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In 2001-2007 aerosols were measured in the coastal zone (11 campaigns) and over the open waters of the Gdańsk Basin (southern Baltic) (5 campaigns). The marine aerosols contained nitrogen and sulphur compounds, which increased their acidity. This situation intensified during the cool months of the year, when fossil fuel emissions were higher, proportionate to energy and heat requirements. Irrespective of the season, these acidic aerosols were neutralized in the reaction with sea salt. The likelihood of sodium nitrate being formed increased at air humidities > 80% and nitrate concentrations >30 nmol m-3. Sodium sulphate was present in aerosols mostly in autumn and winter, with northerly advection, and at the highest wind speeds. The excess of free ammonia resulted in the formation of ammonium sulphate and ammonium nitrate in aerosols over the southern Baltic.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
299--318
Opis fizyczny
Bibliogr. 36 poz., rys., tab., wykr.
Twórcy
autor
autor
- Institute of Oceanography, University of Gdańsk, al. Marszałka J. Piłsudskiego 46, 81-378 Gdynia, Poland
Bibliografia
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- 32.Sievering H., Ennis G., Gorman E., 1990, Size distributions and statistical analysis of nitrate, excess sulphate, and chloride deficit in the marine boundary layer during GCE/CASE/WATOX, Global Biogeochem. Cy., 4(4), 395-405, http://dx.doi.org/10.1029/GB004i004p00395
- 33.Spokes L.J., Yeatman S.G., Cornell S.E., Jickells T.D., 2000, Nitrogen deposition to the eastern Atlantic Ocean. The importance of south-easterly flow, Tellus B, 52(1), 37-49, http://dx.doi.org/10.1034/j.1600-0889.2000.00062.x
- 34.Yao X.H., Lau A.P.S., Fang M., Chan C.K., Hu M., 2003, Size distributions and formation of ionic species in atmospheric particulate poll utants in Beijing, China: 1-inorganic ions, Atmos. Environ., 37(21), 2991-3000, http://dx.doi.org/10.1016/S1352-2310(03)00255-3
- 35.Yeatman S.G., Spokes L.J., Jickells T.D., 2001, Comparisons of coarse-mode aerosol nitrate and ammonium at two polluted coastal sites, Atmos. Environ., 35(7), 1321-1335, http://dx.doi.org/10.1016/S1352-2310(00)00452-0
- 36.Zhuang H., Chan C.K., Fang M., Wexler A.S., 1999, Formation of nitrate and non-sea-salt sulphate on coarse particles, Atmos. Environ., 33(26), 4223-4233, http://dx.doi.org/10.1016/S1352-2310(99)00186-7
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS8-0028-0049