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Surface modification of PBO fiber by electrostatic discharge for composites

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Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: PBO fibers provide great potential applications as reinforcement fibers for advanced composites due to the excellent thermal resistance and specific stiffness and strength. However, the interfacial adhesion between reinforcing fiber and polymer matrix in a composite system is a primary factor for the stress transfer from matrix to fiber. In this paper, the effects of surface treatment on the modification of PBO fiber and its composite materials have been investigated using electrostatic discharge under atmospheric pressure. The surface treatment process has been designed to improve fiber/matrix interfacial bonding quality while providing minimum alteration to the bulk characteristics of the reinforcement fiber. Design/methodology/approach: Both as-spun (AS) and high-modulus (HM) PBO fibers were surface treated and characterized in this study. The characterization techniques included scanning electron microscopy, MTS tensile tester, dynamic contact angle analysis system and microbond pull-out tests. Findings: The results showed that PBO fibers exhibited-10% reduction in tensile strength after the proposed treatment process. The AS fiber surface free energy could be increased from 49.90 mJ/m² to 65.42 mJ/m² (+31%) and the HM fiber surface free energy could be increased from 46.20 mJ/m² to 65.36 mJ/m² (+41%). The interfacial shear strength between PBO fiber and the epoxy matrix was improved to 41.6 MPa (+20%) for AS fiber system, and it improved to 40.1 MPa (+23%) for HM fiber system. The composite failure mode also shifted from fiber/matrix interface adhesive failure to partly cohesive failure. Research limitations/implications: The composite interfacial shear strength was improved through the increased surface free energy of PBO fiber. The more cohesive failure mode allowed more energy to be dissipated during failure. Originality/value: The proposed electrostatic discharge treatment process could improve the surface characteristics of PBO fiber and the applications in advanced composites.
Rocznik
Strony
722--728
Opis fizyczny
Bibliogr. 20 poz., il., tab., wykr.
Twórcy
autor
autor
  • Advanced Materials Laboratory and Institute of Electro-Optical Engineering Chang Gung University, Kweisan, Taoyuan 333, Taiwan R.O.C., wu@mail.cgu.edu.tw
Bibliografia
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  • [2] T. Kitagawa, K. Yabuki, R. J. Young, Investigation into the relationship between processing, structure and properties for high-modulus PBO fibres. Part 1. Raman band shifts and broadening in tension and compression, Polymer 42 (2001) 2101-2012.
  • [3] F. Larsson, L. Svensson, Carbon, polyethylene and PBO hybrid fibre composites for structural lightweight armour, Composites Part A: Applied Science and Manufacturing 33 (2002) 221-231.
  • [4] G. M. Wu, Y. T. Shyng, Surface modification and interfacial adhesion of rigid rod PBO fibre by methanesulfonic acid treatment, Composites Part A: Applied Science and Manufacturing 35 (2004) 1291-1300.
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  • [10] D. Sun, G. K. Stylios, Fabric surface properties affected by low temperature plasma treatment, Journal of Materials Processing Technology 173 (2006) 172-177.
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  • [14] M. Pascu, C. Vasile, M. Gheorghiu, Modification of polymer blend properties by argon plasma/electron beam treatment: surface properties, Materials Chemistry and Physics 80 (2003) 548-554.
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  • [16] G. M. Wu, C. H. Hung, J. H. You, S. J. Liu, Surface modification of reinforcement fibers for composites by acid treatments, Journal of Polymer Research 11 (2004) 31-36.
  • [17] D. A. Biro, G. Pleizier, Y. Deslandes, Application of the microbond technique: effects of hygrothermal exposure on carbon-fiber/epoxy interfaces, Composites Science and Technology 46 (1993) 293-301.
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  • [20] G. M. Wu, Y. T. Shyng, Surface modification of PBO fiber by electrostatic discharge for composites, Journal of Achievements in Materials and Manufacturing Engineering 17 (2006) 169-172.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAN-0002-0029
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