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Mesomorphic, dielectric, and optical properties of fluorosubstituted biphenyls, terphenyls, and quaterphenyls

Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Konferencja
Conference on Liquid Crystals : Chemistry, Physics and Applications ; (17 ; 09.2007 ; Augustów, Poland)
Języki publikacji
EN
Abstrakty
EN
Compounds with moderate and large negative dielectric anisotropy (Δ ε ) are very attractive liquid crystal (LC) for vertical alignment mode (VA). Materials with such properties can be achieved by lateral substitution of a polar group into a mesogenic molecule. We synthesized some new LC materials with a negative value of Δ ε, a moderately high birefringence (Δ n), and a low viscosity. The mesomorphic and physical behaviour of the novel biphenyls, terphenyls and quaterphenyls fluorosubstituted in the rigid core and also with fluorinated alkyl and alkoxy chains are investigated. The prepared series of four LC compounds are promising for new LC mixtures for various applications. Examples of nematic mixtures with Δ ε ∼ -3.25 will be presented.
Twórcy
autor
autor
autor
autor
  • Institute of Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warsaw, Poland, pkula@wat.edu.pl
Bibliografia
  • 1. V. Reiffenrath, J. Krause, H.J. Plach, and G. Weber, “New liquid-crystalline compounds with negative dielectric anisotropy”, Liq. Cryst. 5, 159-170 (1989).
  • 2. P. Kirsch and M. Bremer, “Nematic liquid crystals for active matrix displays: molecular design and synthesis”, Angew. Chem. Int. Edit. 39, 4216-4235 (2000).
  • 3. D. Pauluth and K. Tarumi, “Optimization of liquid crystals for television”, J. SID 13, 693-701 (2005).
  • 4. K. Ohmura, S. Kataoka, T. Sasaki, and Y. Koike, “Development of super-high image quality vertical alignment mode LCD”, SID'97 Digest, 845-848 (1997).
  • 5. M. Hird, J.W. Goodby, and K.J. Toyne, “Nematic materials with negative anisotropy for display applications”, Proc. SPIE 3955, 15-23 (2000).
  • 6. M.E. Glendenning, J.W. Goodby, M. Hird, and K.J. Toyne, “The synthesis and mesomorphic properties of 2,2',3-triand 2,2',3,3'-tetra-fluoro-1,1':4',1''-terphenyls for high dielectric biaxiality ferroelectric liquid crystal mixtures”,J. Chem. Soc. Perk. 2, 481-491 (1999).
  • 7. R. Dąbrowski, W. Drzewiński, J. Dziaduszek, J. Gąsowska, P.A. Henderson, P. Kula, J.M. Oton, and N. Bennis, “Orthoconic antiferroelectric liquid crystals containing biphenyl, terphenyl, or naphthyl mesogenic unit”,Opto-Electron. Rev. 15, 32-36 (2007).
  • 8. S.T. Wu, E. Ramos, and U. Finkenzeller, “Polarized UV spectroscopy of conjugated liquid crystals”, J. Appl. Phys. 68, 75-78 (1990).
  • 9. T. Ando, S. Matsui, K. Miyazawa, H. Takeuchi, Y. Koizumi, Y. Sekiguchi, E. Nakagawa, and F. Takeshita, “Preparation of liquid crystal compounds, liquid crystal compositions containing the compounds and liquid crystal display devices made by using the compositions”, Patent WO 9.736.847 (1997).
  • 10. G.W. Gray, M. Hird, D. Lacey, and K.J. Toyne, “The synthesis and transition temperatures of some 4,4”-dialkyl- and 4,4''-alkoxyalkyl -1,1':4',1”terphenyls with 2,3 or 2',3'-difluoro substituents and of the biphenyl analogue”, J. Chem. Soc. Perk. 2, 2041-205 (1989).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWA0-0036-0005
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