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Języki publikacji
Abstrakty
Ethoxylation of methanol, ethanol and butanol in the electric fields of 50 Hz and 2.45 GHz frequency was investigated. The conversion of oxirane, fractional composition of the obtained ethoxylates, and the byproduct contents were determined. The catalyst affects the electrical parameters of the reactions' medium, which can be used as a convenient tool for the the process control. No additional influence on the reaction path and the products distribution was detected except for the thermal effects of the investigated electric fields. A negative exception exists with the 50 Hz electric field ethoxylation of methanol.
Czasopismo
Rocznik
Tom
Strony
10--15
Opis fizyczny
Bibliogr. 19 poz., tab., rys., wykr.
Twórcy
autor
- "Blachownia" Institute of Heavy Organic Synthesis, ul. Energetyków 9, 47-225 Kędzierzyn-Koźle, Poland
autor
- Silesian Technical University, Department of Mathematics and Physics, Gliwice, Poland
Bibliografia
- (1) Lund H., Baizer M. M., Organic Electrochemistry; Marcel Dekker, Inc.: New York, 1991.
- (2) Little R. D., Weinberg N. L., Electroorganic Synthesis; Marcel Dekker, Inc.: New York, 1991.
- (3) Mingos D. M. P., Microwaves in Chemical Syntheses, Chem. Ind. 1994, 1 August, 596.
- (4) Gedye R., Smith F., Westaway K., Ali H., Baldisera L., Laberge L., Rousell J., The use of Microwave Ovens for Rapid Organic Synthesis Tetrahedron Letters, 1986, 27, 276.
- (5) Bose A. K., Manhas M. S., Banik B. K., Robb E. W., Microwave-induced organic reaction enhancement (more) chemistry: techniques for rapid, safe and inexpensive synthesis Res. Chem. Intermed., 1994, 20, 1.
- (6) Bailey F. E., Koleske Jr. J. V., Alkylene Oxides and Their Polymers; Marcel Dekker, Inc. New York, 1991.
- (7) Falbe J., Surfactants in Consumer Products, Springer-Yerlag: Heidelberg, 1987.
- (8) Hreczuch W., Poskrobko H., Pyżalski K., Szymanowski J., OxyethyIation and Oxypropylation of Low Molecular Alcohols, Ind. Eng. Chem. Res., 1999, 38, 2225.
- (9) Hreczuch W., Bekierz G, Szymanowski J., Homologue Distribution of Alcohol Ethoxylates, Tenside Surfactants Deterg. 1995, 32, 55.
- (10) Voelkel A., Szymanowski J., Hreczuch W., Polarity of Broad and Narrow Distributed EthoxyIates of Fatty Alcohols, J. Am. Oil Chem. Soc, 1993, 70, 711.
- (11) Barhoum R,, Szymanowski J., Hreczuch W., Meissner E., Narrowing of Alkylphenol Ethoxylate Distribution, J. Chem. Technol. Biotechnol. 1994, 61, 215.
- (12) Poskrobko H., Poskrobko J., Hreczuch W., Sobczyńska A., Szymanowski J.,OxyethyIation and Oxypropylation of Alcohols of Low Molecular Mass in the Presence of Amine-Type Catalysts, J. Chem. Technol. Biotechnol., 2000, 75, 1.
- (13) Hreczuch W., Szymanowski J., Synthesis of Surfactants with Narrow-Range Distribution of Polyoxyalkylene Chain, J. Am. Oil Chem. Soc. 1996, 73, 73.
- (14) Garcia M. T., Ribosa I., Leal S. J., Hreczuch W., Effect of Homolog Distribution on the Toxicity of Alcohol Elhoxylates, J, Am. Oil Chem. Soc. 1996, 73, 903.
- (15) Lebedev, N. N.; Savelyanov, W. P. Baranov. Y. I. Rules for Ethylene Oxide Distribution in oils Reaction with Alcohols and Water and Determination of the Products Formed. Usp. Dokl. Khim. 1969, 8, 1815.
- (16) Zimakov P., Tshurakov A., Prigotovleniye Monoetilovogo Efira Etilenglikolya, Prom. Org. Khim., 1936, 1, 329.
- (17) Weibull B., The distribution of Compounds Formed in the Reaction between Ethylene Oxide and Alcohols, Acta Chem. Scand. 1995, 49, 207.
- (18) Szymanowski J., Atamańczuk B., Szewczyk H., Molar mass distribution of the polioxyethylene derivatives of alcohols, alkylphenols and alkylamines. J. Chem. Technol. Biotechnol. 1987, 40, 1.
- (19) Poskrobko J., Wasilewski J., Dziwiński E., Poskrobko H., By-products of alcohol ethoxylation in the presence of triethylamine, Tenside Surfactants Deterg. 1995, 32, 351.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS3-0020-0065
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