Wpływ substancji powierzchniowo czynnych na zwilżalność niskoenergetycznych hydrofobowych ciał stałych

Jańczuk, B.; Szymczyk, K.; Wójcik, W.

Artykuł - szczegóły

Tytuł artykułu

Wpływ substancji powierzchniowo czynnych na zwilżalność niskoenergetycznych hydrofobowych ciał stałych

Autorzy

Jańczuk B. , Szymczyk K. , Wójcik W.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

Warianty tytułu

The influence of the surface active agents on wettability of low energetic hydrophobic solids

Języki publikacji

Abstrakty

The paper reviews the thermodynamic of the most important problems of wettability of a solid and correlation between adsorption of surface active agents at water-air, and solid-water interfaces and wettability of hydrophobic low-energy solids. Three types of wetting have been considered; spreading wetting, adhesional wetting and immersional wetting. The usefulness of the Good and Girifalco, Fowkes, Owens and Wendt, and van Oss et al. approaches to interfacial free energy of liquid- -liquid and solid-liquid for determination of work of spreading, immersion and adhesion is presented. The correlation between the work of spreading, immersion and adhesion and contact angle is also shown. On the basis of the contact angle the relationship between wettability of the solids and its surface free energy and surface tension of liquid is discussed. Zisman found for low-energy solids a straight linear relationship between cos<θ((θ is the contact angle) and surface tension of liquids or aqueous surfactant solutions. The extrapolation of this relationship to cosθ = 1 allows estimation of the liquid surface tension required to give a contact angle of zero degree, which Zisman described as the critical surface tension. However, in contrary to Zisman, Bergeman and van Voorst Vader, stated that there is straight linear relationship between the adhesional tension (γ_1γ,cosθ) and surface tension, γ_1γ, of aqueous solutions of several types of surface active agents (surfactants). Such relationship was also confirmed by other investigators, however, the different equations describing the wettability of the same solids than Bergeman and van Voorst Vader by aqueous solutions of surfactants has been suggested. A direct method to investigate relative adsorption at interfaces is described. The usefulness of Lucassen-Reynders equation derived from Young and Gibbs equations for the studies of the correlation between adsorption of the surface active agents at water-air and solid-water interfaces and wettability of low-energy hydrophobic solids is discussed. We proved that on the basis of the surface tension of low-energy hydrophobic solids, surface tension of aqueous solution of surfactants or their mixtures, and Fowkes approach to interfacial tension the wettability of low-energy hydrophobic solids can be predicted.

Słowa kluczowe

adhezja adsorpcja zwilżanie współczynnik rozpływania kąt zwilżania krytyczne napięcie powierzchniowe zwilżania substancje powierzchniowo czynne

adhesion adsorption wettability spreading coefficient contact angle critical surface tension of wetting surface active agents

Wydawca

Polskie Towarzystwo Chemiczne

Czasopismo

Wiadomości Chemiczne

Rocznik

2005

Tom

[Z] 59, 5-6

Strony

489--508

Opis fizyczny

Bibliogr. 44 poz., rys.

Twórcy

autor

Jańczuk B.

Bronek@hermes.umcs.lublin.pl

Zakład Zjawisk Międzyfazowych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej, Pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

autor

Szymczyk K.

Zakład Zjawisk Międzyfazowych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej, Pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

autor

Wójcik W.

Zakład Zjawisk Międzyfazowych, Wydział Chemii, Uniwersytet Marii Curie-Skłodowskiej, Pl. Marii Curie-Skłodowskiej 3, 20-031 Lublin

Bibliografia

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[13] S. Wu, [w:] Polymer Blends, Vol. 1, Eds: D.R. Paul, S. Neumann, Academic Press, New York 1961.
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[15] CJ. van Oss, M.K. Chaudhmy, RJ. Good, Chem. Rev., 1988, 8 8, 927.
[16] RJ. Good, CJ. van Oss, [w:] Modern Approach to Wettability: Theory and Applications, Eds. M.E. Schrader, G. Loeb, Plenum Press, New York 1991, s. 1.
[17] E. Chibowski, L. Hołysz, Langmuir, 1992, 8, 710.
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[22] W.A. Zisman, Contact Angle, Wettability and Adhesion, [w:] Advances in Chemistry Series, Vol. 43, American Chemical Society, Washinghton, DC, 1964.
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[39] J.R. Dann, J. Colloid Interface Sci., 1970, 32, 321.
[40] F.M. Fowkes, Ind. Chem., 1964, 56/12, 40.
[41] B. Jańczuk, T. Białopiotrowicz, W. Wójcik, Colloid Surf., 1989, 36, 391.
[42] B. Jańczuk, W. Wójcik, A. Zdziennicka, M.L. Gonzalez-Martin, J.M. Bruque, Wiad. Chem., 200, 54, 9.
[43] B. Jańczuk, J.A. Mendez-Sierra, M.L. Gonzalez-Martin, J.M. Bruque, W. Wójcik, J. Colloid Interface Sci., 1996, 184, 607.
[44] B. Jańczuk, J.A. Mendez-Sierra, M.L. Gonzalez-Martin, J.M. Bruque, W. Wójcik, J. Colloid Interface Sci., 1997, 192, 408.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-article-BUS2-0007-0095