Otrzymywanie i badanie właściwości 1,1,2,2-tetranitroaminoetanu

• Autorzy: Szala M. , Szymańczyk L.

Warianty tytułu

EN

Synthesis and properties of 1,1,2,2-tetranitroaminoethane

• Języki publikacji: PL

Abstrakty

PL

1,1,2,2-tetranitroaminoetan (TNAE) o wysokiej czystości otrzymano w wyniku zasadowej hydrolizy tetranitroglikolurylu z wydajnością wynoszącą 61% wydajności teoretycznej. Strukturę produktu określono na podstawie wyników badań spektroskopowych (1H, 13C NMR, IR). Tetranitroaminoetan rozkłada się egzotermicznie w temperaturze 143°C. Wrażliwość na tarcie TNAE wynosi 160 N, a na uderzenie 1 J. Obliczone wartości prędkości i ciśnienia detonacji TNAE dla gęstości 1,84 g/cm3 wynoszą odpowiednio 9570 m/s i 41,2 GPa.

EN

The known methods of tetranitroaminoethane (TNAE) synthesis are reviewed. The reaction path starting from easily available substrates and giving the highest yield of TNAE was chosen to produce this compound at a laboratory scale. Solid product of base promoted hydrolysis of tetranitroglycoluril was analyzed using elemental analysis and 1H, 13C NMR. Friction and impact sensitivity of product was examined. Heat of combustion was measured and standard enthalpy of formation was calculated. Detonation parameters were calculated using special thermochemical code.

Słowa kluczowe

PL

tetranitroaminoetan; materiały wysokoenergetyczne; nitroaminy

EN

tetranitroaminoethane; high energetic materials; nitroamines

• Wydawca: Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
• Czasopismo: Biuletyn Wojskowej Akademii Technicznej
• Rocznik: 2012
• Tom: Vol. 61, nr 2
• Strony: 257--267
• Opis fizyczny: Bibliogr. 19 poz., tab., wykr.

Twórcy

autor

Szala M.

autor

Szymańczyk L.

• Wojskowa Akademia Techniczna, Wydział Nowych Technologii i Chemii, 00-908 Warszawa, ul. S. Kaliskiego 2,

Bibliografia

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