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Butadiene-acrylonitrile elastomers as PVC modifiers

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Języki publikacji
EN
Abstrakty
EN
Purpose: The purpose of the paper is to present the results of research programme on influence of acrylonitrilebutadiene copolymers on plasticized polyvinylchloride compounds used as window gasket material. Design/methodology/approach: Short review concerning application of modified plasticized PVC compounds as gasket material was presented. In experimental part two types of acrylonitrile-butadiene copolymers were used as elastomeric plasticizers for PVC. Formulations with fifteen different levels of elastomeric modifiers content (up to 25% by weight) were prepared and tested. As reference formulations three commercial compounds were additionally tested. Shore hardness, short-term and long-term elastic recovery, tensile strength, elongation at break and migration of plasticizers from gasket material to unplasticized PVC were searched. Findings: Incorporation of acrylonitrile-butadiene copolymers into PVC enhanced many properties essential for its application as window gasket material. The most important changes occurred for long-term and short term elastic recovery, tensile strength and elongation at break. At the same time addition of these butadiene-acrylonitrile elastomers did not change migration of other plasticizers contained in gasket material into rigid PVC in being in contact with gasket. Obtained results showed that among tested compounds best properties as gasket material exhibited plasticized PVC with 23% of acrylonitrile-butadiene copolymer Chemigum P83. Reference commercial formulations exhibited worse performance properties than new compounds with this acrylonitrile-butadiene copolymer. Practical implications: Research programme allowed to elaborate plasticized PVC compounds modified with acrylonitrile-butadiene copolymer that can be industrially applied for PVC window gaskets. Originality/value: Obtained results are of scientific and practical value. Research programme allowed to investigate the influence of elastomeric modifiers on plasticized PVC properties. Research results are also of practical importance.
Rocznik
Strony
41--48
Opis fizyczny
Bibliogr. 17 poz., il., wykr.
Twórcy
autor
autor
  • Division of Metal and Polymer Materials Processing, Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland, jozef.stabik@polsl.pl
Bibliografia
  • [1] K. Flaga, Advances in materials applied in civil engineering, Journal of Materials Processing Technology 106 (2000) 173-183.
  • [2] F. Kamisli, C. Turan, A study on usability of magnesium oxide with titanium dioxide in PVC door and window profiles, Journal of Materials Processing Technology 159 (2005) 40-47.
  • [3] Technical catalogue of window gaskets, AIB, 2005, Knurów Poland (in Polish).
  • [4] S. Ramakrishna, Z. Ming Huang, H. M. Yew, Development of a novel flexible composite material, Journal of Materials Processing Technology 89-90 (1999) 473-477.
  • [5] J. R. Pena, M. Hidalgo, C. Mijangos, Plastification of poly (vinyl chloride) by polymer blending, Journal of Applied Polymer Science 75 (2000) 1303-1312.
  • [6] D. Dickmann, Plasticizers, Modern Plastics Encyclopedia’91 McGraw Hill, New York 1990, 202-208.
  • [7] G. Wypych, Handbook of Plasticizers, ChemTec Publishing, 2004.
  • [8] G. Wu, J. Zhao, H. Shi, H. Zhang, The influence of coreshell structured modifiers on the toughness of poly (vinyl chloride) grafted copolymer of polybutadiene and polymethyl methacrylate, European Polymer Journal 40 (2004) 2451-2456.
  • [9] M. Rahman, C. S. Brazel, The plasticizer market an assessment of traditional plasticizers and research trends to meet new challenges, Progress in Polymer Science 29 (2004) 1223-1248.
  • [10] A. Hassan, B. Hawotrh, Impast properties of acrylate rubber-modified PVC: Influence of temperature, Journal of Materials Processing Technology 172 (2006) 341-345.
  • [11] M. Rojek, J. Stabik, Modification of PVC compounds with butadiene-acrylonitrile elastomers, Journal Achievements in Materials and Manufacturing Engineering 17 (2006) 141-144.
  • [12] M. Obłój-Muzaj, B. Świerz-Motysia, B. Szabłowska, Polyvinyl chloride, WNT, Warszawa 1997 (in Polish).
  • [13] S.-H. Zhu, C. M. Chan, S. C. Wong, Y. W. Mai, Mechanical properties of PVC/SBR blends compatibilized by acrylonitrile-butadiene rubber and covulcanization, Polymer. Engineering Science, 39 (1999) 1998-2006.
  • [14] L. Zhou, X. Wang, Y. Lin, J. Yang, Q. Wu, Comparison of the toughening mechanisms of poly (vinyl chloride)/chlorinated polyethylene and poly(vinyl chloride)/acrylonitrile-butadiene-styrene copolymer blends, Journal of Applied Polymer Science 90 (2003) 916-924.
  • [15] A. de Zarraga, S. Villanueva, M. E. Muńoz, R. Obeso, J. J. Peńa, B. Pascual, A. Santamaría, Ternary Blends to Improve Heat Distortion Temperature and Rheological Properties of PVC, Macromolecular Materials and Engineering 289 (2004) 648-652.
  • [16] B. Jurkowski, B. Jurkowska, Preparing of polymeric compounds WNT Warszawa 1995 (in Polish).
  • [17] N. R. Manoj, P. P. De, An investigation of the chemical interactions in blends of poly (vinyl chloride) and nitrile rubber during processing, Polymer 39 (1998) 733-741.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAN-0001-0007
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