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Exposure and temperature dependences of contact angle of liquid crystals on photoaligning surface

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EN
Abstrakty
EN
We report on first studies of wetting of liquid crystal on photoaligning surface. We observed strong light-induced variations of a contact angle of a liquid LC 5CB on a photoaligning surface of fluoro-polyvinyl-cinnamate (PVCN-F) and we connected these variations with changes of PVCN-F polarity. We also present drastic changes of the contact angle of a nematic liquid crystal (MLC-6080) on the PVCN-F surface in a vicinity of temperature anchoring transition of liquid crystal from homeotropic orientation to planar one. We did not find any peculiarities in temperature dependence of the contact angle of isotropic liquid (glycerol) on PVCN-F and of nematic liquid crystal on pure glass in the same temperature range. It allows us to suggest that rearrangement of LC molecules and flexible fragments in the LC-polymer interface are responsible for the change of surface tensions both of LC and polymer and the observed jump of the contact angle.
Twórcy
autor
autor
  • Institute of Physics, National Academy of Sciences of Ukraine, 46 Nauky Prospect, 03-028 Kyiv, Ukraine, kurioz@iop.kiev.ua
Bibliografia
  • [1] L. T. Creagh and A. R. Kmetz: Mechanism of surface alignment in nematic liquid crystals. Substrate surface effects. Mol. Cryst. Liq. Cryst. 24, 59-68, 1973.
  • [2] J. Cognard, Alignment of Nematic Liquid Crystals and Their Mixtures, Gordon and Breach, Science Publishers, New York, 1982.
  • [3] W. Gibbons, P. Shannon, S. T. Sun, and B. Swetlin: Surface-mediated alignment of nematic liquid crystals with polarized laser light. Nature 351, 49-50, 1991.
  • [4] A. G. Dyadyusha, V. M. Kozenkov, T. Ya. Marusii, Yu. O. Reznikov, V. Yu. Reshetnyak, and A. I. Khizhnyak: Light-induced planar alignment of nematic liquid crystal by the anisotropic surface without mechanical texture. Ukr. Fiz. Zh. 36, 1059-1062, 1991.
  • [5] M. Schadt, K. Schmitt, V. Kozenkov, and V. Chigrinov: Surface-induced parallel alignment of liquid crystals by linearly polymerized photopolymers. Jpn. J. Appl. Phys. 31, 2155-2164, 1992.
  • [6] D. Andrienko, A. Dyadyusha, Yu. Kurioz, Yu. Reznikov, F. Barbet, D. Bormann, M. Warenghem, and B. Khelifa: Photoalignment of pentyl-cyanobiphenyl on the fluorinated polyvinil-cinnamates induced by UV and visible light. Mol. Cryst. Liq. Cryst. 329, 219-226, 1999.
  • [7] L. Bugayova, I. Gerus, A. Glushchenko, A. Dyadyusha, Yu. Kurioz, V. Reshetnyak, and Yu. Reznikov: Non-monotonic exposure dependence of the pretilt angle and surface polarity of the photo-orientant F-PVCN. Liq. Cryst. 29, 209-212, 2002.
  • [8] Yu. Kurioz, D. Kurysh, V. Reshetnyak, and Yu. Reznikov: Temperature induced anchoring transition in nematic liquid crystal cell. Proc. SPIE 5257, 128-132, 2003.
  • [9] A. Dyadyusha, A. Khizhnyak, T. Marusii, Yu. Reznikov, O. Yaroshchuk, V. Reshetnyak, W. Park, S. Kwon, H. Shin, and D. Kang: An oblique orientation of nematic liquid crystals on a photosensitive aligning polymer. Mol. Cryst. Liq. Cryst. 263, 399-413, 1995.
  • [10] A. W. Adamson and A. P. Gast, Physical Chemistry of Surfaces, Sixth edition, A Wiley-Interscience Publication, New York, 1997.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWAD-0016-0033
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