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Bezodpadowa synteza monomerów 1-propenoksylowych
Języki publikacji
Abstrakty
Non-waste synthesis of 1-propenoxyl monomers of C4 diols ((Z)-butane-2-ene-l,4-diols) via isomerization of the corresponding allyl ethers of diols catalysed by the ruthenium(II) complexes has been investigated. [RuHCl(CO)(PPh3)3] is a very active and selective catalyst precursor of isomerization of allyl ethers of diols, containing neither a triple bond nor unprotected primary allylic hydroxyl group. The optimal parameters for the synthesis of 1-propenyl ethers and their physic-chemical properties ('H NMR, MS, boiling point) are given. Synthesized propenyl ether monomers were of high purity, therefore, they are suitable directly for use in photointiated cationic polymerization.
Czasopismo
Rocznik
Tom
Strony
22--24
Opis fizyczny
Bibliogr. 6 poz., tab.
Twórcy
autor
- Institute of Organic Chemical Technology, Technical University of Szczecin, Pułaski St. 10, 70-322 Szczecin
autor
- Institute of Organic Chemical Technology, Technical University of Szczecin, Pułaski St. 10, 70-322 Szczecin
autor
- Institute of Inorganic Chemistry, Technology and Electrochemistry. Silesian Technical University. Krzywoustego St. 6. 44-100 Gliwice
Bibliografia
- (1) Rajaraman S., Crivello J., Tandem isomerization/cationic polymerization of allylic ethers, Polym. Mater. Sci. Eng., 1997, 77, 603 - 604.
- (2) Parri O. And Farrand L., Reactive mesogenoc propenyl ethers, (Merck Patent Gmbh, Germany); Brit. UK Pat. Appl. GB 2311289 A1; 1998.
- (3) Saito T., Maeda K., Yamoda S., Light-curable coating materials for paper, (Sanyo Chemical Industriers Ltd., Japan); JP 09143897 A2, 1997.
- (4) Crivello J., Jo K., Propenyl ethers. 1. The synthesis of propenyl ether monomers, J. Polym. Sci. Part A: Polym. Chem., 1993, 31, 1473-1482.
- (5) Krompiec S., Izomeryzacja alkenów i ich funkcyjnie podstawionych pochodnych katalizowana kompleksami rutenu, Zesz. Nauk. Pol. Śl., 136, 1997.
- (6) Janus E., Antoszczyszyn M., Urbala M., Synthesis of mono- and diallyl ethers of 1,4-dihydroxybutane, (Z)-1,4-dihydroxy-2-butene and1,4-dihydroxy-2-butyne, Polish J. Appl. Chem., 1999, 43, 77 - 83.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS3-0020-0057