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Purpose: The aim of this work was to determine an effect of X-ray irradiation on activation of silver reduction from water solutions of its salts, resulting in fabrication of nanocrystalline product. Design/methodology/approach: The process and products of the reduction of silver nitrate water solutions, containing the additions of other compounds or not, including particle growth inhibitors, irradiated with X-rays of different energy or with a laser beam, were investigated. Findings: It was found that irradiation had significant effect on the initiation of the reduction process and on its rate and proceeding. The radiation dose is not of great importance provided than some its threshold value is exceeded. It was also found that polyvinyl pyrrolidone (PVP), used as growth inhibitor of silver crystallites, exhibits a reducing effect in the studied processes. Research limitations/implications: It is recommended to perform further research aimed at increasing mass yield of irradiation-activated reduction process and at selecting efficient method for deposit separation from the solution at the maintained high refinement of silver particles. Practical implications: The results from this study extend the scope of available methods for preparation of silver nanoparticles by a new one, which is based on process activation by irradiation of the substrates by X-rays. Originality/value: The new method for silver nano-particles fabrication has been successfully tested and its usefulness has been proved. Conditions for conducting the process of silver (I) ions reduction by this method have been proposed.
Wydawca
Rocznik
Tom
Strony
23--26
Opis fizyczny
Bibliogr. 15 poz., tab., wykr.
Twórcy
autor
autor
autor
autor
autor
autor
- Institute of Non-Ferrous Metals, ul. Sowińskiego 5, 44-100 Gliwice, Poland, mariuszs@imn.gliwice.pl
Bibliografia
- [1] Y. T. Yu, Y. Tsu, Investigation on Production Mechanism of Ultrafine Particles in ERC (Evaporation and Rapid Condensation) Method, Materials Transactions JIM 34/9 (1993) 809-814.
- [2] J. Singh, E. Whitney, P. E. Denney, Production of nanoparticles and tubes by laser liquid interaction, US Patent no 6068800, 2000.
- [3] L. A. Dobrzański, A. Drygała, P. Panek, M. Lipiński, P. Zięba, Application of laser in multicrystalline silicon surface processing, Journal of Achievements in Materials and Manufacturing Engineering 24/2 (2007) 179-182.
- [4] M. Żenkiewicz, Methods for the calculation of surface free energy of solids, Journal of Achievements in Materials and Manufacturing Engineering 24/ 1 (2007) 137-145.
- [5] K. S. Chou, C. Y. Ren, Synthesis of nanosized silver particles by chemical reduction method, Materials Chemistry and Physics 64 (2000) 241-246.
- [6] Y. Tan, X. Dai, Y. Li, D. Zhu, Preparation of gold, platinum, palladium and silver nanoparticles by the reduction of their salts with a weak reducant-potassium bitartarte, Journal of Materials Chemistry 13 (2003) 1069-1075.
- [7] B. He, J. J. Tan, K. Y. Liew, Kong Yong, H. Liu, Synthesis of size controlled Ag nanoparticles, Journal of Molecular Catalysis A, Chemical 221 (2004) 121-126.
- [8] H. Wang, Q. X. Chen, D. S. Jianguo, Preparation of silver nanoparticlesby chemical reduction method, Colloids and Surfaces A: Physicochemical and Engineering Aspects 256 (2005) 111-115.
- [9] J. Brummer, R. Langlois, Controlling Synthesis of Nano-structured Silver Aggregates by Light, Nanotechnology 17 (2006) 1901-1905.
- [10] S. Lien-Chung Hsu, Rong-Tarng Wu, Synthesis of contamination-free silver nanoparticle suspensions for micro-interconnects, Materials Letters 61 (2007) 3719-3722.
- [11] J. D. Hanawalt, H. W. Rinn, L. K. Frevel, Chemical Analysis by X-Ray Diffraction-Classification and Use of X-Ray Diffraction Patterns, Industrial and Engineering Chemistry 10/9 (1938) 457-512.
- [12] W. B. Pearson, A Handbook of Lattice Spacings and Structures of Metals and Alloys, Pergamon Press, Oxford, 1958.
- [13] H. P. Klug, L. E. Alexander, X-Ray Diffraction Procedures, John Wiley and Sons, New York, 1954.
- [14] M. Staszewski, Z. M. Rdzawski, A. Wrona, Residual stresses in the strips from copper-based alloys, Journal of Achievements in Materials and Manufacturing Engineering 25/2 (2007) 35-38.
- [15] A. Bielański, General and inorganic chemistry, 4th edition, PWN, Warsaw, 1976 (in Polish).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAN-0003-0004