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Properties of a-Si:N:H films beneficial for silicon solar cells applications

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Języki publikacji
EN
Abstrakty
EN
Amorphous silicon-nitride thin films a-Si:N:H were obtained by plasma enhanced chemical vapour deposition (PECVD) method from SiH₄+NH₃ at 13.56 MHz. The process parameters were chosen to obtain the films of properties suitable for optoelectronic and mechanical applications. FTIR analysis of a-Si:N:H films indicated the presence of numerous hydrogen bonds (Si-H and N-H) which passivate structural defects in multicrystalline silicon and react with impurities. The morphological investigations show that the films are homogeneous. The deposition of a-Si:N:H layers leads to the decrease in friction coefficient of used substrates. Optical properties were optimised to obtain the films of low effective reflectivity, large energy gap Eg from 2.4 to 2.9 eV and refractive index in the range of 1.9 to 2.2. Reduction of friction coefficient for monocrystalline silicon after covering with a-Si:N:H films was observed: from 0.25 to 0.18 for 500 cycles.
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autor
autor
  • Department of Electronics, AGH University of Science and Technology, 30 Mickiewicza Ave., 30-059 Cracow, Poland, swatow@agh.edu.pl
Bibliografia
  • [1] B. Sopori: Dielectric films for Si solar cell applications. J. Electron. Mater. 34, 564-570 (2005).
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  • [3] S. Jonas, P. Rava, T. Stapinski, and E. Walasek: UHV plasma enhanced CVD system for preparation of new generation amorphous silicon based efficient solar cells. Opto-Electron. Rev. 9, 91-95 (2001).
  • [4] F. Giorgis, F. Giuliani, C. F. Pirri, E. Tresso, C. Summonte, R. Rizzoli, R. Galloni, A. Desalvo, and P. Rava: Optical, structural and electrical properties of device quality a-Si1-xNx:H films grown by plasma enhanced chemical vapour deposition. Phil. Mag. 77, 925-944 (1998).
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  • [6] B. Swatowska and T. Stapinski: Amorphous hydrogenated silicon-nitride films for applications in solar cells. Vacuum 82, 942-946 (2008).
  • [7] J. Meneve, E. Dekempeneer, S. Kuypers, R. Jacobs, and J. Smeets: Substrate bias effect on the tribological properties of a-Si1-xCx:H films. Diam. Relat. Mater. 4, 366-369 (1995).
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  • [9] B. Swatowska, H. Czternastek, M. Lipinski, T. Stapinski, and K. Zakrzewska: Antireflective coatings of a-Si:C:H on silicon. Proc. the 28th IMAPS Poland Chapter Conf. Wrocław, 385-388 (2004).
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  • [12] K. C. Sahoo, M. K. Lin, E. Y. Chang, C. C. Chen, J. H. Huang, and C. W. Chang: Fabrication of antireflective sub-wave-length structures on silicon nitride using nano cluster mask for solar cell application. Nanoscale Res. Lett. 4, 680-683 (2009).
  • [13] B. Swatowska and T. Stapinski: Influence of properties of amorphous a-Si:C:H coatings on parameters of silicon solar cells - theoretical simulation. Proc. 30th IMAPS Poland Chapter Conf., Cracow, 463-466 (2006).
  • [14] B. Swatowska, T. Stapinski, and S. Zimowski: Influence of properties of amorphous a-Si:N:H coatings on parameters of silicon solar cells. Proc. 31st IMAPS Poland Chapter Conf., Rzeszow-Krasiczyn, 405-408 (2007).
  • [15] R. Swanepol: Determination of the thickness and optical constants of amorphous silicon. J. Phys. E. Sci. Instrum. 16, 1214-1222 (1983).
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  • [18] B. Sopori: Silicon nitride processing for control of optical and electronic properties of silicon solar cells. J. Electron. Mater. 32, 1034-1042 (2003).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAD-0027-0009
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