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Polycondensation of urea phosphate to ammonium polyphosphate

Autorzy
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Ammonium polyphosphate of average chain length n = 2.5 - 3.0 can be obtained through the polycondensation of urea phosphate at a temperature of 140 - 160°C. The phosphates fraction in the product amounts to about 90% whereby it has a high capacity to chelate fertilizer microelements. The effect of such parameters as temperature and reaction time on the composition and kinetics of the reaction was assessed by means of derivatographic and model tests.
Rocznik
Strony
8--12
Opis fizyczny
Bibliogr.16 poz., tab., rys., wykr.
Twórcy
autor
  • Institute of Inorganic Technology and Mineral Fertilizers, Faculty of Chemistry, Wroclaw University of Technology, ul. Wybrzeże Wyspiańskiego 27, 50-370 Wroclaw, Poland
Bibliografia
  • (1) Kočetkov V.N., Issiedovanie po proizvodstvu polifosfatov ammonija na osnove ekstrakcyjnnoj fosfornoj kisloty soderzaščej 50 - 54% P2O5, Chim. Prom., 1994, 2, 94.
  • (2) Kočetkov V.N., Tulina E.V., Polučenie polifosfatov ammonija na osnove ammonizacii uparennoj ekstrakcionnoj fosfornoj kisloty v trubčatom reaktore, Chim. Prom., 1991, 6, 347.
  • (3) Stinson J.M., Striplin H.M., Brown N.A., Seatz L.F., Ammonium metaphosphate fertilizer. Pilot plant production and greenhouse tests of fertilizer from ammonia and phosphorus pentoxide vapors, J. Agri. Food Chem., 1956, 3, 248.
  • (4) Postnikov N.N., Termičeskaja fosfornaja kislota, soli i udobrenija na ee osnove, Chimija, Moskva, 1976.
  • (5) Becker P., Phosphates and Phosphoric Acid, Marcel Dekker, New York and Basel, 1989.
  • (6) Slack A.V., Phosphoric acid, Marcel Dekker, New York, 1968.
  • (7) Granular APP and UAP fertilizers using an energyefficient pipe-cross reactor and drum granulator process, New Development in Fertilizer Technology, 16th demonstration, National Fertilizer Development Center TVA, Muscle Shoals, 1987, 25.
  • (8) Commercialization of TVA pressurized pipe-cross reactor for production of DAP, MAP nad APP, New Development in Fertilizer Technology, 16th demonstration, National Fertilizer Development Center TVA, Muscle Shoals, 1987,36.
  • (9) Górecki H., Hoffmann J., Kuzko A., Urea phosphate - a feed additive and preservative, Polish Technical Reviev, 1987, 2 - 3, 22.
  • (10) Lewis H.T., Jones T.M., Bumell J.R., Two-stage process for crystaiizations of urea phosphate for production of clear polyphosphate liquid fertilizer, Ind. Eng. Prod. Res. Dey., 1983,1, 11.
  • (11) Hodge C.A., Motes T.W., Production of high-quality liquid fertilizer from wet process acid via urea phosphate, Fertilizer Research, 1994, 39, 59.
  • (12) Sarbaev A.N., Korjakin A.G., Termografija ortofosfata karbamida, Ž. Prikl. Chim., 1974, 4, 717.
  • (13) Mc Cullough J.F., Sheridan R.C., Frederick L.L., Pyrolysis of urea phosphate, J. Agric. Food. Chem., 1978, 3, 670.
  • (14) Nayar K.V, Gopinath R., Manufacture of high-analysis complex fertilizers through urea-phosphate route from wet-process phosphoric acid, Brit. Chem. Eng., 1970, 11, 1403.
  • (15) Górecki H., Hoffmann J., Schroeder J., Technology of producing fodder urea phosphate from wet process phosphoric acid (in Polish), Przem.Chem., 1982, 1 - 4, 48.
  • (16) Górecki H., Hoffmann J., Kuzko A., Schroeder J., Pilot production of fodder urea phosphate (in Polish), Przem. Chem., 1982, 7, 185.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUS3-0020-0022
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