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Experimental studies of the dielectric properties in the nematic and isotropic phases of 4-cyanophenyl-4'-n-octylbenzoate (8CPB) have been performed in the frequency range from 50 kHz to 100 MHz. The relaxation process related to the rotation around the short molecular axis has been analysed. The results obtained have revealed that in the vicinity of the I-N phase transition, the molecular subdiffusional rotation process occurs. It is connected with the pretransitional effects which are observed both in the static and dynamic dielectric measurements. On the basis of the temperature dependence of the relaxation time in the nematic and isotropic phases, the orientational order parameter < P2 > has been determined. The values of < P2 > obtained in this way have been compared with those evaluated from the measurements of the polarized electronic absorption of the dichroic dye, dissolved as guest probe in the mesogenic host.
Wydawca
Czasopismo
Rocznik
Tom
Strony
63--70
Opis fizyczny
Bibliogr. 41 poz., wykr.
Twórcy
autor
autor
autor
autor
autor
- Faculty of Technical Physics, Poznań University of Technology, 13a Nieszawska Str., 60-965 Poznań, Poland, bauman@phys.put.poznan.pl
Bibliografia
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- [2] H. Kresse: Dielectric behaviour of liquid crystals. in Advances in Liquid Crystals, Vol. 6, pp. 109-172, edited by G.H. Brown, Academic Press, New York, 1983.
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- [4] D. Dunmur: Introduction to dielectric relaxation in anisotropic fluids. in Relaxtion Phenomena, pp. 163-181, edited by W. Haase and S. Wróbel, Springer-Verlag, Berlin, 2003.
- [5] J. Jadżyn, U. Sokołowska and J. L. Déjardin: Temperature behaviour of the electric field-induced entropy increment within a homologous series of nematogenic compounds. J. Phys. Chem. B112, 9050-9052, 2008.
- [6] J. Jadżyn, J. Świergiel, D. Bauman, R. Dąbrowski, K. Czupryński and U. Sokołowska: Pretransitional dielectric properties of nematogenic 4-cyano-phenyl-4'-n-heptylbenzoate. Phase Transit. 82, 409-419, 2009.
- [7] J. Jadżyn, G. Czechowski, J. L. Déjardin and M. Ginovska: Anomalous rotational diffusion in the vicinity of the isotropic to nematic phase transition. J. Phys.: Condens. Mat. 17, 813-819, 2005.
- [8] J. Jadżyn, J. L. Déjardin and G. Czechowski: Singular pretransitional behaviour of the electric field-dependent part of the thermodynamic quantities of strongly polar mesogenic liquids in the isotropic phase. Acta Phys. Pol. A111, 877-884, 2007.
- [9] N. Bielejewska, E. Chrzumnicka, E. Mykowska, R. Przybylski, M. Szybowicz, K. Władysiak and D. Bauman: Comparative study of orientational order of some liquid crystals from various homologous series. Acta Phys. Pol. A110, 777-793, 2006.
- [10] M. Ginovska, H. Kresse, D. Bauman, G. Czechowski and J. Jadżyn: Static and dynamic dielectric behaviour of mesogenic compounds of different polarity in the vicinity of the isotropic to nematic phase transition. Phys. Rev. E69, 022701:1-4, 2004.
- [11] G. Czechowski, unpublished data.
- [12] D. Bauman, E. Chrzumnicka, E. Mykowska, M. Szybowicz and N. Grzelczak: Study of orientational order of some mesogenic compounds by spectroscopy methods using linearly polarized light. J. Mol. Struct. 744/747, 307-313, 2005.
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- [21] J. Jadżyn and G. Czechowski: Interactions and dynamics of mesogenic molecules in the vicinity of the isotropic to nematic phase transition. J. Mol. Struct. 844/845, 59-63, 2007.
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- [23] J. Jadżyn and G. Czechowski: Prenematic behaviour of the electric-field-induced increment of the basic thermodynamic quantities of isotropic mesogenic liquids of different polarity. J. Phys. Chem. B111, 3727-3729, 2007.
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- [36] E. Wolarz, Molecular Orientation and Dynamics in Doped Liquid-Crystalline Polymers and Liquid-Crystal Dimers, Habilitation Dissertation, Poznań, 2005. (in Polish)
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- [38] A. V. Ivashenko and V. G. Rumyantsev: Dyes in liquid crystals. Mol. Cryst. Liq. Cryst. 150A, 1-167, 1987.
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- [41] D. Bauman and H. Moryson: Guest-host interactions in dichroic dye-liquid crystal mixture in smectic A and nematic phases. J. Mol. Struct. 404, 113-118, 1997.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAD-0018-0006