Verifying the assumption of a steady-state intermediate concentration

• Autorzy: Głowiński J. , Tylus W.
• Języki publikacji: EN

Abstrakty

EN

The behaviour of the chemical affinity at the stage of intermediate product formation was analysed in a monomolecular, a homogenous catalytic and in a nucleophilic substitution reactions. Under conditions of the steady-state approximation, the rate of change of the chemical affinity at this stage of reaction must be such that the rate of intermediate formation and that of its decay are nearly identical. This assumption was used to determine a quantitative criterion for the steady-state approximation. The method used to derive a criterion is also given. The examples of applications were provided.

Słowa kluczowe

EN

steady-state; complex reaction; intermediate; criterion

PL

stan ustalony; reakcja złożona; półprodukt

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 1999
• Tom: Vol. 1, nr 1
• Strony: 7--10
• Opis fizyczny: Bibliogr. 14 poz., tab., wykr.

Twórcy

autor

Głowiński J.

autor

Tylus W.

• Institute of Inorganic Technology, Wroclaw University of Technology