Semifluorowane alkany (SFA) - właściwości w ciele stałym, roztworach i na granicach międzyfazowych

• Autorzy: Broniatowski M. , Dynarowicz-Łątka P.

Warianty tytułu

EN

Semifluorinated alkanes (SFA) - properties in bulk solid, in solutions and at interfaces

• Języki publikacji: PL

Abstrakty

EN

Semifluorinated n-alkanes (SFA), of the general formula F(CF2)m-(CH2)nH (abbreviated as FmHn) consist of a linear hydrocarbon segment linked to a fluorocarbon chain. These two units are highly incompatible, what arises from a very different physical and mechanical properties of hydrogenated and perfluorinated hydrocarbons. The presence of two opposing segments within one molecule makes semifluorinated alkanes a very interesting class of compounds, which show a particular behavior in bulk and at interfaces. Their highly asymmetric structure, arising from the incompatibility of the both constituent parts, results in surface activity of these molecules (so-called primitive surfactants) when dissolved in organic solvents, and allows for the Langmuir monolayer formation if spread at the air/water interface, despite of the absence of polar group. Since 1984, semifluorinated alkanes have been subject to many studies concerning their structure and physicochemical properties in bulk phase (solid and liquid) and at interfaces (oil/water; air/water). The present article reviews the results obtained so far.

Słowa kluczowe

PL

fluor; semifluorowane alkany; SFA; właściwości SFA w ciele stałym; SFA w roztworach

EN

semifluorinated alkanes; SFA; SFA in solutions; SFA in bulk solid

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Wiadomości Chemiczne
• Rocznik: 2004
• Tom: [Z] 58, 7-8
• Strony: 535--569
• Opis fizyczny: rys., bibliogr. 102 poz.

Twórcy

autor

Broniatowski M.

autor

Dynarowicz-Łątka P.

• Wydział Chemii Uniwersytetu Jagiellońskiego, Zakład Chemii Ogólnej, ul. Ingardena 3, 30-060 Kraków

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