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Wielopierścieniowe węglowodory aromatyczne związane z PM1, PM2.5, PM10 i całkowitym pyłem zawieszonym w Aglomeracji Górnośląskiej
Języki publikacji
Abstrakty
Polycyclic aromatic hydrocarbons (PAHs) are persistent organic pollutants, ubiquitous in the whole environment. They are relatively well known and are still of interest due to their well documented carcinogenic and mutagenic properties. In ambient air of urban regions they mostly occur as adsorbed to particles of suspended dust. The richest in these compounds and therefore most hazardous to humans, fraction of dust is the fraction of the finest particles. The paper presents results of investigations of dust sampled with use of an impactor Dekati PM10 in Zabrze, a site typical of Upper Silesian conditions. While sampling, the impactor segregates sampled particles into four fractions by their aerodynamic diameters. Sixteen PAHs were determined in each fraction chromatographically. PAH content in the fraction of the finest particles, i.e. in PM1, was of particular interest.
Wielopierścieniowe węglowodory aromatyczne (WWA) należą do grupy trwałych zanieczyszczeń organicznych obecnych we wszystkich elementach środowiska. Są licznie reprezentowane i stosunkowo dobrze poznane, a ich udokumentowane własności mutagenne i kancerogenne sprawiają, że nadal są w centrum zainteresowań. W powietrzu atmosferycznym obszarów zurbanizowanych najczęściej występują w postaci zaadsorbowanej na cząstkach pyłu zawieszonego. Najbogatszą w te związki, i stąd najniebezpieczniejszą, jest frakcja cząstek najdrobniejszych. Przedmiotem badań był pył zawieszony pobrany impaktorem Dekati PM10 w punkcie charakterystycznym dla Aglomeracji Górnośląskiej w Zabrzu. Impaktor umożliwia rozdział pyłu zawieszonego na cztery frakcje, każda o cząstkach mających średnice aerodynamiczne w innym z czterech przyległych rozłącznych przedziałów. W każdej z frakcji oznaczono zawartość szesnastu WWA metodą chromatograficzną. Uzyskane wyniki umożliwiły ocenę zawartości WWA, a za szczególnie interesujące uznano wyniki zawartości WWA w pyle PM1.
Czasopismo
Rocznik
Tom
Strony
65--72
Opis fizyczny
bibliogr. 38 poz., tab., wykr.
Twórcy
autor
autor
autor
autor
- Institute of Environmental Engineering of the Polish Academy of Sciences ul. M. Skłodowskiej-Curie 34, 41-819 Zabrze, Poland, barbara.kozielska@polsl.pl
Bibliografia
- [1] Borstel R. von, B. Georgi, M. Bahadir: Size-fractioned sampling of particulate Diesel emissions and determination of particle bound PAH, Staub, Reinhaltung der Luft, 55(5), 199-203 1995
- [2] Bzdusek P.A., E.R. Christensen, A. Li, Q.M. Zou: Source apportionment of sediment PAHs in Lake Calumet, Chicago: application of factor analysis with nonnegative constraints, Environmental Science & Technology, 38, 97-103 (2004).
- [3] Commission staff working paper, Impact Assessment of the thematic strategy on air pollution and the Directive on Ambient Air Quality and Cleaner Air for Europe, Commission of the EC, Brussels, 21 September 2005, SEC1133.
- [4] Dockery D., C.A. Pope, X. Xu, J. Spengler, J. Ware, M. Fay, B. Ferris, F. Speizer: An Association between Air Pollution and Mortality in Six US Cities, The New England Journal of Medicine, 329, 1753-1759 (1993).
- [5] Duval M.M., S.K. Friedlander: Source resolution of polycyclic aromatic hydrocarbons in the Los Angeles atmosphere-application of a CMA with first order decay, US EPA Report EPA-600/2-81-161 (1996).
- [6] Esen F., Y. Tasdemir, N. Vardar: Atmospheric concentrations of PAHs, their possible sources and gas-toparticle partitioning at a residential site of Bursa, Turkey, Atmospheric Research, 88, 243-255 (2008).
- [7] Grynkiewicz-Bylina B., B. Rakwic, J.S. Pastuszka: Assessment of exposure to traffic- related aerosol and to particle- associated PAHs in Gliwice, Poland, Polish Journal of Environmental Studies, 1, 117-123 (2005).
- [8] Harrison R.M., D.J.T. Smith, L. Luhana: Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, UK, Environmental Science & Technology, 30, 825-832 (1996).
- [9] Hinds W.C.: Aerosol Technology, Properties, Behavior, and Measurement of Airborne Particles, Second Edition, John Wiley & Sons Inc., New York 1998.
- [10] Holland M.R., H.H. Jones, J. Berdowski, A. Bleeker, A.J.H. Visschedijk: Economic Evaluation of Air Quality Targets for PAHs, Final report for European Commission DG Environment, 2001.
- [11] Katsouyanni K., G. Touloumi, E. Samoli, A. Gryparis, A. Le Tertre, Y. Monopolis, G. Rossi, D. Zmirou, F. Ballester, A. Boumghar, H.R. Anderson, B. Wojtyniak, A. Paldy, R. Braunstein, J. Pekkanen, C. Schindler, J. Schwartz: Confounding and Effect Modification in the Short-Term Effects of Ambient Particles on Total Mortality: Results from 29 European Cities within APHEA2 Project, Epidemiology, 12, 521-531 (2001).
- [12] Klejnowski K., A. Krasa, W. Rogula: Seasonal variability of concentrations of total suspended particles (TSP) as well as PM10, PM2.5 and PM1 modes in Zabrze, Poland, Archives of Environmental Protection, 33(3), 15-29 (2007).
- [13] Kristensson A., Ch. Johansson, R. Westerholm, E. Swietlicki, L. Gidhagenb, U. Wideqvist, V. Vesely: Real-world traffic emission factors of gases and particles measured in a road tunnel in Stockholm, Sweden, Atmospheric Environment, 38, 657-673 (2004).
- [14] Li A., J.K. Jang, P.A. Scheff: Application of EPA CMB8.2 model for source apportionment of sediment PAHs in Lake Calumet, Chicago, Environmental Science & Technology, 37, 2958-2965 (2003).
- [15] Liu D., S. Gao, X. An: Distribution and Source Apportionment of Polycyclic Aromatic Hydrocarbons from Atmospheric Particulate Matter PM2.5 in Beijing, Advances in Atmospheric Sciences, 25(2), 297-305 (2008).
- [16] Nielsen T.: Traffic contribution of polycyclic aromatic hydrocarbons in the center of a large city, Atmospheric Environment, 30, 3481-3490 (1996).
- [17] Nikolao K., P.M. Masclet, G. Mouvier: Sources and chemical reactivity of polynuclear aromatic hydrocarbons in the atmosphere - a critical review, Science of the Total Environmental, 32, 102-132 (1984).
- [18] Niles R., Y.L. Tan: Determination of polynuclear aromatic hydrocarbons and mononitrated derivatives in air and diesel particulates, Analytica Chimica Acta, 221, 53-63 (1989).
- [19] Rajput N., A. Lakhani: Measurements of polycyclic aromatic hydrocarbons at an industrial site in India, Environmental Monitoring Assessment, 150, 273-284 (2009).
- [20] Ramdahl T., J. Alfheins, A. Björseth: PAH emission from various sources and their evolution over the last decades in mobile sources emission including organic species, D. Reidel ed., Publ. Comp., 1983.
- [21] Ramdahl T., G. Becher: Characterization of polynuclear aromatic hydrocarbon derivatives in emission from wood and cereal straw combustion, Analytica Chimica Acta, 144, 83-91 (1982).
- [22] Ravindra K., E. Wauters, R. van Grieken: Spatial and temporal variations in particulate polycyclic aromatic hydrocarbon (PAH) levels over Menen (Belgium) and their relation with air mass trajectories, [in:] C. Borrego, et al. (Eds.), Air Pollution Modeling and its Application XVIII Developments in Environmental Sciences Series, 6, 838-841 (2007).
- [23] Ravindra K., E. Wauters, R. van Grieken: Variation in particulate PAHs levels and their relation with the transboundary movement of the air masses, Science of The Total Environment, 396(2-3), 100-110 (2008).
- [24] Rozporządzenie Ministra Środowiska z dnia 5 grudnia 2002 r. w sprawie wartości odniesienia dla niektórych substancji w powietrzu, Dz. U. Nr 1/2003, poz. 12.
- [25] Sanderson, E.G., J-P. Farant: Atmospheric size distribution of PAHs: Evidence of a high-volume samplingartifact, Environmental Science and Technology, 39(19), 7631-7637 (2005).
- [26] Schönbuchner H., G. Guggenberger, K. Peters, H. Bergmann, W. Zec: Particle-Size Distribution of PAH in the Air of a Remote Norway Spruce Forest in Northern Bavaria, Water, Air and Soil Pollution 128(3-4), 355-367 (2001).
- [27] Schwartz J., W. Dockeryd, L.M. Neas: Is daily mortality associated specifically with fine particles?, Journal of the Air and Waste Management Association, 46(10), 927-939 (1996).
- [28] Sheu L., W.J. Lee, C.C. Su, C.C. Chao, Y.C. Fan: Dry deposition of polycyclic aromatic hydrocarbons in the ambient air of both urban and petrochemical-industry areas, Journal of Environmental Engineering ASCE, 1101-1109 (1995).
- [29] Smith D.J.T., R.M. Harrison: Polycyclic aromatic hydrocarbons in atmospheric particles, [in:] R.M. Harrison, R. van Grieken (Eds.), Atmospheric Particles, Wiley, 1998.
- [30] Spurny K.R.: Chemical Mixtures in Atmospheric Aerosols and Their Correlation to Lung Diseases and Lung Cancer Occurrence in the General Population, Toxicology Letters, 88, 271-277 (1996).
- [31] Tang X.L., X.H. Bi, G.Y. Sheng, J.H. Tan, J.M. Fu: Seasonal Variation of the Particle Size Distribution of n-Alkanes and Polycyclic Aromatic Hydrocarbons (PAHs) in Urban Aerosol of Guangzhou, China, Environmental Monitoring and Assessment, 117, 193-213 (2006).
- [32] Tian F., J. Chen, X. Qiao, Z. Wang, P. Yang, D. Wang, L. Ge: Sources and seasonal variation of atmospheric polycyclic aromatic hydrocarbons in Dalian, China: Factor analysis with non-negative constraints combined with local source fingerprints, Atmospheric Environment, 43(17), 2747-2753 (2009).
- [33] White P.A.: The genotoxicity of priority polycyclic aromatic hydrocarbons in complex mixtures, Mutation Research, 515, 85-98 (2002).
- [34] Wu S.P., S. Tao, W.X. Liu: Particle size distributions of polycyclic aromatic hydrocarbons in rural and urban atmosphere of Tianjin, China, Chemosphere, 62, 357-367 (2006).
- [35] Yan J., L. Wang, P.P. Fub, H. Yu: Photomutagenicity of 16 polycyclic aromatic hydrocarbons from the US EPA priority pollutant list, Mutation Research, 557, 99-108 (2004).
- [36] Yang H.H., C.F. Chiang: Size distribution and dry deposition of road dust PAHs, Environment International, 25(5), 585-597 (1999).
- [37] Yunker M.B., R.W. Macdonald, R. Vingarzan, R.H. Mitchell, D. Goyette, S. Sylvestre: PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition, Organic Geochemistry, 33, 489-515 (2002).
- [38] Zou L.Y, W. Zhang, S. Atkiston: The characterizations of polycyclic aromatic hydrocarbons emissions from burning of different firewood species in Australia, Environmental Pollution, 124, 283-289 (2003).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS8-0002-0054