Dystrybucja biomarkerów i dojrzałość termiczna materii organicznej w tonsteinie i węglu kamiennym z pokładu 385/2 z kopalni Bogdanka (Lubelskie Zagłębie Węglowe)

• Autorzy: Gola M. R. , Karger M. , Gazda L.

Warianty tytułu

EN

Biomarker's distribution and thermal maturity of organic matter w tonsteinie i węglu kamiennym z pokładu 385/2 z kopalni Bogdanka "Bogdanka" mine (Lublin Coal Basin)

• Języki publikacji: PL

Abstrakty

EN

The paper presents results of geochemical analyses of organic matter (OM) in a tonstein bed and surrounding bituminous coal from the Upper Carboniferous (Westphalian B) coal seam no. 385/2 from the Bogdanka mine, Lublin Coal Basin. In all studied samples, including those of tonstein and bituminous coal, OM was found to be very similar in composition. Distribution of hydrocarbons in investigated rocks is characterized by strong predominance with odd-number carbon-atom of the long-chain n-alkanes in comparison to the even-number and high concentration of C29 steranes, what implies relatively high input of higher-plant OM in these samples. Minor concentration of C28 steranes and perylene points at presence of fungi. In all extracts, the tri- and tetracyclic diterpanes co-occur with their aromatized derivatives, what suggests presence of the tap resin species - precursors of the conifer families in the plant community. The abundance of sesquiterpanes, pentacyclic triterpanes and benzohopanes indicates a significant bacterial input, most possibly connected with bacterial activity after deposition of terrestrial OM. The original material of tonstein was pyroclastic in orgin, and deposited directly on plants living at the surface of a mire. That material hadn’t had any direct influence on chemicalOMtransformation. The biomarker data, both for coals and tonstein, reveals that sedimentary organic matter was heated up to a temperature corresponding to the level of immature/start of oil window. On the other hand, the increase in thermal maturity value, based on distribution of the aromatic hydrocarbons in organic matter in tonstein (theoretical vitrinite values - Rc, Rcs) are probably due to the presence of incompletely burned organic remains (charcoals), transported to the sedimentary basin along with volcanic ashes.

Słowa kluczowe

PL

Lubelskie Zagłębie Węglowe; tonstein; biomarkery; dojrzałość termiczna materii organicznej

EN

Lublin Coal Basin; tonstein; biomarkers; thermal maturity of organic matter

• Wydawca: Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy
• Czasopismo: Przegląd Geologiczny
• Rocznik: 2011
• Tom: Vol. 59, nr 12
• Strony: 777--784
• Opis fizyczny: Bibliogr. 44 poz., tab., wykr.

Twórcy

autor

Gola M. R.

autor

Karger M.

autor

Gazda L.

Bibliografia

• 1.VAN AARSEN B.G.K., HESSELS J.K.C., ABBINK O.A. & DE LEEUW J.W. 1992 - The occurrence of polycyclic sesqui-, tri-, and oligoterpenoids derived from resinous polymeric cadinene in crude oil from southeast Asia. Geochimica et Cosmochimica Acta, 56 (3): 1231-1246.
• 2.BIEŃKO W. 2004 - Lubelski Węgiel Bogdanka S.A. - process engineering of the coal preparation plant. Inżynieria Mineralna, July-December: 45-49.
• 3.DIDYK B.M., SIMONEIT B.R.T., BRASSEL S.C. & EGLINTON G. 1978 - Organic geochemical indicators of paleoenvironmental conditions of sedimentation. Nature, 272 (5650): 216-222.
• 4.DISNAR J.R. & HAROUNA M. 1994 - Biological origin of tetracyclic diterpanes, n-alkanes and other biomarkers in Lower Carboniferous Gondwana coals (Niger). Organic Geochemistry, 21(2): 143-152.
• 5.FABIAŃSKA M., BZOWSKA G., MATUSZEWSKA A., RACKA M. & SKRĘT U. 2003 - Gas Chromatography-Mass Spectrometry in geochemical investigation of organic matter of the Grodziec Beds (Upper Carboniferous), Upper Silesian Coal Basin, Poland. Chemie der Erde (Geochemistry), 63 (1): 63-91.
• 6.HUANG W.-Y. & MEINSCHEIN W.G. 1979 - Steroles as source indicators of organic materials in sediments. Geochimica et Cosmochimica Acta, 40 (3): 323-330.
• 7.HUGHES W.B., HOLBA A.G. & DZOU L.I.P. 1995 - The ratios of dibenzothiophene to phenanthrene and pristane to phytane as indicators of depositional environment and lithology of petroleum source rocks. Geochimica et Cosmochimica Acta, 59 (17): 3581-3598.
• 8.HUNT J.M. 1996 - Petroleum geochemistry and geology. 2nd Edition, W.H. Freeman Company, New York: 1-743.
• 9.HUSSLER G., CONNAN J. & ALBRECHT P. 1984 - Novel families of tetra- and hexacyclic aromatic hopanoids predominant in carbonate rocks and oils. Organic Geochemistry, 15 (6): 39-49.
• 10.JASPER K., KROSS B.M., FLAJS G., HARTKOPF-FRÖDER C. & LITTKE R. 2009 - Characteristic of type III kerogen in coal-bearing strata from the Pennsylvanian (Upper Carboniferous) in the Ruhr Basin, Western Germany: Comparison of coals, dispersed organic matter, kerogen concentrates and coal-mineral mixtures. International Journal of Coal Geology, 80 (1): 1-19.
• 11.JIANG C., ALEXANDER R., KAGI R.I. & MURRAY A.P. 2000 -Origin of perylene in ancient sediments and its geological significance. Organic Geochemistry, 31(12): 1545-1559.
• 12.VAN KAAM-PETERS, KÖSTER J., VAN DER GAAST S.J., DEKKER M., DE LEEUW J.W. & SINNINGHE DAMSTÉJ.S. 1998 -The effect of clay minerals on diasterane/sterane ratios. Geochimica et Cosmochimica Acta, 62 (17): 2923-2929.
• 13.KMIECIK H. & KNAFEL S. 1988 - Karbon Lubelskiego Zagłębia Węglowego. Geneza węgla. Prace Państwowego Instytutu Geologicznego, 72: 160-167.
• 14.KOTARBA M.J. CLAYTON J.L., RICE D.D. & WAGNER M. 2002 -Assessment of hydrocarbon source rock potential of Polish bituminous coals and carbonaceous shales. International Journal of Coal Geology, 184(1-2): 11-35.
• 15.KOTARBA M.J. & CLAYTON J.L. 2003 - A stable carbon isotope and biological marker study of Polish bituminous coals and carbonaceous shales. International Journal of Coal Geology, 55 (2-4):
• 16.73-94. KOTARBA M.J. & LEWAN M.D. 2004 - Characterizing thermogenic coalbed gas from Polish coals of different ranks by hydrous pyrolysis. Organic Geochemistry, 35 (5): 615-646.
• 17.LIPIARSKI I. & MUSZYŃSKI M. 1997 - Tonsteins from the West-phalian B from the Lublin Coal Basin (Poland). Prace Państwowego Instytutu Geologicznego, 157: 267-273.
• 18.LIPIARSKI I., MUSZYŃSKI M. & STOLECKI J. 1993 - Tonstein from the coal seam no. 385 in the Lublin Formation (Lower Westpha-lian) from the Lublin Coal Basin. Geological Quarterly, 37 (4): 537-564.
• 19.MELLO M.R. & MAXWELL J.R. 1991 - Organic geochemical and biological marker characterization of source rocks and oils derived from lacustrine environments in the Brazilian Continental Margin. [In]: Lacustrine basin exploration - case studies and modern analogies (ed. B J. Katz). AAPG Memoir 50: 77-98.
• 20.MIGIER T. 1988 - Karbon Lubelskiego Zagłębia Węglowego. Stratygrafia karbonu na podstawie makroflory. Prace Państwowego Instytutu Geologicznego, 72: 120-131.
• 21.MIRANDA A.C.M.L., LOUREIRO M.R.B. & CARDOSO J.N. 1999 -Aliphatic and aromatic hydrocarbons in Candiota coal samples: novel series of bicyclic compounds. Organic Geochemistry, 30 (9): 1027-1038.
• 22.MOLDOWAN J.M., SEIFERT W.K. & GALLEGOS E.J. 1985 - Relationships between petroleum composition and depositional environment of petroleum source rocks. AAPG Bulletin, 69 (8): 1255-1268.
• 23.MUSIAŁ Ł. & TABOR M. 1988 - Karbon Lubelskiego Zagłębia Węglowego. Stratygrafia karbonu na podstawie makrofauny. Prace Państwowego Instytutu Geologicznego, 72: 88-112.
• 24.NOBLE R.A., ALEXANDER R.I., KAGI R.I. & KNOX J. 1985 -Tetracyclic diterpenoid hydrocarbons in some Australian coals, sediments and crude oils. Geochimica et Cosmochimica Acta, 49 (10): 2141-2147.
• 25.NOTT CJ., XIE S., AVSEJS L.A. & MADDY D. 2000 - n-Alkane distributions in ombrotrophic mires as indicators of vegetation change related to climatic variation. Organic Geochemistry, 31 (2-3): 231-235.
• 26.OLSZÓWKA A. 1989 -Warunki hydrogeologiczne Lubelskiego Zagłębia Węglowego. Górnictwo węgla kamiennego. Prace Państwowego Instytutu Geologicznego, 75: 64-66.
• 27.OTTO A., WALTHER H. & PÜTTMANN W. 1997 - Sesqui- and diterpenoid biomarkers preserved in Taxodium rich Oligocene oxbow lake clays, Weisselster basin, Germany. Organic Geochemistry, 26 (1-2): 105-115.
• 28.OTTO A. & SIMONEIT B.R. 2001 - Chemosystematic and diagenesis of terpenoids in fossil conifer species and sediment from the Eocene Zeitz formation, Saxony, Germany. Geochimica et Cosmochimica Acta, 65 (20): 3505-3527.
• 29.OURISSON G., ALBRECHT P. & ROHMER M. 1979 - The hopano-ids: Palaeochemistry and biochemistry of a group of natural products. Pure and Applied Chemistry, 51 (4): 709-729.
• 30.PETERS K.E. & MOLDOWAN J.M. 1993 - The biomarker guide. Interpreting molecular fossils in petroleum and ancient sediments. Prentice Hall, Englewood Cliffs, NJ: 1-363.
• 31.PHILP R.P. 1985 - Fossil fuel biomarkers. Methods in Geochemistry and Geophysics. Elsevier, 23: 1-294.
• 32.PHILP R.P. 1994 - Geochemical characteristic of oils derived predominantly from terrigenous source materials. In: Coal and coal-bearing strata as oil-prone source rocks? (eds. A.C. Scott and A.J. Fleet), Geological Society Special Publication, 77: 71-91.
• 33.RADKE M., WELTE D.H. & WILSCH H. 1986 - Maturity parametrs based on aromatic hydrocarbons: Influence of organic matter type. Organic Geochemistry, 10 (1-3): 51-63.
• 34.ROTHWELL G.W., MAPES G. & MAPES R.H. 1997 - Late Paleozoic conifers of North America: structure, diversity and occurrences. Review of Palaeobotany and Palynology, 95 (1-4): 95-113.
• 35.ROTHWELL G.W., MAPES G. & HERNANDEZ-CASTILLO G.R. 2005 - Hanskerpia gen. nov. and phylogenetic relationships among the most ancient conifers (Voltziales). Taxon, 54 (3): 733-750.
• 36.SCHULTZE T. & MICHEALIS W 1990 - Structure and origin of ter-penoid hydrocarbons in some German coals. Organic Geochemistry, 16 (4-6): 1051-1058.
• 37.SCHEFFLER K. 2004 - Reconstruction of sedimentary environment and climate conditions by multi-geochemical investigations of Late Palaeozoic glacial to postglacial sedimentary sequences from SW-Gon-dwana. Dissertation zur Erlangung des Doktorgrades der Mathemati-sch-Naturwissenschaftlichen Fakultät der Rheinischen Fredrich-Wilhelms-Univeristät, Bonn, http://deposit.ddb.de.
• 38.SEIFERT W.K. & MOLDOWAN J.M. 1980 - The effect of thermal stress on source-rock quality as measured by hopane stereochemistry. Physics and Chemistry of the Earth, 12: 229-237.
• 39.SIESKIND O., JOLY G. & ALBRECHT P. 1979 - Simulation of the geochemical transformation of sterols: superacid effect of clay minerals. Geochimica et Cosmochimica Acta, 43 (10): 1675-1680.
• 40.SIMONEIT B.R.T. 1977 - Diterpenoid compounds and other lipids in deep-sea sediments and their geochemical significance. Geochimica et Cosmochimica Acta, 41 (4): 463-476.
• 41.SIMONEIT B.R.T. 1986 - Cyclic terpenoids of the geosphere. [In]: Johns, R.B. (Ed.), Biological Markers in the Sedimentary Record. Elsevier, Amsterdam: 43-99.
• 42.SOBOŃ-PODGÓRSKA J. 1988 - Karbon Lubelskiego Zagłębia Węglowego. Stratygrafia karbonu na podstawie mikrofauny (otworni-ce). Prace Państwowego Instytutu Geologicznego, 72: 112-120. TISSOT B.P. & WELTE D.H. 1984 - Petroleum formation and occurrence. 2nd Edition. Springer Verlag: 1-699.
• 43.VOLKMAN J.K. & MAXWELL J.R. 1986 - Acyclic isoprenoids as biological markers. [In]: Biological markers in the sedimentary record, (ed. R.B. Johns). Methods in Geochemistry and Geophysics. Elsevier, 24: 1-12.
• 44.WEN Z., RUIYONG W., RADKE M., QINGYU W., GUOYING S. & ZHILI L. 2000 - Retene in pyrolysates of algal and bacterial organic matter. Organic Geochemistry, 31 (7-8): 757-762.