Synthesis of 3-chloropropyltrichlorosilane via the catalytic hydrosilylation of allyl chloride with trichlorosilane catalyzed by platinum catalyst - from laboratory scale to pilot plant

Guliński, J.; Marciniec, B.; Maciejewski, H.; Oczkowicz, S.

Artykuł - szczegóły

Tytuł artykułu

Synthesis of 3-chloropropyltrichlorosilane via the catalytic hydrosilylation of allyl chloride with trichlorosilane catalyzed by platinum catalyst - from laboratory scale to pilot plant

Autorzy

Guliński J. , Marciniec B. , Maciejewski H. , Oczkowicz S.

Wybrane pełne teksty z tego czasopisma

http://content.sciendo.com/view/journals/pjct/pjct-overview.xml

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Warianty tytułu

Języki publikacji

Abstrakty

The method for the synthesis of 3-chloropropyltrichlorosilane based on the hydrosilylation of allyl chloride with trichlorosilane in the presence of an original Pt catalytic system has been worked out. The yield and selectivity of Cl(CH2)3SiCl3 depend on the nature of the catalytic system and several other factors (the mode of substrate addition, reaction procedure, etc.)- The optimum reaction conditions were determined. A successful scale-up of the process under study allowed us to implement it on a pilot scale as the first step of the newly emerging Polish low-tonnage organosilane industry.

Słowa kluczowe

3-chloropropyltrichlorosilane hydrosilylation trichlorosilane allyl chloride platinum catalyst pilot plant

hydrosililowanie chlorek allilu platyna katalizatory zakład doświadczalny

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

1999

Tom

Vol. 1, nr 1

Strony

11--15

Opis fizyczny

Bibliogr. 38 poz., tab., wykr.

Twórcy

autor

Guliński J.

metalorg@main.amu.edu.pl

Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland, Fax: (61) 865 95 68

autor

Marciniec B.

Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland, Fax: (61) 865 95 68

autor

Maciejewski H.

Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland, Fax: (61) 865 95 68

autor

Oczkowicz S.

UNISIL Co, Lid, Kwiatkowskiego 13, 30-100 Tarnów, Poland

Bibliografia

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Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUS3-0020-0003