Zastosowanie TLC do monitorowania syntezy 1,1-diamino-2,2-dinitroetenu

• Autorzy: Błądek J. , Cudziło S. , Pietrzyk S. , Chyłek Z.

Warianty tytułu

EN

Application of TLC for monitoring of 1,1-diamino-2,2-dinitroethene synthesis

• Języki publikacji: PL

Abstrakty

PL

Przedstawiono wyniki doświadczeń nad zastosowaniem instrumentalnej chromatografii cienkowarstwowej (TLC) do oznaczania 1,1-diamino-2,2-dinitroetenu (DADNE), 2-metylopirymidyna- 4,6-dionu (substrat) oraz związków przejściowych, otrzymywanych w trakcie syntezy DADNE. Wyznaczono parametry analityczne ww. substancji oraz metodykę ich oznaczeń. Wykazano możliwość zastosowania TLC do monitorowania procesu technologicznego.

EN

The paper presents investigation results on application of thin layer chromatography (TLC) for determination of 1,1-diamino-2,2-dinitoethene (DADNE), its substrate and intermediate products produced in the synthetic path starting from 2-methyl-pyrimidine-4,6-dione. Analytical parameters of the substances and methodology of their quantitative analysis were determined. The developed methods were used for controlling the DADNE synthesis process.

Słowa kluczowe

PL

1,1-diamino-2,2-dinitroeten; produkty pośrednie; analiza; TLC

EN

1,1-diamine-2,2-dinitroethane; intermediate products; analysis; TLC

• Wydawca: Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
• Czasopismo: Biuletyn Wojskowej Akademii Technicznej
• Rocznik: 2006
• Tom: Vol. 55, nr 4
• Strony: 283--290
• Opis fizyczny: Bibliogr. 16 poz., wykr.

Twórcy

autor

Błądek J.

autor

Cudziło S.

autor

Pietrzyk S.

autor

Chyłek Z.

• Wojskowa Akademia Techniczna, Wydział Nowych Technologii i Chemii, Instytut Chemii, 00-908 Warszawa, ul. S. Kaliskiego 2

Bibliografia

• [1] B. JANZON, H. BERGMAN, C. ELDSATER, C. LAMNEVIK, H. OSTMARK, FOX-7 - a novel, high performance, low-vulnerability high explosive for warhead applications, 20th International Symposium on Ballistcs, Orlando, FL, USA, 23-27.09.2003.
• [2] Y. N. MATYUSHIN, G. T. AFANASEV, V. P. LEBEDEV, M. N. MAHOV, V. I. PEPEKIN, TATB and FOX-7: thermochemistry, performance, detonability, sensitivity, 34th International Annual Conference of ICT, Karlsruhe, Germany, 24-27.06.2003.
• [3] H. OSTMARK, A. LANGLET, H. BERGMAN, N. WINGBORG, U. WELLMAR, U. BEMM, FOX-7 - a new explosive with low sensitivity and high performance, 11th International Symposium on Detonation, Snowmass, CO, USA, 1998.
• [4] U. BEMM, H. OSTMARK, 1,1-Diamino-2,2-dinitroethylene - a novel energetic material with infinite layers in two dimensions, Acta Cryst., C54, 1998, 1997-1998.
• [5] A. GINDULYTE, L. MASSA, L. HUANG, J. KARLE, Proposed mechanism of 1,1-diamino-2,2-dinitroethylene decomposition: A functional theory study, J. Phys. Chem. A, 103, 1999, 11045-11051.
• [6] N. LATYPOV, J. BERGMAN, A. LANGLET, U. WELLMAR, U. BEMM, Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene, Tetrahedron, 54, 1998, 11525-11536.
• [7] N. LATYPOV, A. LANGLET, U. WELLMAR, Chemical compound suitable for use as an explosive, intermediate and method for preparing the compound, US Patent 6 312 538 B1, Nov. 6, 2001.
• [8] H. OSTMARK, H. BERGMAN, U. BEMM, P. GOEDE, E. HOLMGREN, M. JOHANSSON, A. LANGLET, N. LATYPOV, A. PETTERSSON, M-L PETTERSSON, N. WINGBORG, C. VORDE, H. STENMARK, L. KARLSSON, M. HIHKIO, 2,2-dinitro-ethene-1,1-diamine (FOX-7) - properties, analysis and scale-up-32nd International Annual Conference of ICT, Karlsruhe, Germany, 2001.
• [9] A. A. ASTRATIEV, A. DASHKO, D. MERSHIN, A. STEPANOV, A. URAZGILDIEV, Russian Journal of Organic Chemistry, 37, 2001, 729-733.
• [10] E. HOLMGREN, H. CARLSSON, P. GOEDE, N. LATYPOV, C. CRESCENZI, Characterization of FOX-7, its precursors and possible byproducts, 34th International Annual Conference of ICT, Karlsruhe, Germany, 24-27.06.2003.
• [11] U. TICMANIS, M. KAISER, G. PANTEL, I. FUHR, U. TEIPEL, Kinetics and chemistry of thermal decomposition of FOX-7, 35th International Annual Conference of ICT, Karlsruhe, Germany, 2004.
• [12] P. B. KEMPA, M. HERRMANN, F. J. MOLINA METZGER, V. THOME, A. KJELLSTROM, N. LATYPOV, Phase transitions of FOX-7 studied by X-ray diffraction and thermal analysis, 35th International Annual Conference of ICT, Karlsruhe, Germany, 2004.
• [13] N. V. GARMASHEVA, I. V. CHEMAGINA, V. P. FILIN, M. B. KAZAKOVA, G. B. LOBOIKO, Investigation of diaminodinitroethylene, New Trends in Research of Energetic Materials, Pardubice, Czech Republic, 2004, 116-122.
• [14] R. WILD, U. TEIPEL, Characterization and explosive properties of FOX-7, 35th International Annual Conference of ICT, Karlsruhe, Germany, 2004.
• [15] U. TEIPEL, I. FUHR, K. HARTLIEB, A. KJELLSTROM, C. ELDSATER, Crystallization of 1,1-diamino-2,2-dinitroethylene A(FOX-7), 35th International Annual Conference of ICT, Karlsruhe, Germany, 2004.
• [16] S. CUDZIŁO, W. KICIŃSKI, Properties and preparation of DADNE (in Polish), Biul. WAT, 53 (2-3), 2004, 183-200.