The synthesis of 1-propenyl ethers and their photopolymerization

• Autorzy: Martysz D. , Urbala M. , Antoszczyszyn M.

Warianty tytułu

PL

Synteza eterów 1-propenylowych i ich fotopolimeryzacja

• Języki publikacji: EN

Abstrakty

EN

The di(l-propenyl) ether has been observed to be a highly reactive monomer in photoinitiated cationic polymerization undergoing very high conversions to polymer at very short irradiation times. The polymerization process was investigated for various UV-systems containing: the model 1-propenyl ether 1,4-dipropenoxybutane, the epoxy resin Epidian 6 or the unsaturated polyester resin Estromal 103 and cationic or radical initiator. The amounts of ether and initiators were changed in compositions.

Słowa kluczowe

EN

isomerization of allyl ethers; propenyl ethers; photopolymerization

PL

izomeryzacja eterów allilowych; etery propenylowe; fotopolimeryzacja

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2001
• Tom: Vol. 3, nr 3
• Strony: 25--26
• Opis fizyczny: Bibliogr. 8 poz., tab.

Twórcy

autor

Martysz D.

• Institute of Organic Chemical Technology, Technical University of Szczecin, Pułaskiego St. 10, 70-322 Szczecin, Poland

autor

Urbala M.

• Institute of Organic Chemical Technology, Technical University of Szczecin, Pułaskiego St. 10, 70-322 Szczecin, Poland

autor

Antoszczyszyn M.

• Institute of Organic Chemical Technology, Technical University of Szczecin, Pułaskiego St. 10, 70-322 Szczecin, Poland

Bibliografia

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• (3) Crivello J. V., Design of network polymers by photopolymerization, Die Angewandte Makromolekulare Chemie, 1996, 240, 83-90.
• (4) Crivello J. V., Jo K., Propenyl ethers. I. The synthesis of propenyl ether monomers, J. Polym. Sci. Part A: Polym. Chem., 1993, 31, 1473-1482.
• (5) Krompiec S., Izomeryzacja alkenów i ich funkcyjnie podstawionych pochodnych katalizowana kompleksami rutenu, Zesz. Nauk. Pol. Śl., 1997, 136.
• (6) Crivello J. V., Sangermano M., Visible and long-wave-length photoinitiated cationic polymerization, J. Polym. Sci. Part A: Polym. Chem., 2001, 39, 343-356.
• (7) Janus E., Antoszczyszyn M., Urbala M., Synthesis of mono-and diallyl athers of 1,4-dihydroxybutane, (Z)-1,4-dihydroxy-2-butene and 1,4-dihydroksy-2-butyne, Polish J. Appl Chem., 1999, 43, 77-83.
• (8) Lewison J. J., Robinson S. N., Transition-metal complexes containing phosphorus ligands Part III. Convenient syntheses of some triphenylphosphine complexes of the platinum metals, J. Chem. Soc. (A), 1970, 2947.