor
autor
  • Materials Science Department, Silesian University of Technology, ul. Krasińskiego 8, 40-019 Katowice, Poland, grzegorz.moskal@polsl.pl
Bibliografia
  • [1] R. Viswanathan, W. T. Bakker, Materials for boilers in ultra supercritical power plants, Proceedings of the ”2000 International Joint Power Generation” Conference, Miami Beach, 2000, 1-21.
  • [2] V. K. Sikka, C. T. Ward, K. C. Thomas, Modified 9Cr-1Mo steel-an improved alloy for steam generator application, Ferritic steels for high temperature applications, Proceedings of the International Conference ”Production, Fabrication, Properties and Application of Ferritic Steels for High Temperature Applications”, Metals Park, 1981, 65-84.
  • [3] A. Czyrska-Filemonowicz, A. Zielinska-Lipiec, P. J. Ennis, Modified 9% Cr steels for advanced power generation: microstructure and properties, Journal of Achievements in Materials and Manufacturing Engineering 19/2 (2006) 43-48.
  • [4] A. Czyrska-Filemonowicz, A. Zielinska-Lipiec, P. J. Ennis, Microstructure and creep behaviour of the new 9% Cr steel containing tungsten for power generation, Proceedings of the 4th Scientific International Conference ”Achievements in Mechanical and Materials Engineering” AMME'95, Gliwice-Wisła, 1995, 43-46.
  • [5] J. Ehlers, D. J. Young, E. J. Smaardijk, A. K. Tyagi, H. J. Penkalla, L. Singheiser, W. J. Quadakkers, Enhanced oxidation of the 9%Cr steel P91 in water vapour containing environments, Corrosion Science 48 (2000) 3428-3454.
  • [6] Y. Iseda, A. Sawaragi, H. Teranishi, M. Kubota, Y. Hayase, Development of new 12%Cr steel tubing (HCM12) for boiler application, The Sumitomo Search 40 (1999) 41-56.
  • [7] J. Dobrzański, The classification method and the technical condition evaluation of the critical elements material of power boilers in creep service made from the 12Cr-1Mo-V, Proceedings of the 13th Scientific International Conference „Achievements in Mechanical and Materials Engineering” AMME'2005, Gliwice-Wisła, 2005, 107-112.
  • [8] R. Viswanathan, W. T. Bakker, Materials for ultra supercritical fossil power plants, EPRI, Palo Alto, CA: 2000, TR-114750.
  • [9] F. Masuyama, New developments in steels for power generation boilers in Advanced Heat Resistant Steels for Power Generation, IOM Communications Ltd., London, 1999.
  • [10] J. Dobrzański, The classification method and the technical condition evaluation of the critical elements' material of power boilers in creep service made from the 12Cr-1Mo-V, Journal of Materials Processing Technology 164-165 (2005) 785-794.
  • [11] W. Garrison, R. F. Buck, An overview of the development of advanced 9-12% Cr steels, Proceedings of the Symposium ”Materials for Rotating Machinery”, Cincinati, 1999.
  • [12] J. Oñoro, Martensite microstructure of 9-12%Cr steels weld metals, Journal of Materials Processing Technology 180/1-3 (2006) 137-142.
  • [13] F. Masuyama, H. Haneda, T. Daikoku, T. Tsuchiya, Development and applications of a high strength, 12% Cr steel tubing with improved weldability, Proceedings of the 7th Liege Conference ”Materials for Advanced Power Engineering”, Energy Technology, 1986, 229-237.
  • [14] J. Pasternak, Analysis of process and structural factors determining the properties and applicability of selected new Cr-Mo-V-W-(Cu) steel grades used for boiler tubes and their welded connections to be operated in supercritical parameters, PhD Thesis-Unpublished, Silesian University of Technology Press, Katowice, 2000 (in Polish).
  • [15] A. Hernas, G. Moskal, K. Rodak, J. Pasternak, Properties and microstructure of 12% Cr-W steels after long-term service, Journal of Achievements in Materials andManufacturing Engineering 17 (2006) 459-462.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAW-0002-0022
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