Synteza amfifilowych kopolimerów szczepionych metodą kontrolowanej (ko)polimeryzacji rodnikowej hydrofilowego makromonomeru poli(tlenku etylenu)

Neugebauer, D.

Artykuł - szczegóły

Tytuł artykułu

Synteza amfifilowych kopolimerów szczepionych metodą kontrolowanej (ko)polimeryzacji rodnikowej hydrofilowego makromonomeru poli(tlenku etylenu)

Autorzy

Neugebauer D.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

Synthesis of amphiphilic graft copolymers via controlled radical (co)polymerization of hydrophilic poly(ethylene oxide) macromonomer

Języki publikacji

Abstrakty

A combination of hydrophilic and hydrophobic characters in one macromolecule of a polymer provides amphiphilic behavior [1, 2]. Such unique properties, which have found significant interest, are exhibited by graft copolymers containing poly(ethylene oxide) (PEO) as side chains attached to the backbone (Scheme 1) [20]. They have greatly expanded a class of materials important for science and biomedicine. This review article describes the PEO graft copolymers prepared by a variety of synthetic procedures used for the atom transfer radical (co)polymerization (ATRP) (Scheme 2) [15-17], i.e. directly by the grafting through, which is also named as the macromonomer method or by the grafting from technique, which requires the use of a multifunctional macroinitiator. Densely homografted copolymers also called molecular brushes [21-25] were obtained by homopolymerization of PEO macromonomer (Scheme 3). The density of PEO grafts was decreased in the copolymerization of PEO macromonomer with a low molecular weight comonomer resulting in loosely grafted copolymers contai-ning uniform PEO side chains (Scheme 4) [46-48]. Consequently, the copolymerization of two macromonomers yielded heterografted brushes (Scheme 5) [21, 23, 26, 45, 53-57]. In this case, the composition of copolymers was designed by the selection of proper comonomers with comparable (rM1 = rM2/rM1 ~ rM2) or different (rM1 > rM2, rM1 < rM2) reactivity ratios, which can form alternating/ random copolymers or spontaneous gradient of PEO chains along backbone, respectively. Using monofunctional macroinitiators with comb or linear composition for polymerization of PEO macromonomer resulted in comb-comb [31] or semi-comb diblock copolymers [21, 23, 27-30]. The reverse structures were also obtained, when the PEO graft copolymers were applied as the monofunctional macroinitiators [31, 32]. The use of polymeric multifunctional macroinitiators (graft or linear) in the polymerization of monomer or macromonomer led to the heterografted copolymers (Scheme 4) [32, 50, 51] or more complexed double grafted copolymers (Scheme 3) [25]. The applications of the PEO graft copolymers in numerous fields are also presented to show their versatile potential [25, 26, 46, 53, 55, 56, 68-76].

Słowa kluczowe

kopolimery szczepione amfifilowość PEO ATRP

graft copolymers amphiphilicity PEO ATRP

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2008

Tom

[Z] 62, 1-2

Strony

49--66

Opis fizyczny

bibliogr. 76 poz., wykr.

Twórcy

autor

Neugebauer D.

Instytut Nauki o Materiałach, Uniwersytet Śląski, ul. Bankowa 14, 40-007 Katowice

Bibliografia

[1] G. Riess, P. Bahadur, [w:] "Block Copolymers" [ w: J Encyclopedia of Polymer Science and Engineering, ME Mark; N.M. Bikales; C.G. Overberger; G. Menges, Eds., John Wiley, New York, 1985. Vol. 2, p 324.
[2] F.S. Bates, G.H. Fredrickson, Ann. Rev. Phys. Chem., 1990, 41, 525.
[3] G.H. Fredrickson, Macromolecules. 1993. 26. 2825.
[4] J. Ruokolainen, M. Saariaho, O. Ikkala. G. ten Brinke. E.L. Thomas. M. Torkkcli. R. Scrimaa. Macromolecules, 1999,32, 1152.
[5] A. Subbotin. M. Saariaho, O. Ikkala. G. ten Brinke. Macromolecules, 2000, 33, 3447.
[6] P. Rempp. P. Lutz, P. Masson, P. Chaumount, F.. Franta, Macromol. Chem. Suppl., 1985. 13, 47.
[7] Y. Tsukahara, K. Tsutsumi, Y. Yamashita, S. Shimada, Macromolecules, 1990, 23. 5201.
[8] M. Wintermantel, M. Gerle. K. Fischer, M. Schmidt, 1. Wataoka, H. Urakawa, K. Kajiwara, Y. Tsukahara, Macromolecules, 1996, 29, 978.
[9] K. Yamada, M. Miyazaki, K. Ohno, T. Fukuda, M. Minoda, Macromolecules, 1999,32. 290.
[10] R. Djalali, N. Hugenberg, K. Fischer, M. Schmidt, Macromol. Rapid Commun.. 1999, 20, 444.
[11] M. Schappacher. A. Defficux, Macromolecules, 2000,33, 7371.
[12] K.L. Beers. S.G. Gaynor, K. Matyjaszewski, S.S. Sheiko. M. Moller, Macromolecules, 1998. 31, 9413.
[13] H.G. BGrner, K.L. Beers. K. Matyjaszewski, S.S. Sheiko, M. Moller. Macromolecules, 2001. 34, 4375.
[14] G. Cheng, A. BOker. M. Zgang, G. Krausch, A.H.F.. Miiller, Macromolecules, 2001, 34, 6883.
[15] J.-S. Wang. K. Matyjaszewski. .1. Am. Chem. Soc. 1995. 117, 5614.
[16] K. Matyjaszewski, I. Xia. Chem. Rev., 2001, 101. 2921.
[17] M. Kamigaito, T. Ando. M. Sawamoto, Chem. Rev., 2001, 101, 3689.
[18] .1. Gromada, J. Spanswick, K. Matyjaszewski. Macromol. Chem. Phys., 2004, 205, 551.
[19] W. Tang, K. Matyjaszewski, Macromolecules, 2006, 39, 4953.
[20] D. Neugebauer, Polym. Int.. 2007. 56, 1469.
[21] X.-S. Wang, S.F. Lascelles, R.A. Jackson, S.P. Armes, Chem. Commun., 1999, 1817.
[22] S. Perrier, S.P. Armes, X.S. Wang, F.L.G. Malet, D.M. Haddleton, J. Polym. Sci. Part A: Polym. Chem., 2001,39. 1696.
[23] X.-S. Wang. S.P. Armes, Macromolecules, 2000, 33, 6640.
[24] X. S. Wang, F.L.G. Malet, S.P. Armes, D.M. Haddleton, S. Perrier. Macromolecules, 2001,34,162.
[25] D. Neugebauer, Y. Zhang, T. Pakuła, S.S. Sheiko, K. Matyjaszewski, Macromolecules, 2003, 36, 6746.
[26] D. Neugebauer, M. Theis, G. Wegner, T. Pakuła, K. Matyjaszewski, Macromolecules, 2006, 39, 584.
[27] X. Li, J. Ji, J. Shen, Polymer, 2006, 47. 1987.
[28] J.K. Oh, F. Perineau, K. Matyjaszewski, Macromolecules, 2006. 39, 3161.
[29] K.L. Robinson, M. V. de Paz-Banez, X. S. Wang, S. P. Armes, Macromolecules, 2001, 34. 5799.
[30] J. Kurjata, J. Chojnowski, C.-T. Yeoh, N.A.A. Rossi, S.J. Holder, Polymer, 2004, 45. 6111.
[31] G. Street, D. Illsley, S.J. Holder, J. Polym. Sci. Part A: Polym. Chem., 2005, 43, 1129.
[32] K. Ishizu, J. Satoh, A. Sogabe, J. Colloid Interface Sci., 2004, 274, 472.
[33] L. Bes, S. Angot, A. Limer, D.M. Haddleton, Macromolecules, 2003, 36, 2493.
[34] D. Bontempo, H.D. Maynard, J. Am. Chem. Soc, 2005, 127, 6508.
[35] R. Duncan, Nat. Rev. Drug Discovery, 2003, 2, 347.
[36] K. Velonia, A.E. Rowan, R.J. Nolte, J. Am. Chem. Soc, 2002, 124, 4224.
[37] Z. Ding, R.B. Fong, C..I. Long, PS. Stayton, AS. Hoffman, Nature, 2001. 411. 59.
[38] K.L. Beers, Ph.D. Thesis, 2000, Pittsburgh. PA.
[39] D. Neugebauer, B.S. Sumerlin, K. Matyjaszewski. B. Goodhart, S.S. Sheiko, Polymer, 2004, 45, 8179.
[40] A. Muhlenbach, F. Rime, J. Polym. Sci. Part A: Polym. Chem., 2003, 41, 3425.
[41] S.G. Roos, A.H.E. Miiller, K. Matyjaszewski, Macromolecules, 1999, 32, 8331
[421 S.C. Hong, K. Matyjaszewski, A.E. Gottfried, M. Brookhard, Polym. Mater. Sci. Eng.. 2001, 84.
[43] H. Shinoda, K. Matyjaszewski, Macromolecules, 2001, 34, 6243.
[44] S. Nguyen, R.H. Marchessault, Macromolecules, 2005, 38, 290.
[45] D. Neugebauer. J. Rydz, 1. Gobel, P. Dacko, M. Kowalczuk, Macromolecules, 2007, 40. 1767.
[46] J.F. Hester, P. Banerjee. Y.-Y. Won, A. Akthakul, M.H. Acar, A.M. Mayes, Macromolecules, 2002, 35, 7652.
[47] M.M. Ali, H.D.H. Stover, Macromoiecules, 2004, 37. 5219.
[48] Y. Wang, G. Lu. J. Huang, J. Polym. Sci. Part A: Polym. Chem.. 2004, 42, 2093.
[49] D. Zhang, C. Ortiz, Macromolecules, 2004, 37, 4271.
[50] D. Neugebauer, Y. Zhang. T. Pakuła, K. Matyjaszewski, Polymer, 2003, 44, 6863.
[51] R. Venkatesh, L. Yajjou, C. E. Koning, B. Kliimperman, Macromol. Chem. Phys., 2004,205, 2161.
[52] T. Stephan, S. Muth. M. Schmidt. Macromolecules. 2002. 35, 9857.
[53] J.-F. Lutz, A. Hoth, Macromolecules, 2006, 39, 893.
[54] P. Xu, H. Tang, S. Li, J. Ren, E. Van Kirk, W. .1. Murdoch, M. Radosz, Y. Shen, Biomacromolecules, 2004,5,1735.
[55] D. Neugebauer, Y. Zhang, T. Pakuła. K. Matyjaszewski, Macromolecules, 2005. 38. 8687.
[56] D. Neugebauer, Zhang Y, Pakuła T., J. Polym. Sci. Part A, 2006, 44, 1347.
[57] D. Neugebauer, Polymer, 2007, 48, 4966.
[58] F. R. Mayo, F. M. Lewis, J. Am. Chem. Soc. 1944. 66, 1594.
[59] V. Jaacks, Makromol. Chem. Commun., 1972, 161, 161.
[60] J. C. Bevington, B. W. Malpass. Eur. Polym. J., 1965, 1, 85.
[61] H. Yuki. Y. Okamoto, S. Shimada. K. Ohta, K. Hatada, J. Polym. Sci. Part A: Polym. Chem.. 1979, 17,1215.
[62] D.M. Haddleton, M.C. Crossman, K.H. Hunt, C. Topping, C. Waterson, K.G. Suddaby, Macromolecules, 1997,30,3992.
[63] H. Uegaki. M. Kotani. M. Kamigato, Sawamoto, M., Macromolecules. 1998, 31, 6756.
[64] G. Moineau. M. Minet, P. Dubois, P. Teyssie, T. Senninger. R. Jerome, Macromolecules. 1999,32, 27.
[65] M.J. Ziegler, K. Matyjaszewski, Macromolecules, 2001, 34, 415.
[66] A.I. Buzin, M. Pyda, P. Costanzo, K. Matyjaszewski, B. Wunderlich, Polymer, 2002, 43. 5563.
[67] A.S. Brar, S. Kaur, Polym. J., 2005, 37. 316.
[68] S. Han, M. Hagiwara, T. lshizone, Macromolecules, 2003, 36, 8312.
[69] H.W. Kim, C.W. Chung, Y.H. Rhee, Int. J. Biol. Macromol., 2005, 35, 47.
[70] A. Dal Pozzo, L. Vanini, M. Fagnoni, M. Guerrini, A. De Benedittis. R.A.A. Muzzarelli. Carbohydr. Polym., 2000, 42, 201.
[71] H.-Q. Xie, M.-H. Cui, J.-S. Guo. Eur. Polym. J., 1997, 33, 1537.
[72] G. Wegner, P. Baum, M. Mueller, J. Norwig, K. Landfester, Macromol. Symp.. 2001, 175. 349.
[73] R.C. Hoffmann, S. Jia, J.C. Bartolome, T.M. Fuchs, J. Bill, P.C.J. Graat, ct al., J. Eur. Ceram. Soc, 2003,23,2119.
[74] Y. Zhang. N. Costantini, M. Mierzwa. T. Pakuła, D. Neugebauer, K. Matyjaszewski, Polymer, 2004, 45, 6333.
[75] B. Drescher, A.B. Scranton, J. Klier, Polymer, 2001, 42, 49.
[76] S.C. Hadjiyannakou, M. Vamvakaki, C.S. Patrickios, Polymer, 2004, 45, 3681.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUS5-0011-0002