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Sintering of TiB2 ceramics

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: Titanium diborides (TiB2) ceramic is particularly interesting because it exhibits high elastic modulus and hardness as well as high thermal conductivity. The interest in TiB2 ceramic increased enormously due to these properties but applications seem to be limited due to difficulties during densification process. In the experiment the TiB2 compacts was obtained using HP-HT method. The aim of this study is to work out and optimize the sintering densification process of TiB2 ceramics. Design/methodology/approach: The high temperature-high pressure (HT-HP) Bridgman type apparatus was used for densification method of TiB2 powder. Ceramics were sintered at pressure of 7.2 ± 0.2 GPa and temperature at 1500-2300*C ± 50*C. The duration of sintering was 60 seconds. In order to investigate the structure changes, the optical and scanning electron microscope was used. Mechanical properties were determined by Vickers hardness. Young modulus measurements were carried out using ultrasonic method. Findings: The TiB2 ceramics was obtained without using sintering agents. The properties and structure of TiB2 ceramics strongly depend on conditions of sintering process. The application of the temperature of 1500*C ± 50*C and pressure of 7.2 ± 0.2 GPa and time of 60 seconds permits to obtain the TiB2 ceramics without cracks. Practical implications: The TiB2 ceramic might be used for production of composites. From a practical position it is important to optimize the sintering densification of TiB2 ceramic. Originality/value: The TiB2 ceramics were formed using HP-HT technique without the use of additives. This method of sintering for TiB2 ceramics is original one.
Słowa kluczowe
Rocznik
Strony
687--690
Opis fizyczny
Bibliogr. 18 poz., il., tab., wykr.
Twórcy
autor
autor
autor
autor
  • Institute of Technology, Pedagogical University, ul. Podchorążych 2, 30-084 Kraków, Poland, isulima@ap.krakow.pl
Bibliografia
  • [1] L. Lu, M. O. Lai, H. Y. Wang, Synthesis of titanium diboride TiB2 and Ti-Al-B Metal matrix composites, Journal of the Materials Science 35 (2000) 241-248.
  • [2] J. F. Shackelford, Material Science and Engineering Handbook, Second Edition by CRC Press, 1994, Florida.
  • [3] C. C. Degnan, P. H. Shipway, The incorporation of selfpropagating, hightemperature synthesis-formed Fe-TiB2 into ferrous melt, Metallurgical and Materials Transactions A33 (2002) 2973-2983.
  • [4] W. Weimin, F. Zhengyi, W. Hao, Y. Runzhang, Influence of hot pressing sintering temperature and time on microstructure and mechanical properties of TiB2 ceramics, Journal of the European Ceramic Society 22 (2002) 1045-1049.
  • [5] V. I. Matkovich, Boron and Refractory Borides. Springer, Berlin, 1977.
  • [6] M. A. Einarrud, E. Hagen, G. Pettersen, T. Grande, Pressureless sintering of titanium diboride with nickel, nickel boride, and iron additives, Journal of the American Ceramic Society 80 (1997) 3013-3020.
  • [7] T. Venkateswaran, B. Basu, G. B. Raju, Doh-Yeon Kim, Densification and properties of transition metal boridesbased cermets via spark plasma sintering, Journal of the European Ceramic Society 26 (2006) 2431-2440.
  • [8] S. Ito, J. Nishii, Y. Takahashi, R. Nakamura, T. Furii, Transport phenomena in some solids under hipping pressure, Solid State Ionics 141-142 (2001) 301-306.
  • [9] G. S. Upadhyaya, Some issues in sintering science and technology, Materials Chemistry and Physics 67 (2001) 1-5.
  • [10] M. A. Meyers, A. Mishra, D. J. Benson, Mechanical properties of nanocrystalline materials, Progress in Materials Science 51 (2006) 427-556.
  • [11] J. Śleziona, J. Wieczorek, M. Dyzia, Mechanical properties of silver matrix composites reinforced with ceramic particles, Journal of Achievements in Materials and Manufacturing Engineering 17 (2006) 165-168.
  • [12] L. A. Dobrzański, M. Kremzer, A. Nagel, B. Huchler, Fabrication of ceramic preforms based on Al2O3 CL 2500 powder, Journal of Achievements in Materials and Manufacturing Engineering 18 (2006) 71-74.
  • [13] R. Konigshofer, S. Furnsinn, P. Steinkellner, W. Lengauer, R. Haas, K. Rabitsch, M. Scheerer, Solid-state properties of hot-pressed TiB2 ceramics, International Journal of Refractory Metals & Hard Materials 23 (2005) 350-357.
  • [14] M. Rosso, Ceramic and metal matrix composite, route and properties, Proceedings of the 12th International Scientific Conference on „Achievements in Mechanical and Materials Engineering” AMME'2003, Gliwice-Zakopane, 2003.
  • [15] W. M. Wang, Z. Y. Fu, Self-propagating high-temperature synthesis of TiB2 powder, Journal of Wuhan University of Technology 10 (1995) 34-39.
  • [16] J. Jaroszewicz, A. Michalski, TiB2 sinters produced of titanium and boron powders using the pulse plasma sintering method, Ceramic 84 (2004) 289-295.
  • [17] J. Jaroszewicz, A. Michalski, Preparation of a TiB2 composite with a nickel matrix by pulse plasma sintering with combustion synthesis, Journal of the European Ceramic Society 26 (2006) 2427-2430.
  • [18] L. Jaworska: Receiving and application of diamond in machining, WNT, Warsaw, 2007.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAN-0002-0024
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