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Second harmonic generation in Ru-derivative chromophores incorporated within PMMA polymers stimulated by acoustic and optic fields

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Warianty tytułu
Konferencja
International Workshop on Nonlinear Optics Applications ; (7 ; 17-20.06.2004 ; Konstancin, Poland)
Języki publikacji
EN
Abstrakty
EN
We have demonstrated the co-existences of second harmonic generation (SHG) and χ (2) grating using acoustical and optical fields in Ru derivatives incorporated within the PMMA polymer matrices. The investigated compounds possess metastable trapping levels originated both from the d-states of Ru as well as the effective charge transfers due to the presence of p-conjugated states. The investigated compounds possess long-lived χ (2) grating which decreases less than 76% under 600 min of laser treatment. Electrostatic field causes additional reanimation of the SHG. Values of the acoustically induced optical second harmonic generation (AIOSHG) for the best Ru chromophres were substantially higher than for known pure inorganic materials. The effective value of the second-order optical susceptibility for the wavelength 1.89 um is about 1.94 pm/V. With increasing acoustical power, the AIOSHG for fundamental YAB-Gd laser light (λ = 1.76 um) increases and achieves its maximum value at acoustical power density of about 1.45 W/cm2.
Twórcy
  • Universite d'Angers, Laboratoire POMA UMR CNRS 6136, 2. Bd Lavoisier, 49045 Angers, France
  • Institute of Physics, Higher Teacher Education School, 13/15 Armii Krajowej Ave., Częstochowa, Poland
autor
  • Institute of Physics, Higher Teacher Education School, 13/15 Armii Krajowej Ave., Częstochowa, Poland
autor
  • Universite d'Angers, Laboratoire POMA UMR CNRS 6136, 2. Bd Lavoisier, 49045 Angers, France
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BWA0-0002-0015
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