Metody syntezy sulfidów fenylowo-fluorometylowych

Banach, Ł.; Ochal, Z.

Artykuł - szczegóły

Tytuł artykułu

Metody syntezy sulfidów fenylowo-fluorometylowych

Autorzy

Banach Ł. , Ochal Z.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

The metods of synthesis of phenyl-fluoromethyl sulfides

Języki publikacji

Abstrakty

Aromatic compounds containing halogenomethylsulfonyl or halogenomethylsulfanyl group are often biologically active as fungicides or herbicides [1–6]. Especially important plant protection agents are fluorine compounds [7–12]. Through to specific activity in living organisms, fluorine compounds found wide application. One of the reasons of high activity of these compounds is their high lipophilicity, which provides increase of solubility in lipides. Due to this fact absorption of fluorine compounds is easier and their transport in organism is faster what increase their efficiency [13–15]. In this paper the methods of synthesis of aromatic compounds containing fluoromethylsulfanyl group are described. Aryl-fluoromethyl sulfides can be easily transformed into sulfones by oxidation [16–18]. Methods of preparation of aryl-fluoromethyl sulfides can be divided into three groups: 1. Fluorination of methylsulfanyl group [19–31] 2. Substitution of chlorine atom into fluorine in phenyl-chloromethyl sulfides [32–34] 3. Fluoromethylation of phenylothiols [35, 36].

Słowa kluczowe

sulfidy fenylowo-fluorometylowe sulfony fenylowo-fluorometylowe pestycydy herbicydy fluorometylowanie fluorowanie

flouromethylphenyl sulfides flouromethylphenyl sulfones pesticides herbicides fluoromethylation fluorination

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2010

Tom

[Z] 64, 11-12

Strony

983--994

Opis fizyczny

Bibliogr. 37 poz., schem.

Twórcy

autor

Banach Ł.

autor

Ochal Z.

Wydział Chemiczny, Politechnika Warszawska ul. Noakowskiego 3, 00-664 Warszawa

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUS8-0005-0027