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The results of investigations on PAHs concentration changes during chemical stabilisation of sewage sludge with Fenton's reagent (1 g of solid FeSO, 7H2O and 10 to 500 cm3 of H2O2 (30%) per dm3; for 2 hours at 20 š 1 °C) are presented. Raw and digested sewage sludge was chemically stabilised. Extraction of PAHs from the solid phase was performed using an ultrasonic method (with cyclohexane: dichioromethane mixture). To extract micropollutants from the supernatant cyclohexane: dichioromethane: methanol mixture was used). The results obtained suggest that PAH concentration changes in chemically stabilised sewage sludge are dependent not only on the chemical oxidant dose but also on the kind of sewage sludge (raw or digested) treated. However, no linear correlation was found between PAH concentrations and the dose of oxidant. A high correlation was observed between PAH concentrations in the supernatant and their water solubility.
Czasopismo
Rocznik
Tom
Strony
249--257
Opis fizyczny
bibliogr. 11 poz., tab., wykr.
Twórcy
autor
- Częstochowa University of Technology, Department of Chemistry, Water and Wastewater Technology, 69 Dąbrowskiego, Częstochowa 42-200, Poland Tel. +48 34 32 50 455, Fax. 448 34 32 50 496, ewisniowska@is.pcz.czest.pl
Bibliografia
- [1] Barbusiński K.., Filipek K. 2000. Aerobic Sludge Digestion in the Presence of Chemical Oxidising Agents. Part II. Fenton's Reagent. Polish Journal of Environmental Studies 9(3): 145 - 149.
- [2] Bernacka L, Pawłowska L. 2000. Potentially toxic substances in sludges from municipal treatment plants. Dział Wydawnictw IOŚ, Warszawa (in Polish).
- [3] Bodzek D., Janoszka B. 1999. Comparison of Polycyclic Aromatic Hydrocarbons and Heavy Metals Contents in Sewage Sludge from Industrialised and Non-Industrialised Region. Water, Air and Soil Pollution 111, 359 -369.
- [4] Buyukkamaci N. 2004. Biological Sludge Conditioning by Fenton's Reagent. Process Biochemistry. 39, 1503 - 1506.
- [5] Flotron V., Delteil C, Bermond A., Camel V. 2003. Remediation of Matrices Contaminated by Polycyclic Aromatic Hydrocarbons: Use of Fenton's Reagent. Polycyclic Aromatic Compounds. 23, 353 -376.
- [6] Flotron V., Delteil C, Bermond A., Camel V. 2005. Removal of Sorbed Polycyclic Aromatic Hydrocarbons from Soil, Sludge and Sediment Samples Using the Fenton's Reagent Process. Chemosphere. 59(10),1427 - 1437.
- [7] Hermanowicz W., Dojlido J., Dożańska W., Koziorowski B. Zerbe I., 1999. Physicochemical Characteristic of Water and Wastewater, Arkady, Warsaw (in Polish). 555pp.
- [8] Krzemieniewski M., Janczukowicz W., Pesta J. Dębowski M., 2003. Effect of Fenton's Reagent and Phenomena Connected with Current Effect on Sewage Sludge Conditioning. In Proceedings of the Conference: Complex and Detailed Problems of Environmental Engineering, Koszalin, 195 -213 (in Polish).
- [9] Nam K., Rodrigues W., Kukor J. 2001. Enhanced degradation of polycyclic aromatic hydrocarbons by biodegradation combined with modified Fenton reaction. Chemosphere. 45(1),11 - 20.
- [10] Stevens J.L., Northcott G.L., Stern G.A., Tomy G.T., Jones K.C., 2003. PAHs, PCBs, PCNs, Organochlorine pesticides, Synthetic Musks and Polychlorinated n-Alkanes in U.K. Sewage Sludge: Survey Results and Implications. Environmental Science & Technology. 37, 462-467.
- [11] Working Document on Sludge. 3rd Draft. EU Commission, Brussels, 27 April, 2000
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS5-0013-0044
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