PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
Tytuł artykułu

Origin and maturity of oils in the Ukrainian Carpathians and their Mesozoic basement

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Geochemical characteristics of 25 oils collected from Skiba Unit of the Outer Carpathians, Boryslav-Pokuttya Unit of the Carpathian Foredeep and their Mesozoic basement in the western Ukraine are presented in the paper. The first recognised oil family consists of almost all oils accumulated in the flysch sequence of the Outer Carpathians and the Carpathian Foredeep which have very similar geochemical characteristics. These oils were generated from Type II or II/III kerogen deposited in clastic sediments. They are low-sulphur and migrated short distances. Slight biodegradation processes are visible only in oils accumulated in shallow deposits in the Skiba Unit. Their source rocks are the Oligocene Menilite Shales from the Boryslav-Pokuttya Unit. Oils from the Kokhanivka and Orkhovychi deposits (the Mesozoic basement of the Carpathian Foredeep) constitute the second family. These oils are extremely heavy, high-sulphur and were generated from high-sulphur Type IIS kerogen deposited in the carbonate environment. The most probable source rocks for these oils are the Upper Jurassic strata. Oil collected from the Vola Blazhivska deposit (the Boryslav-Pokuttya Unit) shows intermediate parameters between the oil families described above. It is characterized by the presence of oleanane and high sulphur content. It was generated from the Menilite Shales containing high-sulphur kerogen. All oils were generated at an early stage or the peak of oil window.
Rocznik
Strony
158--168
Opis fizyczny
Bibliogr. 104 poz., rys., tab., wykr.
Twórcy
autor
autor
autor
  • Faculty of Geology, Geophysics and Environmental Protection, AGH University of Science and Technology, Mickiewicza 30, 30-059 Kraków, Poland, wieclaw@agh.edu.pl
Bibliografia
  • 1.AKINLUA A., AJAYI T. R. and ADELEKE B. B. (2006) - Niger Delta oil geochemistry: insight from light hydrocarbons. J. Petrol. Sc. Engineer., 50 (3-4): 308-314.
  • 2.BARAKAT A. O., MOSTAFA A., EL-GAYAR M. S. and RULLKÖTTER J. (1997) - Source-dependent biomarker properties of five crude oils from the Gulf of Suez, Egypt. Org. Geochem., 26 (7): 441-450.
  • 3.BESSEREAU G., ROURE F., KOTARBA M., KUŚMIEREK J. and STRZETELSKIW. (1996) - Structure and hydrocarbon habitat of the Polish Carpathians. In: Structure and Prospects Alpine Basins and Forelands (eds. P. A. Ziegler, P. A. and F. Horvath): 343-373. Peri-Tethys Mem., 2, Mém. Mus. Nat. History Natur.
  • 4.BLANC P. and CONN AN J. (1994) - Preservation, degradation, and destruction of trapped oil. Am. Ass. Petrol. Geol. Mem., 60: 237-247.
  • 5.CHUNG H. M., BRAND S. W. and GRIZZLE P. L. (1981) - Carbon isotope geochemistry of Paleozoic oils from Big Horn basin. Geochim. Cosmochim. Acta, 45 (10): 1803-1815.
  • 6.CLAYPOOL G. E. and MANCINI E. A. (1989) - Geochemical relationships of petroleum in Mesozoic reservoirs to carbonate source rocks of Jurassic Smackover Formation, Southwestern Alabama. Am. Ass. Petrol. Geol. Bull., 73: 904-924.
  • 7.COPLEN T. B. (1995) - Reporting of stable carbon, hydrogen, and oxygen isotopic abundances. In: Reference and Intercomparison Materials for Stable Isotopes of Light Elements. Proc. Consultants meeting held in Vienna, December 1993, 1-3: 31-34. International Atomic Energy Agency, Vienna.
  • 8.CURTIS J. B., KOTARBAM. J., LEWAN M. D. and WIĘCŁAW D. (2004) - Oil/source rock correlations in the Polish Flysch Carpathians and Mesozoic basement and organic facies of the Oligocene Menilite Shales: insights from hydrous pyrolysis experiments. Org. Geochem., 35: 1573-1596.
  • 9.DIDYK B. M., SIMONEITB. R. T., BRASSELL S. C. andEGLINTON G. (1978) - Organic geochemical indicators of palaeoenvironmental conditions of sedimentation. Nature, 272: 216-222.
  • 10.EKWEOZOR C. M. and UDO O. T. (1988) - The oleananes: origin, maturation and limits of occurrence in Southern Nigeria sedimentary basins. Org. Geochem., 13 (1-3): 131-140.
  • 11.FEDYSHYN V. O., HAVRYLKO V. M., KULCHYTSKI D. Y., KARPENCHUK Y. R. and TKACHENKO A. I. (2001) - Results of prospecting-exploration works and industrial exploration of gas reserves in the Bilche-Volytsia zone of the Precarpathian foredeep and prospects of the new gas fields prospecting (in Ukrainian with English summary). Geol. Geohkim. Horyuch. Kopalyn, 4: 3-23.
  • 12.GALIMOV E. M. (1973) - Izotopy ugleroda v nieftiegazovoy geologii. Izd. Nedra, Moskva.
  • 13.GALIMOV E. M. (1986) - Izotopnyi metod vyyavlenia neftematerynskykh otlozheniy na primierie mestorozhdieniy riada regionov SSSR. Izviestia Akad. Nauk SSSR, Ser. Geol., 4: 3-21.
  • 14.HALPERN H. I. (1995) - Development and applications of light-hydrocarbon-based star diagrams. Am. Ass. Petrol. Geol. Bull., 79 (6): 801-815.
  • 15.HORSFIELD B., SCHENK H. J., MILLS N. and WELTE D. H. (1992) -An investigation of the in-reservoir conversion of oil to gas: compositional and kinetic findings from closed-system pro-grammed-temperaturepyrolysis. Org. Geochem., 19 (1-3): 191-204.
  • 16.HUANG W.-Y. and MEINSCHEIN W. G. (1979) - Sterols as ecological indicators. Geochim. Cosmochim. Acta, 43 (5): 739-745.
  • 17.HUGHES W. B., HOLBA A. G. and DZOU L. I. P. (1995) - The ratios of dibezothiophene to phenantrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks. Geochim. Cosmochim. Acta, 59 (17): 3581-3598.
  • 18.HUNT J. M. (1996) - Petroleum geochemistry and geology. W. H. Freeman and Company, New York.
  • 19.HUNT J. M., LEWAN M. D. and HENNET R. C. (1991) - Modeling oil generation with time - temperature index graphs based on the Arrhenius equation. Am. Ass. Petrol. Geol. Bull., 75 (4): 795-807.
  • 20.KARNKOWSKI P. (1999) - Oil and gas deposits in Poland. The Geosynoptics Society "Geos" and University of Mining and Metallurgy, Kraków.
  • 21.KOLTUN Y. V. (1992) - Organic matter in Oligocene Menilite Formation rocks of the Ukrainian Carpathians: palaeoenvironment and geochemical evolution. Org. Geochem., 18 (4): 423-430.
  • 22.KOLTUN Y. V., ESPITALIÉ J., KOTARBA M., ROURE F., ELLOUZ N. and KOSAKOWSKI P. (1998) - Petroleum generation in the Ukrainian external Carpathians and the adjacent foreland. J. Petrol. Geol., 21 (3): 265-288.
  • 23.KOSAKOWSKI P., WRÓBEL M. and KOLTUN Y. V. (2011) - 1 -D modelling of the hydrocarbon generation history of the Jurassic source rocks in the in the Tarnogród-Stryi area (SE Poland and western Ukraine). Ann. Soc. Geol. Pol., 81 (3): 473-485.
  • 24.KOSAKOWSKI P., WIĘCŁAW D., KOTARBAM. J. and KOWALSKI A. (2012) - Habitat and hydrocarbon potential of the Mesozoic strata in the Kraków-Rzeszów area (SE Poland). Geol. Quart., 56 (1): 139-152.
  • 25.KOTARBA M. J. and KOLTUN Y. V. (2006) - The origin and habitat of hydrocarbons of the Polish and Ukrainian Parts of the Carpathian Province. Am. Ass. Petrol. Geol. Mem., 84: 395-442.
  • 26.KOTARBA M. J. and PERYT T. M. (2011) - Geology and petroleum geochemistry of Miocene strata in the Polish and Ukrainian Carpathian Foredeep and its Palaeozoic-Mesozoic basement. Ann. Soc. Geol. Pol., 81(3): 211-220.
  • 27.KOTARBA M. J., WIĘCŁAW D., KOLTUN Y. V., LEWAN M. D., MARYNOWSKI L. and DUDOK I. V. (2005) - Organic geochemical study and genetic correlations between source rocks and hydrocarbons from surface seeps and deep accumulations in the Starunia area, fore-Carpathian region, Ukraine. In: Polish and Ukrainian Geological Studies (2004-2005) at Starunia - the Area of Discoveries of Woolly Rhinoceroses (ed. M. J. Kotarba): 125-145. Pol. Geol. Inst. Soc. Res. Environment. Changes "Geosphere", Warszawa-Kraków.
  • 28.KOTARBA M. J., WIĘCŁAW D., KOLTUN Y. V., MARYNOWSKI L., KUŚMIEREK J. and DUDOK I. V. (2007) - Organic geochemical study and genetic correlation of natural gas, oil and Menilite source rocks in the area between San and Stryi rivers (Polish and Ukrainian Carpathians). Org. Geochem., 38 (8): 1431-1456.
  • 29.KRUGE M. A., MASTALERZ M., SOLECKI A. and STANKIEWICZ B. A. (1996) - Organic geochemistry and petrology of oil source rocks, Carpathian Overthrust region, southeastern Poland - implications for petroleum generation. Org. Geochem., 24 (8-9): 897-912.
  • 30.KÖSTER J., KOTARBA M., LAFARGUE E. and KOSAKOWSKI P. (1998) - Source rock habitat and hydrocarbon potential of Oligocene Menilite Formation (Flysch Carpathians, Southeast Poland): an organic geochemical and isotope approach. Org. Geochem., 29 (1): 543-558.
  • 31.KVALHEIM O. M., CHRISTY A. A., TELNS N. and BJ0RSETH A. (1987) - Maturity determination of organic matter in coals using the methylphenanthrene distribution. Geochim. Cosmochim. Acta, 51: 1883-1888.
  • 32.LEWAN M. D. (1983) - Effects of the thermal maturation on stable organic carbon isotopes as determined by hydrous pyrolysis of Woodford Shale. Geochim. Cosmochim. Acta, 47 (8): 1471-1479.
  • 33.LEWAN M. D. (1984) - Factors controlling the proportionality of vanadium to nickel in crude oils. Geochim. Cosmochim. Acta, 48 (11): 2231-2238.
  • 34.MANGO F. D. (1991) - The stability of hydrocarbons under the time-temperature conditions of petroleum genesis. Nature, 352: 146-148.
  • 35.MANGO F. D. (1997) - The light hydrocarbons in petroleum: a critical review. Org. Geochem., 26 (7/8): 417-440.
  • 36.MASTERSON W. D., DZOU L. I. P., HOLBA A. G., FINCANNON A. L. and ELLIS L. (2001) - Evidence for biodegradation and evaporative fractionation in West Sak, Kuparuk and Prudhoe Bay field areas, North Slope, Alaska. Org. Geochem., 32 (3): 411-441.
  • 37.MOLDOWAN J. M., SEIFERT W. K. and GALLEGOS E. J. (1985) - Relationship between petroleum composition and depositional environment of petroleum source rocks. Am. Ass. Petrol. Geol. Bull., 69 (8): 1255-1268.
  • 38.MOLDOWAN J. M., SUNDARARAMAN P. and SCHOELL M. (1986) -Sensitivity of biomarker properties to depositional environment and/or source input in the Lower Toarcian of S. W. Germany. Org. Geochem., 10 (4-6): 915-926.
  • 39.MOLDOWAN J. M., DAHL L., HUIZINGAB. J., FAGO F. J., HICKEYL. J., PEAKMAN T. M. and TAYLOR D. W. (1994) - The molecular fossil record of Oleanane and its relation to angiosperms. Science, 265: 768-771.
  • 40.OBERMAJER M., FLOWER M. G. and SNOWDON L. R. (1999) -Depositional environment and oil generation in Ordovican source rocks from southwestern Ontario, Canada. Organic geochemical and petrological approach. Am. Ass. Petrol. Geol. Bull., 83 (9): 1426-1453.
  • 41.ORR W. L. (1986) - Kerogen/asphaltene/sulfur relationships in sulfur-rich Monterey oils. Org. Geochem., 10 (1-3): 499-516.
  • 42.ORR W. L. (2001) - Evaluating kerogen sulfur content from crude oil properties: cooperative Monterey organic geochemistry study. In: The Monterey Formation from Rocks to Molecules (eds. C. M. Isaacs and J. Rullkötter): 348-367. Columbia University Press, New York.
  • 43.PALMER S. (1984) - Effect of water washing on C15+ hydrocarbon fraction of crude oils from northwest Palawan, Philippines. Am. Ass. Petrol. Geol. Bull., 68 (2): 137-149.
  • 44.PALMER S. (1993) -Effect of biodegradation and water washing on crude oil composition. In: Organic Geochemistry (eds. M. H. Engel and S. A. Macko): 511-533. Plenum Press, New York.
  • 45.PEPPER A. and DODD T. A. (1995) - Single kinetic models of petroleum formation. Part II: Oil-gas Cracing. Mar. Petrol. Geol., 12 (3): 321-340.
  • 46.PETERS K. E. and MOLDOWAN J. M. (1991) - Effects of source, thermal maturity, and biodegradation on the distribution and isomerization of homohopanes in petroleum. Org. Geochem., 17 (1): 47-61.
  • 47.PETERS K. E. and MOLDOWAN J. M. (1993) - The biomarker guide: interpreting molecular fossils in petroleum and ancient sediments. Englewood Cliffs, Prentice-Hall, New Jersey.
  • 48.PETERS K. E., WALTERS C. C. and MOLDOWAN J. M. (2005) - The biomarker guide. Biomarkers and isotopes in petroleum exploration and earth history. Ed. 2, Cambridge University Press, Cambridge.
  • 49.RADKE M. (1988) - Application of aromatic compounds as maturity indicators in source rocks and crude oils. Mar. Petrol. Geol., 5 (8): 224-236.
  • 50.SOFER Z. (1984) - Stable carbon isotopic compositions of crude oils: application of the source depositional environments and petroleum alteration. Am. Ass. Petrol. Geol. Bull., 68 (1): 31-49.
  • 51.STAHL W. J. (1980) - Compositional changes and 13C/12C fractionations during the degradation of hydrocarbons by bacteria. Geochim. Cosmochim. Acta, 44 (11): 1903-1907.
  • 52.Ten HAVEN H. L. (1996) - Applications and limitations of Mango's light hydrocarbon parameters in petroleum correlation studies. Org. Geochem., 24 (10-11): 957-976.
  • 53.Ten HAVEN H. L., LAFARGUE E. and KOTARBA M. (1993) - Oil/oil and oil/source rock correlations in the Carpathian Foredeep and overthrust, south-east Poland. Org. Geochem., 20 (7): 935-959.
  • 54.THOMPSON K. F. M. (1983) - Classification and thermal history of petroleum based on light hydrocarbons. Geochim. Cosmochim. Acta, 47 (2): 303-316.
  • 55.THOMPSON K. F. M. (1987) - Fractionated aromatic petroleums and the generation of gas-condensates. Org. Geochem., 11 (6): 573-590.
  • 56.THOMPSON K. F. M. (2010) -Aspects of petroleum basin evolution due to gas advection and evaporative fractionation. Org. Geochem., 41 (4): 370-385.
  • 57.VUL M. Y., DENEGA B. I., KRUPSKY Y. Z., NIMETS M. V., SVYRYDENKO V. G. and FEDYSHYN V. O., eds. (1998) - Western oil and gasbearing region. In: Atlas of Oil and Gas Fields of Ukraine in Six Volumes, v. 5 (eds. M. M. Ivanyuta, V. O. Fedyshyn et al.). Ukrainian Oil and Gas Academy, Lviv.
  • 58.WAPLES D. W. and TORNHEIM L. (1978) - Mathematical models for petroleum-forming processes: carbon isotope fractionation. Geochim. Cosmochim. Acta, 42 (5): 467-472.
  • 59.WIĘCŁAW D. (2011) - Origin of liquid hydrocarbons in the Miocene strata of the Polish Carpathian Foredeep and its Palaeozoic-Mesozoic basement. Ann. Soc. Geol. Pol., 81 (3): 443-458.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS6-0036-0007
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.