Hazardous Compounds in Urban Pm in the Central Part of Upper Silesia (Poland) in Winter

• Autorzy: Rogula-Kozłowska W. , Kozielska B. , Klejnowski K.

Warianty tytułu

PL

Niebezpieczne związki w miejskim pyle zawieszonym w centralnej części Górnego Śląska w zimie

• Języki publikacji: EN

Abstrakty

EN

Thirteen fractions of ambient dust were investigated in Zabrze, a typical urban area in the central part of Upper Silesia (Poland), during a heating season. Fifteen PAH and Cr, Mn, Co, Ni, As, Se, Cd, Pb contents of each fraction were determined. The dust was sampled with use of a cascade impactor and chemically analyzed with an energy dispersive X-ray fl uorescence spectrometer (PANalytical Epsilon 5) and a gas chromatograph with a fl ame ionisation detector (Perkin Elmer Clarus 500). The concentrations of PM1 and the PM1-related PAH and elements were much higher than the ones of the coarse dust (PM2.5-10) and the substances contained in it. The concentrations of total PAH and carcinogenic PAH were very high (the concentrations of PM1-, PM2.5-, and PM10-related BaP were 16.08, 19.19, 19.32 ng m-3, respectively). The municipal emission, resulted mainly from hard coal combustion processes, appeared to be the main factor affecting the air quality in Zabrze in winter.

PL

Próbki trzynastu frakcji pyłu zawieszonego były pobierane w Zabrzu w okresie grzewczym (centralna część Górnego Śląska, Polska). Punkt poboru jest charakterystyczny dla obszaru miejskiego. Zbadano zawartość 15 WWA oraz Cr, Mn, Co, Ni, As, Se, Cd, Pb w każdej frakcji pyłu. Do poboru pyłu zastosowano impaktor kaskadowy, a do analizy chemicznej – spektrometr fl uorescencji rentgenowskiej z dyspersją energii (PANalytical Epsilon 5) oraz chromatograf gazowy z detektorem płomieniowo-jonizacyjnym (Perkin Elmer Clarus 500). Zarówno stężenia pyłu PM1 jak i stężenia związanych z nim WWA i pierwiastków były znacznie wyższe niż stężenia pyłu grubego (PM2.5-10) i związanych z nim substancji. Stężenia sumy WWA, a w szczególności kancerogennych związków tej grupy były bardzo wysokie (np. stężenia dla BaP związanego z PM1- i PM2.5- oraz PM10- wynosiły odpowiednio: 16.08, 19.19, 19.32 ng m-3). Na podstawie uzyskanych wyników badań dla ww. zanieczyszczeń stwierdzono, że za stan jakości powietrza w Zabrzu, w zimie, odpowiedzialna jest emisja komunalna – stacjonarne źródła spalania, głównie spalanie węgla.

Słowa kluczowe

EN

PM1; PM2.5; heavy metals; PAH; benzo(a)pyrene; carcinogenicity; hazardous compounds; toxicity equivalency factor; BEQ

PL

pył zawieszony; pył PM2,5; pył PM1; metale ciężkie; WWA; wielopierścieniowe węglowodory aromatyczne; związki rakotwórcze; jakość powietrza; Zabrze

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2013
• Tom: Vol. 39, no. 1
• Strony: 53--65
• Opis fizyczny: Bibliogr. 68 poz., tab., wykr.

Twórcy

autor

Rogula-Kozłowska W.

autor

Kozielska B.

autor

Klejnowski K.

• Institute of Environmental Engineering of the Polish Academy of Sciences, M. Skłodowska-Curie 34, 41-819 Zabrze, Poland,

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