Chloroorganiczne pestycydy i polichlorowane bifenyle w osadach rzek Polski

• Autorzy: Bojakowska I. , Gliwicz T.

Warianty tytułu

EN

Chlorinated pesticides and polychlorinated biphenyls in river sediments of Poland

• Języki publikacji: PL

Abstrakty

EN

Concentrations of chlorinated pesticides and polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB153, PCB138, PCB180), were determined in 80 river sediment samples collected from the whole area of Poland. Chlorinated pesticides were found in almost all samples. The most frequently detected pesticides were isomer y-HCH (Lindane) and the DDT group compounds. The concentrations of Lindane exceeding the detection limit were recorded in 95% of samples and Lindane contents above the PEL value were noted in 32.5% of the analysed samples. The high contests of pesticides were recorded mainly in river sediments near urban-industrial centres. The presence of p,p’-DDT was noted in 31 samples and its metabolite p,p’-DDE —in 78 samples, and p,p’-DDD —in 69 samples. The concentration of p,p’-DDE above PEL value (6.75 ug/kg) were detected in 9 samples, p’-DDD (8.51 ug/kg) —in 9 samples, p,p’-DDT —in 13 samples. Of the remaining pesticides the concentrations of heptachlor epoxide exceeding the detection limit were observed in 5 sediment samples, Dieldrin —in 15 samples, Aldrin —in 10 samples, Endrin —in 10 samples, Endosulfan I only in 1 sample, Endosulfan II — in 4 samples and Methoxychlor — in 2 samples. The concentrations of Heptachlor epoxide higher than the PEL value (2,74 ug/kg) were detected in 1 sample (1.3%). Of 48.8% of the analysed river sediment samples contained polychlorinated biphenyls above detection limit; in two locations the PCB concentrations were high enough to pose a threat for water organisms.

Słowa kluczowe

PL

związki chloroorganiczne; zanieczyszczenia; osad rzeczny; geochemia osadów

EN

chlorinated compounds; pollution; river sediments; Poland

• Wydawca: Państwowy Instytut Geologiczny - Państwowy Instytut Badawczy
• Czasopismo: Przegląd Geologiczny
• Rocznik: 2005
• Tom: Vol. 53, nr 8
• Strony: 649--655
• Opis fizyczny: Bibliogr. 20 poz., tab., wykr.

Twórcy

autor

Bojakowska I.

• Państwowy Instytut Geologiczny, ul. Rakowiecka 4, 00-975 Warszawa

autor

Gliwicz T.

• Państwowy Instytut Geologiczny, ul. Rakowiecka 4, 00-975 Warszawa

Bibliografia

• 1. BOJAKOWSKAI. SOKOŁOWSKA G. & STRZELECKI R. 2000 - Trwałe zanieczyszczenia organiczne - wielopierścieniowe węglowodory aromatyczne, polichlorowane bifenyle i pestycydy chloroorganiczne - w osadach zbiornika włocławskiego. Prz. Geol., 48: 837-843.
• 2. BREMIE G., OKLA L. & LARSSON P. 1998 - PCB in water and sediment of a lake after remediation of contaminated sediment. Ambio, 27: 398-403.
• 3. BRÜGMANN L. 1998 - Hintergrundbelastung von Ostsee-Sedimen- tationsbecken vor der deutschen Küste. In Schadstoffbelstung der sedimente in den Ostseeküstengewässern. BfG Koblenz-Berlin: 17-80.
• 4. CCME (Canadian Council of Ministers of the Environment) 1999 - Canadian Environmental Quality Guidelines: Canadian Sediment.
• 5. CROCKETT A. & WHITE G. 2003 - Mapping Sediment Contamination and Toxicity in Winter Quarters Bay, McMurdo Station, Antarctica. Water, Soil, Air Pollut., 85: 257-275.
• 6. EISENBERG J., BENNETT D. & MCKONE T. 1998 - Chemical dynamics of persistent organic pollutants: a sensitivity analysis relating soil concentration levels to atmospheric emissions. Environ. Sci. Technol., 32: 115-123.
• 7. GRYNKIEWICZ M, POLKOWSKA Ż., GÓRECKI T. & NAMIEŚNIK J. 2003 - Pesticides in precipitation from an urban region in Poland (Gdańsk-Sopot-Gdynia Tricity) between 1998 and 2000. Water, Air, and Soil Pollut., 149: 3-16.
• 8. GULLBRING P., HAMMAR T., HELGG A., TROEDSSON B., HANSSON K. & HANSSON F. 1998 - Remediation of PCB-contaminated sediments in lake Järnsjön: investigations, considerations and remedial action. Ambio, 27: 374-384.
• 9. GUZZELLA L. 1997 - PCBs and organochlorine pesticides in Lake Orta (Northern Italy) sediments. Water, Air, and Soil Pollut., 99: 245-254.
• 10. HABAK-WSV (Handlungsanweisung fur den Umgang mit Baggergut im Kustenbereich) 1999 - BfG (Bundesanstalt fur Gewasserkunde) nr 1100.
• 11. HSU Y., HOLSEN T. & HOPKEP. 2003 - Locating and quantifying PCB sources in Chicago: receptor modeling and field sampling. Environ. Sci. Technol., 37: 681-890.
• 12. JAWARD F. FARRAR N., HARNER T. SWEETMAN A. & JONES K. 2004 - Passive Air Sampling of PCBs, PBDEs, and Organochlorine Pesticides Across Europe. Environ. Sci. Technol., 38 : 34- 41.
• 13. KANNAN K., MARUYA K. & TANABE S. 1997 - Distribution and chracterization of polychlorinated biphenyl congeners in soil and sediments from a superfund site contaminated with Aroclor 1268. Environ. Sci. Technol., 31: 1483-1488.
• 14. MACDONALD D. 1994 - Approach to the Assessment of sediment quality in Florida Coastal Waters. Vol. 1 Development and evaluation of sediment quality assessment guidelines.
• 15. MÜLLER A. & SCHILLING P. 1998 - Sedimentbelastung und Stoffhaushalt im Nordlichen Peenestrom. In Schadstoffbelstung der sedimente in den Ostseekustengewässern. BfG Koblenz-Berlin: 97-121.
• 16. OFFENBERG J. & BAKER J. 1997 - Polychlorinated biphenyls in Chicago precipitation: enhanced wet deposition in near-shore lake Michigan. Environ. Sci. Technol., 31: 1534-1538.
• 17. RAMAMOORTHY Sub & RAMAMOORTHY Sita 1997 - Chlorinated organic compounds in the Environment. Lewis Publishers.
• 18. SHEN L., WANIA F., LEI Y., TEIXEIRA C., MUIR D. & BIDLEMAN T. 2005 - Atmospheric distribution and long-range transport behaviour of organochlorine pesticides in North America. Enviorm. Sci. Technol., 39: 409-420.
• 19. TOTTEN L., GIGLIOTTI C., OFFENBERG J., BAKER J. & EISENREICH S. 2003 - Reevaluation of air-water exchange fluxes of PCBs in Green Bay and Southern Lake, Michigan. Environ. Sci. Technol., 37: 1739-1743.
• 20. YAMASHITA N., KANNAN K., IMAGAWA T., VILLENEUVE D., HASHIMOTO S &, MIYAZAKI A. & GIESY J. 2000 - Vertical profile of polychlorinated dibenzo-p-dioxins, dibenzofuransm, naphtalenes, biphenyls, polycyclic aromatic hydrocarbons, and alkylphenols in sediment core from Tokyo Bay, Japan. Environ. Sci. Technol., 34: 3560-3567.