Speciation of Aluminium in the Water and Bottom Sediment of Fish-Breeding Ponds

• Autorzy: Kluczka J. , Zołotajkin M. , Ciba J.

Warianty tytułu

PL

Specjacja glinu w wodzie i osadzie dennym stawów rybno-hodowlanych

• Języki publikacji: EN

Abstrakty

EN

Water and bottom sediment samples collected from a few fish-breeding ponds/reservoirs were subjected to tests. The aim of this paper was to determine the total content of aluminium and its fractions in the samples tested to estimate the potential risk to fish caused by the toxic forms of aluminium. The monomeric inorganic aluminium in waters was determined using the ion exchange and extraction-colorimetric method with oxychinoline according to Barnes's-Driscoll's procedure. The bottoms were fractionated using a three-step sequential extraction procedure and the microwave mineralisation. The total content of aluminium in waters and extracts was determined using the spectrophotometric method with eriochromocyanine R, and comparatively using the ICP OES technique. The results were subjected to statistical analysis. The level of concentration of labile Al in the waters about 26-34 ?g/dm3 and content of exchangeable Al 5-34 mg/g range in bottom sediments are possibly hazardous to aquatic organisms.

PL

Badaniom poddano próbki wody i osadu dennego pobrane z kilku stawów rybnych. Oznaczono całkowitą zawartość oraz frakcje glinu w badanych próbkach. Glin monomeryczny nieorganiczny wyznaczono metodą wymiany jonowej i ekstrakcyjno-kolorymetryczną z zastosowaniem oksychinoliny według procedury Barnes'a-Driscoll'a. Frakcjonowanie osadów dennych wykonano procedurą ekstrakcji sekwencyjnej Tessier'a w wersji ujednoliconej oraz z zastosowaniem mineralizacji mikrofalowej. Glin całkowity w wodzie oraz w ekstraktach oznaczono metodą spektrofotometryczną z eriochromocyjaniną R, porównawczo techniką ICP OES i dokonano oceny statystycznej otrzymanych wyników. Poziom stężenia glinu labilnego w wodach: 26-34 ?g/dm3 oraz glinu wymiennego i kwasowego w osadach: 5-34 mg/g nie wskazuje na zagrożenie dla hodowli ryb pod warunkiem, że zachowana będzie kwasowość wody. Przy pH = 4,3 następuje znaczny wzrost stężenia wszystkich oznaczanych form glinu, w tym również najbardziej toksycznego dla ryb - glinu monomerycznego nieorganicznego (Ali), którego stężenie zwiększa się ponad 10-krotnie w porównaniu do wód o odczynie pH = 7,1-8,2.

Słowa kluczowe

EN

aluminium; speciation; pond water; bottom sediments

PL

glin; specjacja; staw rybny; osad denny

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2012
• Tom: Vol. 38, no. 1
• Strony: 83--96
• Opis fizyczny: Bibliogr. 42 poz., tab.

Twórcy

autor

Kluczka J.

autor

Zołotajkin M.

autor

Ciba J.

• Department of Chemistry, Inorganic Technology and Fuels, Silesian University of Technology, ul. Bolesława Krzywoustego 6, 44-101 Gliwice, Poland,

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