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Aerozole pochodzenia antropogenicznego w strefie brzegowej Basenu Gdańskiego
Języki publikacji
Abstrakty
Concentrations of ionic components of aerosols and gaseous components of air in the coastal zone of the Southern Baltic were determined. In aerosols over the seawater sulphates of marine origin were always found, however, they were not related to the marine salt. Their role as condensation nuclei in clouds is emphasized with the particular focus on scatter of solar radiation behind the atmosphere. In May 2003, in the atmosphere over Gdynia, no ammonium sulphate was detected and ammonium nitrate was found to be responsible for the reflection of the solar radiation. At the same time when aerosols over the Gulf of Gdańsk were poor with ammonium nitrate the backscatter of light was made essentially by ammonium sulphate. Because of high Rh of the air over both stations aerosol was likely to be supersaturated with water vapor. Both ammonium salts were, in turn, observed over Sopot in August with the NH4NO3 / (NH4),2SO4 ratio equal to 1:3. The relative air humidity was above crystallization point. The aerosol was wet and considered to be responsible for the backscattering of the solar radiation.
W strefie brzegowej południowego Bałtyku i nad otwartym morzem zmierzono stężenia jonowych składników aerozoli oraz gazowych składników powietrza. W atmosferze nadmorskiej w aerozolach obecne były zawsze siarczany morskiego pochodzenia, niezwiązane z solą morską (nssSO4), które jako jądra kondensacji w chmurach odbijają promieniowanie słoneczne poza atmosferę. W maju 2003 w atmosferze nad Gdynią nic obserwowano siarczanu amonu w aerozolach, a za odbijanie światła odpowiedzialny był azotan amonu. W tym samym czasie, gdy w aerozolach nad Głębią Gdańską nie było azotanu amonu rolę tę pełnił siarczan amonu. Ze względu na wysoką wilgotność powietrza nad obiema stacjami aerozol był przesycony parą wodną. Nad Sopotem, w sierpniu 2003 roku obserwowano obie sole amonowe, a stosunek NH4NO3 / (NH4),2SO4 wynosił 1:3. Wilgotność względna powietrza atmosferycznego była wówczas powyżej punktu krystalizacji, aerozol był "mokry" i odpowiadał za odbijanie promieniowania słonecznego.
Czasopismo
Rocznik
Tom
Strony
15--24
Opis fizyczny
Bibliogr. 22 poz., tab., wykr.
Twórcy
autor
- University of Gdańsk, Institute of Oceanography, al. Pitsudskiego 46, 81-378 Gdynia, Poland
autor
- University of Gdańsk, Institute of Oceanography, al. Pitsudskiego 46, 81-378 Gdynia, Poland
Bibliografia
- [1]. PN-91/C-04642/05: Water and wastes. Determination of pollutants in atmospheric precipitation. Analysis of the sum of nitrite and nitrate ions and nitrite ions by colorimetric method, 1992 (in Polish).
- [2]. PN-91/C-04642/03: Water and wastes. Determination of pollutants in atmospheric precipitation. Analysis of sulfate ions by colorimetric method, 1992 (in Polish).
- [3]. Bales T., M. Scholes: Working towards a new atmospheric project within IGPB, Global Change News Letter, 50, 11-14 (2002).
- [4]. Brasseur G., B. Moore III: The new evolving IGPB, Global Change News Letter, SO, 1-3 (2002).
- [5]. De Bock L.A., H. Van Malderen, R E. Van Grieken: Individual aerosol particle composition variations in air masses crossing the North Sea, Environ. Sci. Technol., 28, 1513-1520 (1994).
- [6] Duce R.A., E.J. Hoffman: Chemical fractionation at the air-sea interface, Annual Rev. of Earth and Planet, Science, 4, 187-228 (1976).
- [7] Dougle P.G., J.P. Veefkind, H.M. ten Brink: Crystallization of mixtures of ammonium nitrate, ammonium sulfate and soot, J. Aerosol Sci., 29, 3, 375-386 (1998).
- [8] Dougle P.G., A.L. Vlasenko, J.P. Veefkind, H.M. ten Brink: Humidity dependence of the light scattering by mixtures of ammonium nitrate, ammonium sulfate and soot, J. Aerosol Sci., 27, 1, 513-514 (1996).
- [9] EMEP: Co-operative Program for Monitoring and Evaluation of the Long Range Transmission of Air Pollutants in Europe, Manual for Sampling and Chemical Analysis, Chem. 3, 1977.
- [10] Falkowska L., A. Lewandowska: Sulfates in different size particles in the marine boundary layer over the southern Baltic Sea, Oceanologia, 46(2), 201-215 (2004).
- [11] Gebhart K.A., S. Copeland, W.C. Malm: Diurnal and seasonal patterns in light scattering, extinction, and relative humidity, Atmospheric Environment, 35, 5177-5191 (2001).
- [12] Grasshoff K„ M. Ehrhardt, K. Kremling: Methods of seawater analysis, Verlag Chemie, Weinhen - New York 1983.
- [13] Houghton J.T.: Climate Change: Radiative Forcing of Climate, 3, Cambridge University Press, Cambridge 1995.
- [14] Houghton J.T., Y. Ding, D.J. Griggs, M. Noguer, PJ. van der Linden, X. Dai, K. Maskell, C.A. Johnson (eds.): Climate Change: The Scientific Basis. Contribution of Working Group 1 to the Third Assessment Report of the Intergovernmental Panel on Climate Change, IPCC, Cambridge University Press, Cambridge UK and New York USA, 2001, pp. 881.
- [15] Lewandowska A., L. Falkowska: Ammonia and ammonium over the southern Baltic Sea Part I. Preparation of aerosol and air samples for the determination of ammonia by the indophenol method, Oceanologia, 46(2), 175-184 (2004).
- [16] Lewandowska A., L. Falkowska, M. Bełdowska: Ammonia and ammonium over the southern Baltic Sea Part 2. The origin of ammonia and ammonium over two coastal stations: Gdynia and Hel, Oceanologia, 46(2), 185-200 (2004).
- [17] Nadstazik A., L. Falkowska: Selected ionic components of the marine aerosol over the Gulf of Gdansk, Oceanologia, 43(1), 23-37 (2001).
- [18] Nadstazik A., R. Marks, M. Schulz: Nitrogen species and macroelements in aerosols over the southern Baltic Sea, Oceanologia, 42(4), 411-424 (2000).
- [19] Seinfeld J.H., S.N. Pandis: Atmospheric chemistry and physics from air pollution to climate change, Willey Interscience Publication 1998, pp. 1326.
- [20] Stelson A.W., J.H. Seinfeld: Relative humidity and temperature dependence of the ammonium nitrate dissociation constant, Atm. Environ., 16, 983-992 (1982).
- [21] ten Brink H.M., A. Khlystov, G.P.A. Kos, T. Tuch, C. Roth, W. Kreyling: A high-flow humidograph for testing the water uptake by ambient aerosol, Atmospheric Environment, 34, 4291-4300 (2000).
- [22] ten Brink H.M., C. Kruisz, G.P.A. Kos, A. Berner: Composition/Size of the light-scattering aerosol in the Netherlands, Atmospheric Environment, 30, 23, 3955-3962 (1997).
Typ dokumentu
Bibliografia
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bwmeta1.element.baztech-article-BUS2-0008-0092