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Luminescence and structural properties of thermally evaporated benzanthrone dyes thin films

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Języki publikacji
EN
Abstrakty
EN
We report optical and luminescence properties of 3-N, N-diacetylaminobenzanthrone thin films deposited on glass substrate by thermal evaporation. The structural and optical properties of organic thin films were studied by means of the confocal microscope with an input of femtosecond laser radiation, X-ray diffractometer, and scanning electron microscope (SEM). Intense luminescence with the maximum at 530 nm was observed when excited by laser radiation with the wavelengths 458, 476, 488, 496, 514 nm. In addition, the luminescence caused by two-photon absorption of femtosecond (fs) laser radiation has been investigated. Semi empirical calculations by AM1 and ZINDO/S methods and ab initio calculations using Gaussian software were carried out to estimate the electron system of structure. The calculations show planar configurations for the aromatic core and diacetylamino fragment of this compound. The study of the structure of benzanthrone derivative thin films with X-ray diffraction (XRD) methods, indicates the distance between molecular layers and ordered molecular fragments.
Rocznik
Strony
227--232
Opis fizyczny
Bibliogr. 14 poz., rys., il., wykr.
Twórcy
autor
autor
autor
autor
autor
  • Innovative Microscopy Center, Daugavpils University, 13 Vienibas Str., LV-5400, Daugavpils, Latvia, bulanov@inbox.lv
Bibliografia
  • 1. J. Kalinowski, „Optical materials for organic light-emitting devices”, Opt. Mater. 30, 792-799 (2008).
  • 2. N. Koch, „Organic electronic devices and their functional interfaces”,Chem. Phys. Chem. 8, 1438-1455 (2007).
  • 3. L. S. Hung and C. H. Chen, „Recent progress of molecular organic electroluminescent materials and devices”, Mater. Sci. Eng. R 39, 143-222 (2002).
  • 4. L. D. Carlos, R. A. S. Ferreira, and V. de Zea Bermudez, „Hybrid materials for optical applications”, in: Synthesis, Characterization and Applications, edited by G. Kickelbick, Hybrid Materials, Wiley-VCH, pp. 337-398, Weinheim, 2007.
  • 5. E. Kirilova, S. Belyakov, G. Kirilov, I. Kalnina, and V. Gerbreder, „Luminescent properties and crystal structure of novel benzanthrone dyes”, J. Lumin. 129, 1827-1830 (2009).
  • 6. M. J. S. Dewar, E. G. Zoebisch, E. F Healy, and J. J. P. Stewart, „AM1: a new general purpose. Quantum mechanical molecular model”, J. Am. Chem. Soc. 107, 3902-3909 (1985).
  • 7. J. Ridley and M. Zerner, „An intermediate neglect of differential overlap technique for spectroscopy: pyrrole and the azines”, Theor. Chim. Acta 32, 111 (1973).
  • 8. R. G. Parr and W. Yang,Density-Functional Theory of Atoms and Molecules. Oxford University Press, Oxford, 1989.
  • 9. B. Siddlingeshwar, S. M. Hanagodimath, E. M. Kirilova, and G. K. Kirilov, „Photophysical characteristics of three novel benzanthrone derivatives: Experimental and theoretical estimation of dipole moment”, J. Quant. Spectrosc. Radiat. Transfer 112, 448-456 (2011).
  • 10. P. Bentley, J. F. McKellar, and G. O. Phillips, „The photochemistry of benz[de]anthracen-7-ones. Part I. Electronic absorption and emission spectroscopy”, J. Chem. Soc. Perkin Trans. 2, 523 (1974).
  • 11. R. N. Nurmukhametov, „The electronic absorption and luminescence spectra of n-hetero-aromatic compounds and their derivatives”, Russian Chem. Rev. 36, 693 (1967).
  • 12. P. Kapusta, O. Machalicky, R. Hrdina, M. Nepras, M. B. Zimmt, and V. Fidler, „Photophysics of 3-substituted benzanthrones: substituent and solvent control of intersystem crossing”, J. Phys. Chem. A 107, 9740 (2003).
  • 13. S. Liu, K. S. Lin, V. Churikov, Y. Z. Su, J. T. Lin, T. H. Huang, and C. C. Hsu, „Two-photon absorption properties of star-shaped molecules containing peripheral diarylthienylamines”, Chem. Phys. Lett. 390, 433-439 (2004).
  • 14. E. M Kirilova, S. V Belyakov, and I. Kalnina, „Synthesis and study of N,N-substituted 3-amidinobenzanthrones”, in: Topics in Chemistry & Material Science, edited by G. Vayssilov and R. Nikolova, Heron Press, 3, pp. 19-28, Sofia, 2009.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAD-0033-0019
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