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Bitumen and salt contents within the Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)

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EN
Abstrakty
EN
Geochemical studies were conducted on bitumen and salts saturating the Pleistocene and Holocene sediments from an abandoned ozokerite mine in Starunia. This location is noted for the discovery of remnants of a mammoth and three woolly rhinoceroses in 1907, and a nearly completely preserved rhinoceros carcass in 1929. The bitumen (oil) and brines (chloride ions) were preserving agents for the large Pleistocene mammals. The main mass of organic carbon hosted in the Pleistocene muds is related to bitumen originating from oil migrating from deep accumulations within the Boryslav-Pokuttya Unit. The highest analysed bitumen content is 9.26 wt%. The chloride ion content, originating from highly concentrated brines ascending from the salt-bearing Miocene Vorotyshcha beds, vary from 0 to 4.66 wt% but this usually does not exceed 1 wt%. The natural pathways of underground fluids (oil, gas and water) migration within the Quaternary sediments were disturbed by intensive ozokerite mining operations run between the last three decades of the 19th century and 1960. Therefore, the present preservation and conservation conditions of large, extinct mammals' remains can be different from those prevailing during the Pleistocene, when the mammals were buried. Taking into consideration the contents of the remaining preservatives: chloride and bitumen, the most favourable zone for fossils conservation and preservation is located close to boreholes Nos 22, 23, 28 and 36N, where the thickness of Pleistocene muds exceeds 2 metres. Generally, the spatial distributions of bitumen and chloride ion contents within the Holocene sediments and salt-bearing Miocene Vorotyshcha beds are very similar to those in the Pleistocene sediments.
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Strony
447--461
Opis fizyczny
bibliogr. 32 poz., rys., tab., wykr.
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autor
autor
autor
autor
  • Faculty of Geology, Geophysics and Environmental Protection, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Kraków, Poland, kotarba@agh.edu.pl
Bibliografia
  • Adamenko, O. M., Stelmach, O. R., Zinchuk, M. S. & Kotarba, M. J., 2005. History of petroleum exploration in the Starunia area, fore-Carpathian region, Ukraine. In: Kotarba, M. J. (ed.), Polish and Ukrainian geological studies (2004-2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa-Kraków: 53- 61.
  • Alexandrowicz, S. W., 2004. Starunia and the Quaternary research in the tradition and initiatives of the Polish Academy of Arts and Sciences. (In Polish, English summary). Studia i materiały do dziejów Polskiej Akademii Umiejętności. Polska Akademia Umiejętności, Kraków, 3, 261 pp.
  • Alexandrowicz, S. W., 2005. The history of Starunia - a palaeontologic site and old ozokerite mine. In: Kotarba, M. J. (ed.), Polish and Ukrainian geological studies (2004-2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa-Kraków: 21-38.
  • Barabasz, W., Chmiel, M. J. & Ostafin, M., 2009. Microbiological characteristics of Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine). Annales Societatis Geologorum Poloniae, 79: 439-446.
  • Duliński, M., Różański, K. & Kotarba, M. J., 2005. Isotopic and chemical composition of surface and groundwaters in the Starunia area, fore-Carpathian region, Ukraine. In: Kotarba, M. J. (ed.), Polish and Ukrainian geological studies (2004- 2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa- Kraków: 187-194.
  • Espitalié, J., Deroo, G. & Marquis, F., 1985. La pyrolyse Rock Eval etses applications (part I). Revue del'Institut Français du Pétrole, 40: 563-579.
  • Espitalié, J., Deroo, G. & Marquis, F., 1986. La pyrolyse Rock Eva letses applications (part II). Revue del'Institut Français du Pétrole, 41: 755-784.
  • Espitalié, J., Laporte, J., Madec, M., Marquis, F., Leplat, P., Paulet, J. & Boutefeu, A., 1977. Methode rapide de characterisation des roches meres, leur potential petrolieret de leur degréd'évolution. Revue del'Institut Français du Pétrole, 32: 23-42.
  • Hunt, J. M., 1979. Pe tro leum Geochemistry and Geology. W. H. Freeman, San Francisco, 617 pp.
  • Koltun, Y. V., Adamenko, O. M., Kotarba, M. J., Dudok, I. V., Pavluk, M. I., Burzewski, W. & Stelmakh, O. R., 2005. Geological setting and petroleum occurrence of the Starunia area, fore-Carpathian region, Ukraine. In: Kotarba, M. J. (ed.), Polish and Ukrainian geological studies (2004-2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa-Kraków: 61-78.
  • Korin, S. S., 2005. Miocene salt-bearing Vorotyshcha Beds in the Starunia area, fore-Carpathian region, Ukraine. In: Kotarba, M. J. (ed.), Polish and Ukrainian geological studies (2004- 2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa- Kraków: 79-86.
  • Kotarba, M. J., 2002. Composition and origin of hydrocarbons saturating the remnants of woolly rhinoceros from Starunia, the Ukrainian Carpathians. (In Polish, English summary). Przegląd Geologiczny, 50: 531-534.
  • Kotarba, M. J. (ed.), 2005. Polish and Ukrainian geological studies (2004-2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa- Kraków, 218 pp.
  • Kotarba, M. J., 2009. Interdisciplinary studies at Starunia palaeontological site and vicinity (Carpathian region, Ukraine) in the years 2006-2009: previous discoveries and research, purposes, results and perspectives. Annales Societatis Geologorum Poloniae, 79: 219-241.
  • Kotarba, M. J. & Koltun, Y. V., 2006. Theorigin and habitat of hydrocarbons of the Polish and Ukrainian Parts of the Carpathian Province. In: Golonka, J. & Picha, F. J. (eds), The Carpathians and their foreland: Geology and hydrocarbon resources. American Association of Petroleum Geologists Memoir, 84: 395-442.
  • Kotarba, M. J., Alexandrowicz, S. W. & Stachowicz-Rybka, R., 2008a. Historia i program dalszych badań geologicznych na obszarze byłej kopalni ozokerytu i stanowiska paleontologicznego w Staruni. (In Polish). Przegląd Geologiczny, 56: 34-441.
  • Kotarba, M. J., Dzieniewicz, M., Mościcki, W. J. & Sechman, H., 2008b. Unique Quaternary environment for discoveries of woolly rhinoceroses in Starunia, fore-Carpathian re gion, Ukraine: Geochemical and geoelectric studies. Geology, 36: 567-570.
  • Kotarba, M. J. & Stachowicz-Rybka, R., 2008. Wyjątkowe stanowisko paleontologiczne i środowisko osadów plejstoceńskich, w których znaleziono nosorożce włochate w Staruni (Karpaty Wschodnie). (In Polish). Przegląd Geologiczny, 56: 442-452.
  • Kotarba, M. J., Więcław, D., Koltun, Y. V., Lewan, M. D., Marynowski, L. & Dudok, I. V., 2005a. Organic geochemical study and genetic correlations between source rocks and hydrocarbons from surface seeps and deep accumulations in the Starunia area, fore-Carpathian region, Ukraine. In: Kotarba, M. J. (ed.), Polish and Ukrainian geological studies (2004- 2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa- Kraków: 125-146.
  • Kotarba, M. J., Dzieniewicz, M. & Sechman, H., 2005b. Geochemical survey, molecular and isotopic compositions, and genetic identification of near-surface gases from the Starunia area, fore-Carpathian region, Ukraine. In: Kotarba, M. J. (ed.), Polish and Ukrainian geological studies (2004-2005) at Starunia - the area of discoveries of woolly rhinoceroses. Polish Geological Institute and Society of Research on Environmental Changes "Geosphere", Warszawa-Kraków: 157-174.
  • ŹKotarba, M. J., Sechman, H. & Dzieniewicz, M., 2009a. Distribution and origin of gaseous n-alkanes and carbon dioxide in the Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine). Annales Societatis Geologorum Poloniae, 79: 403-419.
  • Kotarba, M. J., Fabiańska, M., Więcław, D., Kowalski, A. & Zych, H., 2009b. Biological markers and stable carbon isotope studies of bitumen impregnating Quaternary sediments at Starunia palaeontological site and vicinity (Carpathian region, Ukraine). Annales Societatis Geologorum Poloniae, 79: 463-480.
  • Leenheer, M. J., 1984. Mississippian Bakken and equivalent formations as source rocks in the western Canadian basins. Or ganic Geochemistry, 6: 521-532.
  • Mitura, F., 1944. Geologia złoża wosku w Staruni. (In Polish). Unpublished report, Archive of the Jagiellonian University, Kraków, 18 ms. pp.
  • Mościcki, W. J., Toboła, T. & Zarzyka-Ryszka, M., 2009. Salinity of Quaternary sediments and halophytes at Starunia palaeontological site and vicinity (Carpathian region, Ukraine). Annales Societatis Geologorum Poloniae, 79: 391-402.
  • Pieczonka, J., Piestrzyński, A., Mucha, J., Głuszek, A., Kotarba, M. J. & Więcław, D., 2008. The redbed-type precious metal deposit in the Sieroszowice-Polkowice coppermining district, SW Poland. Annales Societas Geologorum Poloniae, 78: 151-280.
  • Sechman, H., Kotarba, M. J. & Dzieniewicz, M., 2009. Surfacegeochemical survey at Starunia palaeontological site and vicinity (Carpathian region, Ukraine). Annales Societatis Geologorum Poloniae, 79: 375-390.
  • Smith, J. T., 1994. Petroleum system logicas an exploration tool in frontier setting. In: Magoon, L. B. & Dow, W. G. (eds), The Petroleum System - from Source to Trap. American Association of Petroleum Geologists Memoir, 60: 25-49.
  • Sokołowski, T. & Stachowicz-Rybka, R., 2009. Chronostratigraphy and changes of environment of Late Pleistocene and Holocene at Starunia palaeontological site and vicinity (Carpathian region, Ukraine). Annales Societatis Geologorum Poloniae, 79: 315-331.
  • Sokołowski, T., Stachowicz-Rybka, R. & Woronko, B., 2009. Upper Pleistocene and Holocene deposits at Starunia palaeontological site and vicinity (Carpathian region, Ukraine). Annales Societatis Geologorum Poloniae, 79: 255-278.
  • Stachowicz-Rybka, R., Granoszewski, W. & Hrynowiecka- Czmielewska, A., 2009. Quaternary environmental changes at Starunia palaeontological site and vicinity (Carpathian region, Ukraine) based on palaeobotanical studies. Annales Societatis Geologorum Poloniae, 79: 279-288.
  • Ślączka, A., Krugłov, S., Golonka, J., Oszczypko, N. & Popadyuk, I., 2006. Geology and hydrocarbon resources of the Outer Carpathians, Poland, Slovakia and Ukraine: General geology. In: Golonka, J. & Picha, F. J. (eds), The Carpathians and their foreland: Geology and hydrocarbon resources. American Association of Petroleum Geologists Memoir, 84: 221-258.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS7-0001-0017
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