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Purpose: In the paper the results of chemical composition investigations of passive layers formed on implants made of Cr-Ni-Mo steel, Co-Cr-W-Ni alloy and Ni-Ti alloy have been presented. Design/methodology/approach: Chemical composition investigations of the passive layer have been carried out with the use of X-ray Photoelectron Spectroscopy (XPS). The X-ray photoelectron spectroscopy with monochromatic radiation AlK α of 1486,6 eV was applied. The tests were carried out on the samples of polished as well as polished and passivated surfaces. The measurement of photoelectron spectrum in the wide range of binding energy from 0-1400 eV and precise measurements of the spectrum lines of elements from the surface layer were conducted. Findings: The chemical composition analysis of passive layers on the Cr-Ni-Mo steel, the Co-Cr-W-Ni alloy and the Ni-Ti alloy has revealed the presence of the following elements: (C, N, O, Na, Mg, Ca, Cr, Fe, Ni), (C, O, N, Cr, Fe, Co, Ni, W) and (C, N, O, Na, Si, S, Cl, K, Ca, Ti, Ni) respectively. Research limitations/implications: The research was carried out on samples, not on final parts. The tests were carried out in in vitro conditions. The obtained results are promising however further studies, in particular in blood environment, will determine a usefulness of the suggested technique of stents' surface improvement. Originality/value: The obtained results show the usefulness of the applied surface treatment to refine surfaces of implants made of the Cr-Ni-Mo steel, the Co-Cr-W-Ni alloy and the Ni-Ti alloy.
Słowa kluczowe
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Rocznik
Tom
Strony
273--276
Opis fizyczny
Bibliogr. 16 poz., wykr.
Twórcy
autor
autor
autor
- Division of Biomedical Engineering, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, witold.walke@polsl.pl
Bibliografia
- [1] Z. Paszenda, Issues of metal materials used for implants in interventional cardiology, Engineering of Biomaterials 21 (2002) 3-9.
- [2] A. Krauze, A. Ziębowicz, J. Marciniak, Corrosion resistance of intramedullary nails used in elastic osteosynthesis of children, Journal of Materials Processing Technology 162-163 (2005) 209-214.
- [3] W. Kajzer, A. Krauze, W. Walke, J. Marciniak, Corrosion resistance of Cr-Ni-Mo steel in simulated body fluids, Journal of Achievements in Material and Manufacturing Engineering 18, 1-2 (2006) 115-118.
- [4] Z. Paszenda, J. Tyrlik-Held, Corrosion resistance investi-gations of coronary stents made of Cr-Ni-Mo steel, Proceedings of the 10th International Scientific Conference „Achievements in Mechanical and Materials Engineering” AMME’2001, Gliwice-Kraków-Zakopane, 2001, 453-460.
- [5] Z. Paszenda, J. Tyrlik-Held, Forming the physicochemical properiteis of coronary stents surface, Proceedings of the 13th Conference of the European Society of Biomechanics ESB2002, Wrocław, 2002, 539-540.
- [6] Z. Paszenda, J. Tyrlik-Held, Coronary stents with passive and carbon layers. Proceedings of the 17th European Conference on Biomaterials ESB2002, Barcelona, 2003, 89.
- [7] M. Kaczmarek, J. Tyrlik-Held, Z. Paszenda, J. Marciniak, Characteristics of stents in application and material aspect, Proceeding of the 12th International Scientific Conference „Achievements in Mechanical and Materials Engineering” AMME’2003, Gliwice-Zakopane, 2003, 421 428.
- [8] J. Marciniak, Biomaterials, Printing House of the Silesian University of Technology, 2002.
- [9] J. Marciniak et al., Stents in minimally invasive surgery, Printing House of the Silesian University of Technology, 2006 (in Polish).
- [10] W. Walke, Z. Paszenda, J. Tyrlik-Held, Corrosion resistance and chemical composition investigations of passive layer on the implants surface of Co-Cr-W-Ni alloy, Journal of Achievements in Materials and Manufacturing Engineering 16 (2006) 74-79.
- [11] I. K. Stefanidis, V. A. Tolis, D. G. Sionis, L. K. Michalis, Development in Intracoronary Stents, Hellenic Journal of Cardiology 43 (2002) 63-67.
- [12] U. Sigwart, J. Puel et al., Intraluminal stents to prevent occlusion and restenosis after transluminal angioplasty, Journal of Medicine 316 (1987) 701-706.
- [13] K. Christensen, R. Larsson et al., Heparin coating of the stent graft-effects on plateles, coagulation and comple-ment activation. Biomaterials 22 (2001) 349-355.
- [14] M. Kaczmarek, W. Simka, A. Baron, J. Szewczenko, J. Marciniak, Electrochemical behavior of Ni-Ti alloy after surface modification, Journal of Achievements in Materials and Manufacturing Engineering 18 (2006) 111-114.
- [15] A. Michiardi, C. Aparicio, J. A. Planell, F. J. Gil, Electro-chemical behaviour of oxidized NiTi shape memory alloys for biomedical applications, Surface & Coatings Technology 201(2007) 6484-6488.
- [16] S. Shabalovskaya, Surface, corrosion and biocompatibility aspects of Nitinol as an implant material, Bio-Medical Materials and Engineering 12 (2002) 69-109.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAN-0001-0034
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