Redoks aktywne receptory kationów i anionów

• Autorzy: Zięba K. , Taraszewska J.

Warianty tytułu

EN

Redox-active receptors of cations and anions

• Języki publikacji: PL

Abstrakty

EN

The electrochemical recognition of cationic, anionic and neutral guests is a fast expanding research area on the interface of electrochemistry and supramolecular chemistry. Its aim is the development of highly sensitive and selective receptors [2, 3]. The redox-active receptors usually consist of two units: the guest binding site and the redox-active unit. After complexation of a guest at the binding site, the changes of the electrochemical properties of redox-active center give information about the complexation. The idea of redox-active receptors is presented in Scheme 1. The present review is devoted to different types of redox-active receptors for cationic and anionic guests. Receptors able to recognize cations are presented according to the mechanism of a communication between redox-active and binding units. These mechanisms are: through bonds communication, through space communication, direct coordination of a cation to redox-active center and the conformational change of redox-center mechanism. In the next chapter are discussed the redox-active receptors for anions according to the type of the redox-active center. In complexation of anionic guests the major role plays the possibility of the creation of hydrogen bonds between anion and receptor. The most extensively studied redox center was ferrocen. Nowadays, in the construction of redox-active receptors more often complexes of metal cations are used [53, 54].

Słowa kluczowe

PL

aktywne receptory redoks; kompleksowanie; kationy; elektrochemia; aniony

EN

redox-active receptors; electrochemistry; complexation; cation; anion

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 2008
• Tom: [Z] 62, 3-4
• Strony: 237--267
• Opis fizyczny: bibliogr. 58 poz., tab., wykr.

Twórcy

autor

Zięba K.

autor

Taraszewska J.

• Instytut Chemii Fizycznej Polskiej Akademii Nauk, ul. Kasprzaka 44/52, 01-224 Warszawa,

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