Non-waste synthesis of 1-propenoxyl monomers

• Autorzy: Urbala M. , Antoszczyszyn M. , Krompiec S.

Warianty tytułu

PL

Bezodpadowa synteza monomerów 1-propenoksylowych

• Języki publikacji: EN

Abstrakty

EN

Non-waste synthesis of 1-propenoxyl monomers of C4 diols ((Z)-butane-2-ene-l,4-diols) via isomerization of the corresponding allyl ethers of diols catalysed by the ruthenium(II) complexes has been investigated. [RuHCl(CO)(PPh3)3] is a very active and selective catalyst precursor of isomerization of allyl ethers of diols, containing neither a triple bond nor unprotected primary allylic hydroxyl group. The optimal parameters for the synthesis of 1-propenyl ethers and their physic-chemical properties ('H NMR, MS, boiling point) are given. Synthesized propenyl ether monomers were of high purity, therefore, they are suitable directly for use in photointiated cationic polymerization.

Słowa kluczowe

EN

1-propenyl ethers; isomerization of allyl ethers; cationic photopolymerization

PL

etery 1-propenylowe; izomeryzacja eterów allilowych; kationowa fotopolimeryzacja

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2001
• Tom: Vol. 3, nr 3
• Strony: 22--24
• Opis fizyczny: Bibliogr. 6 poz., tab.

Twórcy

autor

Urbala M.

• Institute of Organic Chemical Technology, Technical University of Szczecin, Pułaski St. 10, 70-322 Szczecin

autor

Antoszczyszyn M.

• Institute of Organic Chemical Technology, Technical University of Szczecin, Pułaski St. 10, 70-322 Szczecin

autor

Krompiec S.

• Institute of Inorganic Chemistry, Technology and Electrochemistry. Silesian Technical University. Krzywoustego St. 6. 44-100 Gliwice

Bibliografia

• (1) Rajaraman S., Crivello J., Tandem isomerization/cationic polymerization of allylic ethers, Polym. Mater. Sci. Eng., 1997, 77, 603 - 604.
• (2) Parri O. And Farrand L., Reactive mesogenoc propenyl ethers, (Merck Patent Gmbh, Germany); Brit. UK Pat. Appl. GB 2311289 A1; 1998.
• (3) Saito T., Maeda K., Yamoda S., Light-curable coating materials for paper, (Sanyo Chemical Industriers Ltd., Japan); JP 09143897 A2, 1997.
• (4) Crivello J., Jo K., Propenyl ethers. 1. The synthesis of propenyl ether monomers, J. Polym. Sci. Part A: Polym. Chem., 1993, 31, 1473-1482.
• (5) Krompiec S., Izomeryzacja alkenów i ich funkcyjnie podstawionych pochodnych katalizowana kompleksami rutenu, Zesz. Nauk. Pol. Śl., 136, 1997.
• (6) Janus E., Antoszczyszyn M., Urbala M., Synthesis of mono- and diallyl ethers of 1,4-dihydroxybutane, (Z)-1,4-dihydroxy-2-butene and1,4-dihydroxy-2-butyne, Polish J. Appl. Chem., 1999, 43, 77 - 83.